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1.发明授权Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers 有权多组分催化剂体系和用于形成宽分子量聚合物的聚合方法公开(公告)号：US08461276B2
公开(公告)日：2013-06-11
申请号：US13525443
申请日：2012-06-18
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/6592 , C08F4/60 , C08F4/603 , C08F4/606 , C08F4/653
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.
摘要翻译： 本文描述了丙烯聚合方法，由其形成的聚合物和膜。 丙烯聚合方法通常包括在聚合反应容器内将丙烯和一定量的乙烯与第一茂金属催化剂和第二茂金属催化剂接触以形成丙烯基聚合物，其中该量是有效形成基于丙烯的聚合物的量，包括 约2重量％ ％至约6wt。 ％乙烯，第二茂金属催化剂能够比第一茂金属催化剂在丙烯基聚合物中引入更多量的乙烯，并且其中第一茂金属催化剂能够形成丙烯/乙烯无规共聚物，其表现出大于 由第二茂金属催化剂形成的丙烯/乙烯无规共聚物。
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公开(公告)号：US08399726B2
公开(公告)日：2013-03-19
申请号：US12763233
申请日：2010-04-20
IPC分类号： C07C2/66
CPC分类号： C07C2/84 , B01J8/02 , B01J8/18 , B01J19/02 , B01J23/002 , B01J23/02 , B01J23/34 , B01J37/0201 , B01J37/031 , B01J2219/00006 , B01J2219/0209 , B01J2219/0218 , B01J2219/025 , B01J2523/00 , C07C2/64 , C07C5/327 , C07C2521/10 , C07C2523/02 , C07C2523/30 , C07C2523/34 , Y02P20/52 , B01J2523/12 , B01J2523/22 , B01J2523/69 , B01J2523/72 , C07C15/46
摘要： A method for the oxidative coupling of hydrocarbons includes providing an oxidative catalyst inside a reactor and carrying out the oxidative coupling reaction under a set of reaction conditions. The reactor surfaces that contact the reactants and products do not provide a significant detrimental catalyzing effect. In an embodiment the reactor contains an inert lining or a portion of the reactor inner surface is treated to reduce the detrimental catalytic effects. In an embodiment the reactor contains a lining that includes an oxidative catalyst.
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3.发明申请MULTI-COMPONENT CATALYST SYSTEMS AND POLYMERIZATION PROCESSES FOR FORMING IN-SITU HETEROPHASIC COPOLYMERS AND/OR VARYING THE XYLENE SOLUBLES CONTENT OF POLYOLEFINS 有权多组分催化剂体系和形成异源共聚物的聚合方法和/或改变聚烯烃的二甲苯溶液含量公开(公告)号：US20110269923A1
公开(公告)日：2011-11-03
申请号：US13180672
申请日：2011-07-12
申请人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
发明人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , Y10S526/943 , C08F4/65904 , C08F210/16 , C08F2500/12 , C08F2500/05
摘要： Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.
摘要翻译： 本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和多相共聚物。 多组分催化剂体系通常包括选自齐格勒 - 纳塔催化剂体系的第一催化剂组分，其包括二醚内电子给体和由通式XCpACpBMAn表示的茂金属催化剂，其中X是结构桥，CpA和CpB各自表示环戊二烯基 基团或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是过渡金属，A是烷基，烃基或卤素基团，n是0和4之间的整数。多组分催化剂 系统还包括通常由式XCpACpBMAn表示的第二催化剂组分，其中X是结构桥，CpA和CpB各自表示环戊二烯基或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是 过渡金属，A是烷基，烃基或卤素基团，n是0至4之间的整数， nd催化剂组分表现出比第一催化剂组分更高的乙烯响应。
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公开(公告)号：US20100331595A1
公开(公告)日：2010-12-30
申请号：US12494117
申请日：2009-06-29
IPC分类号： C07C5/00
CPC分类号： C07C2/84 , B01J21/10 , B01J23/02 , B01J23/10 , B01J23/36 , C07C2521/10 , C07C2523/02 , C07C2523/10 , C07C2523/36 , Y02P20/52 , Y10S585/906 , C07C9/06 , C07C11/04
摘要： A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.
摘要翻译： 烃的氧化偶合的方法，例如甲烷的氧化偶联，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。
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5.发明申请Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins 有权用于形成原位多相共聚物和/或改变二甲苯可溶物的多组分催化剂体系和聚合方法聚烯烃含量公开(公告)号：US20090105433A1
公开(公告)日：2009-04-23
申请号：US11975014
申请日：2007-10-17
申请人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
发明人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , Y10S526/943 , C08F4/65904 , C08F210/16 , C08F2500/12 , C08F2500/05
摘要： Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.
