摘要:
Squarylium compounds of the formula: ##STR1## wherein Q.sup.1 and Q.sup.2 are each independently a pyrylium, thiopyrylium, selenopyrylium, benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus, and R.sup.1 and R.sup.2 are each independently an aliphatic or cycloaliphatic group, can be prepared by reacting a squaric acid derivative of the formula: ##STR2## with a compound of the formula Q.sup.2 CH.sub.2 R.sup.2 in the presence of a base.
摘要:
Squarylium compounds of the formula: ##STR1## (in which Q.sup.1 and Q.sup.2 are each a chromophoric group having an aromatic unsaturated system conjugated with the squarylium ring and such that in the compounds of formulae Q.sup.1 CH.sub.2 R.sup.1 and Q.sup.2 CH.sub.2 R.sup.2 the methylene hydrogens are active hydrogens, R.sup.1 and R.sup.2 are each independently a hydrogen atom or an aliphatic or cycloaliphatic group, and R.sup.3 and R.sup.4 are each independently a hydrogen atom, or an acyl, aliphatic, cycloaliphatic, aromatic or heterocyclic group, subject to the proviso that one of R.sup.3 and R.sup.4 may be an amino or substituted amino group, or one of R.sup.3 and R.sup.4 is a hydrogen atom and the other is an organosulfonyl group, or R.sup.3 and R.sup.4 together with the intervening nitrogen atom form a nitrogenous heterocyclic ring) are useful as near infra-red absorbers. The presence of the amino group on the squarylium ring enables minor changes in absorption wavelength to be achieved by modifications of this group, and also allows functional groups to be incorporated into the dye without changing the chromophoric groups.
摘要:
In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein each R.sup.1 is the same and is selected from ##STR2## R.sup.2 is alkyl, R.sup.3 is an electron-withdrawing group positioned ortho, meta or para to said N atom, R.sup.4 is hydrogen, alkyl or an electron-withdrawing group positioned ortho, meta or para to said N atom; R.sup.5 is alkyl; X is hydrogen, an electron-withdrawing group or an electron-donating group; and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds, e.g., as photographic light-screening dyes.
摘要:
This invention relates to 3-(julolidinyl)-benz[d]-isothiazole-1,1-dioxide useful as an intermediate in the synthesis of certain 3,3-disubstituted-2,3-dihydrobenz[d]-isothiazole-1,1-dioxide dyes which find utility as, for example, photographic optical filter agents and filter agent precursors.
摘要:
This invention relates to 3-(phenyl/naphthyl)benz[d]isothiazole-1,1-dioxides wherein the phenyl or naphthyl substituent possesses an N-heterocyclic moiety in the para position. These compounds are useful as intermediates in the synthesis of certain 3,3-disubstituted-2,3-dihydrobenz[d]isothiazole-1,1-dioxide dyes which find utility as, for example, photographic optical filter agents and filter agent precursors.
摘要:
A process is provided for the hydrolysis of polyhalobenzenes to polyhalophenols in good yields and purity by initially reacting ethylene glycol with an alkali metal hydroxide to obtain a mixture comprising ethylene glycol alkali metal derivative, alkali metal hydroxide and ethylene glycol, adding to the latter mixture a mono- or di-alkylated benzene, such as toluene or ethylbenzene, then introducing a polyhalobenzene, whereby hydrolysis of the latter occurs and, thereafter, recovering the hydrolyzed benzene.
摘要:
Various embodiments and methods are disclosed relating to one or more media guides configured to guide a surface being printed upon relative to a manually moved print device.
摘要:
Various embodiments and methods are disclosed relating to one or more media guides configured to guide a surface being printed upon relative to a manually moved print device.