Abstract:
A method for producing a conductive polymer film using an apparatus comprising a prism having a working electrode, a light-emitting means, a light probe disposed on both sides of the prism, a container having an electrolytic solution containing a conductive-polymer-forming monomer and a dopant, a counter electrode immersed in the electrolytic solution, a power supply connected to a working electrode and the counter electrode, and a controller connected to the light probe and the power supply means. The method comprises determining an absorption spectrum from light reflected by the conductive polymer film, storing the relation between the absorbance of the conductive polymer film obtained from the absorption spectrum and a parameter of the conductive polymer film in the controller, and controlling current supply to the electrodes based on the relation of the absorbance and the parameter to obtain a desired parameter.
Abstract:
An apparatus for controlling the flow rate of a fluid passing through a micro-flow path, comprising an electrode layer, an electrolyte layer and a conductive polymer membrane in this order, the conductive polymer membrane being exposed to the micro-flow path, and the flow rate being controlled by supplying electric current from the electrode layer to the conductive polymer membrane via the electrolyte layer.
Abstract:
The aromatic heterocyclic copolymer is produced by (a) reacting (i) an aromatic diaminodithiol compound, hydrogen atoms of thiol groups of which compound are substituted with substituted or unsubstituted alkyl groups, with (ii) an aromatic diamino compound and (iii) a dicarboxylic acid derivative in an organic solvent, to produce a precopolymer; and (b) heating the precopolymer to cause a thiazole ring closure reaction. This aromatic heterocyclic copolymer is contained as a reinforcing polymer in a molecular composite material.
Abstract:
Provided is a method for preparing ethanol in high efficiency. The ethanol preparation method includes a step of yielding a saccharide water solution through saccharification of cellulose with an enzyme in water, a step of condensing the saccharide water solution, and a step of yielding an ethanol water solution by fermenting the saccharide in the condensed saccharide water solution into ethanol, wherein the step of condensing the saccharide water solution is performed through a pervaporation treatment on the saccharide water solution by using a water separation membrane composed of polypyrrole doped with a sulfonate ion.
Abstract:
Provided is a water separation membrane capable of effectively separating water from a water solution of ethanol, saccharide or the like. The water separation membrane is composed of polypyrrole doped with a sulfonate ion. The sulfonate ion may be an aromatic or aliphatic sulfonate ion.
Abstract:
A device for concentrating ethanol from an ethanol water solution yielded from lignocellulose is equipped with a water separation membrane, an ethanol water solution storing unit and a depressurizing container provided so as to sandwich the water separation membrane, a dry gas cylinder for supplying dry gas to an ethanol vapor residing unit above the ethanol water solution storing unit, a pump for sucking in the interior of the ethanol vapor residing unit, and a cold trap for collecting the concentrated ethanol by condensing the ethanol vapor sucked in by the pump.
Abstract:
A method for yielding concentrated ethanol from an ethanol water solution yielded from ethanol fermentation of a water solution of saccharide generated by a saccharification of the lignocellulose by enzyme is provided. Water is separated from the ethanol water solution yielded from ethanol fermentation of the water solution of saccharide generated by the saccharification of the lignocellulose by enzyme with pervaporation method using a water separation membrane. Condensate prepared by condensing ethanol vapor existing in a space above a liquid level of the ethanol water solution is collected.
Abstract:
Provided is a method for preparing ethanol in high efficiency. The ethanol preparation method includes a step of yielding a saccharide water solution through saccharification of cellulose with an enzyme in water, a step of condensing the saccharide water solution, and a step of yielding an ethanol water solution by fermenting the saccharide in the condensed saccharide water solution into ethanol, wherein the step of condensing the saccharide water solution is performed through a pervaporation treatment on the saccharide water solution by using a water separation membrane composed of polypyrrole doped with a sulfonate ion.
Abstract:
A method for producing a conductive polymer film, using an apparatus comprising a prism having a working electrode, a light-emitting means and a light probe disposed on both sides of the prism, a container attached to the prism in a liquid-tight manner with its open side facing the working electrode, an electrolytic solution containing a conductive-polymer-forming monomer and a dopant, which is contained in the container, a counter electrode immersed in the electrolytic solution, a power supply means connected to the working electrode and the counter electrode, and a controller connected to the light probe and the power supply means, the method comprising (1) forming the conductive polymer film on the working electrode by supplying current from the power supply means to the working electrode and the counter electrode, while projecting light to the prism, (2) determining an absorption spectrum from the light reflected by the conductive polymer film, (3) storing the relation between the absorbance of the conductive polymer film obtained from the absorption spectrum and a parameter of the conductive polymer film in the controller, and (4) controlling current supply to the working electrode and the counter electrode based on the relation of the absorbance and the parameter to obtain a desired parameter.
Abstract:
A molecular-oriented polymer gel and its cast film obtained by self-assembly of a self-organizable amphiphilic compound and a monomer interacting with the amphiphilic compound, and then polymerizing the monomer, and their production methods.