摘要翻译： 本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和多相共聚物。 多组分催化剂体系通常包括选自齐格勒 - 纳塔催化剂体系的第一催化剂组分，其包括二醚内电子给体和由通式XCpACpBMAn表示的茂金属催化剂，其中X是结构桥，CpA和CpB各自表示环戊二烯基 基团或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是过渡金属，A是烷基，烃基或卤素基团，n是0和4之间的整数。多组分催化剂 系统还包括通常由式XCpACpBMAn表示的第二催化剂组分，其中X是结构桥，CpA和CpB各自表示环戊二烯基或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是 过渡金属，A是烷基，烃基或卤素基团，n是0至4之间的整数， nd催化剂组分表现出比第一催化剂组分更高的乙烯响应。
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公开(公告)号：US20130231513A1
公开(公告)日：2013-09-05
申请号：US13867295
申请日：2013-04-22
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2521/00 , C07C2521/10 , C07C2523/00 , C07C2523/02 , C07C2523/10 , C07C2523/36 , C07C15/073 , C07C15/46
摘要： A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.
摘要翻译： 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。
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公开(公告)号：US08450546B2
公开(公告)日：2013-05-28
申请号：US12494138
申请日：2009-06-29
IPC分类号： C07C2/66
CPC分类号： C07C2/84 , C07C2521/00 , C07C2521/10 , C07C2523/00 , C07C2523/02 , C07C2523/10 , C07C2523/36 , C07C15/073 , C07C15/46
摘要： A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.
摘要翻译： 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。
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8.发明授权Method of coupling a carbon source with toluene to form a styrene ethylbenzene 失效将碳源与甲苯偶联以形成苯乙烯乙苯的方法公开(公告)号：US08318999B2
公开(公告)日：2012-11-27
申请号：US12763234
申请日：2010-04-20
IPC分类号： C07C1/24
CPC分类号： C07C2/862 , C07C2/864 , C07C2/867 , C07C2529/08 , C07C2529/60 , C07C15/46 , C07C15/073
摘要： A process is disclosed for making styrene or ethylbenzene by reacting toluene with a C1 source that is selected from the group consisting of methanol, formaldehyde, formalin, trioxane, methylformcel, paraformaldehyde, methylal, and combinations thereof.
摘要翻译： 公开了通过使甲苯与选自甲醇，甲醛，福尔马林，三恶烷，甲基甲缩醛，多聚甲醛，甲缩醛及其组合的C1源反应制备苯乙烯或乙苯的方法。
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9.发明申请Multi-Component Catalyst Systems and Polymerization Processes for Forming Broad Composition Distribution Polymers 有权多组分催化剂体系和用于形成广泛组分分布聚合物的聚合方法公开(公告)号：US20120264894A1
公开(公告)日：2012-10-18
申请号：US13525443
申请日：2012-06-18
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/76 , C08F210/06
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.
摘要翻译： 本文描述了丙烯聚合方法，由其形成的聚合物和膜。 丙烯聚合方法通常包括在聚合反应容器内将丙烯和一定量的乙烯与第一茂金属催化剂和第二茂金属催化剂接触以形成丙烯基聚合物，其中该量是有效形成基于丙烯的聚合物的量，包括 约2重量％ ％至约6wt。 ％乙烯，第二茂金属催化剂能够比第一茂金属催化剂在丙烯基聚合物中引入更多量的乙烯，并且其中第一茂金属催化剂能够形成丙烯/乙烯无规共聚物，其表现出大于 由第二茂金属催化剂形成的丙烯/乙烯无规共聚物。
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公开(公告)号：US20110092655A1
公开(公告)日：2011-04-21
申请号：US12975354
申请日：2010-12-22
申请人： JOSEPH THORMAN , Shady Henry
发明人： JOSEPH THORMAN , Shady Henry
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F4/65912 , C08F4/65916 , C08F2500/18 , C08F2500/03
摘要： Supported catalysts systems and method of forming the same are described herein. The method generally includes providing a support material, providing a single site transition metal catalyst compound, contacting the transition metal catalyst compound with triisobutyl aluminum (TiBAl) to form a modified catalyst compound and contacting the support material with the modified catalyst compound to form a supported catalyst system.
摘要翻译： 载体催化剂体系及其形成方法在本文中描述。 该方法通常包括提供支撑材料，提供单个位点过渡金属催化剂化合物，使过渡金属催化剂化合物与三异丁基铝（TiBAl）接触以形成改性的催化剂化合物，并使载体材料与改性催化剂化合物接触以形成负载 催化剂体系。
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