公开(公告)号：US08697027B2

公开(公告)日：2014-04-15

申请号：US12546047

申请日：2009-08-24

申请人： Ighor K. Uzhinsky ,  Gary K. Lund ,  John C. Leylegian ,  Florin Girlea ,  Jason S. Tyll ,  Lawrence G. Piper ,  Marten Byl ,  Wallace Chinitz

发明人： Ighor K. Uzhinsky ,  Gary K. Lund ,  John C. Leylegian ,  Florin Girlea ,  Jason S. Tyll ,  Lawrence G. Piper ,  Marten Byl ,  Wallace Chinitz

IPC分类号： C01B3/02 ,  C01B3/04 ,  C01B3/06 ,  C01B3/24 ,  C01B3/26 ,  C01B6/00 ,  H01M8/06 ,  H01M8/10 ,  H01M8/12

CPC分类号： C01B3/065 ,  C01B13/0214 ,  C01B13/0233 ,  C01B2203/066 ,  C01B2210/0062 ,  H01M8/04111 ,  H01M8/0606 ,  H01M8/0612 ,  H01M8/065 ,  H01M2008/1293 ,  H01M2250/20 ,  Y02E60/362 ,  Y02E60/364 ,  Y02E60/525 ,  Y02T90/32

摘要： Methods and systems of providing a source of hydrogen and oxygen with high volumetric energy density, as well as a power systems useful in non-air breathing engines such as those in, for example, submersible vehicles, is disclosed. A hydride reactor may be utilized in forming hydrogen from a metal hydride and a peroxide reactor may be utilized in forming oxygen from hydrogen peroxide. The high temperature hydrogen and oxygen may be converted to water using a solid oxide fuel cell, which serves as a power source. The power generation system may have an increased energy density in comparison to conventional batteries. Heat produced by exothermic reactions in the hydride reactor and the peroxide reactor may be transferred and utilized in other aspects of the power generation system. High temperature water produced during by the peroxide reactor may be used to fuel the hydride reactor.

摘要翻译： 公开了提供具有高体积能量密度的氢和氧源的方法和系统，以及在非空气呼吸发动机（例如潜水车辆）中有用的动力系统。 氢化物反应器可用于从金属氢化物形成氢气，并且过氧化物反应器可用于从过氧化氢形成氧气。 可以使用用作电源的固体氧化物燃料电池将高温氢和氧转化为水。 与常规电池相比，发电系统可能具有增加的能量密度。 在氢化物反应器和过氧化物反应器中通过放热反应产生的热可以转移并用于发电系统的其它方面。 过氧化物反应器产生的高温水可用于燃料氢化物反应器。

公开(公告)号：US08420267B2

公开(公告)日：2013-04-16

申请号：US12581735

申请日：2009-10-19

申请人： Ighor K. Uzhinsky ,  Fernando Aguirre ,  Anthony G. Castrogiovanni

发明人： Ighor K. Uzhinsky ,  Fernando Aguirre ,  Anthony G. Castrogiovanni

IPC分类号： C01B3/04 ,  B01J7/00 ,  H01M8/06

CPC分类号： C01B3/065 ,  C01B3/04 ,  C06B47/10 ,  C06D5/06 ,  Y02E60/362 ,  Y02E60/364

摘要： Provided herein are methods and systems of producing hydrogen using ammonia borane, which has a high hydrogen density while being stable and easily stored. Ammonia borane may be exothermically reacted with a strong oxidizer, such as a mixture of hydrogen peroxide and water. The reaction between ammonia borane and the strong oxidizer may occur spontaneously and may produce heat. Unreacted ammonia borane may be exposed to and thermally decomposed using the heat produced during the exothermic reaction between ammonia borane and the strong oxidizer. The heat may be retained by performing the reactions in a vessel or reactor including a material capable of retaining the heat. A high gravimetric hydrogen yield is obtained from the reaction of ammonia borane with hydrogen peroxide and the thermal decomposition of unreacted ammonia borane. Hydrogen production using the methods and systems may yield a high gravimetric hydrogen content of at least about 10%.

摘要翻译： 本文提供使用氨硼烷生产氢的方法和系统，其具有高氢密度，同时稳定且容易储存。 氨硼烷可能与强氧化剂如过氧化氢和水的混合物放热反应。 氨硼烷和强氧化剂之间的反应可能会自发发生并产生热量。 未反应的氨硼烷可以使用在氨硼烷和强氧化剂之间的放热反应期间产生的热量暴露并热分解。 可以通过在包含能够保持热量的材料的容器或反应器中进行反应来保持热量。 从氨硼烷与过氧化氢的反应和未反应的氨硼烷的热分解得到高重量氢气产率。 使用该方法和系统的氢气生产可产生至少约10％的高重量氢含量。

公开(公告)号：US20100111823A1

公开(公告)日：2010-05-06

申请号：US12581735

申请日：2009-10-19

申请人： Ighor K. Uzhinsky ,  Fernando Aguirre ,  Anthony G. Castrogiovanni

发明人： Ighor K. Uzhinsky ,  Fernando Aguirre ,  Anthony G. Castrogiovanni

IPC分类号： C01B3/04 ,  B01J7/00 ,  C01B3/02

CPC分类号： C01B3/065 ,  C01B3/04 ,  C06B47/10 ,  C06D5/06 ,  Y02E60/362 ,  Y02E60/364

摘要： Provided herein are methods and systems of producing hydrogen using ammonia borane, which has a high hydrogen density while being stable and easily stored. Ammonia borane may be exothermically reacted with a strong oxidizer, such as a mixture of hydrogen peroxide and water. The reaction between ammonia borane and the strong oxidizer may occur spontaneously and may produce heat. Unreacted ammonia borane may be exposed to and thermally decomposed using the heat produced during the exothermic reaction between ammonia borane and the strong oxidizer. The heat may be retained by performing the reactions in a vessel or reactor including a material capable of retaining the heat. A high gravimetric hydrogen yield is obtained from the reaction of ammonia borane with hydrogen peroxide and the thermal decomposition of unreacted ammonia borane. Hydrogen production using the methods and systems may yield a high gravimetric hydrogen content of at least about 10%.

摘要翻译： 本文提供使用氨硼烷生产氢的方法和系统，其具有高氢密度，同时稳定且容易储存。 氨硼烷可能与强氧化剂如过氧化氢和水的混合物放热反应。 氨硼烷和强氧化剂之间的反应可能会自发发生并产生热量。 未反应的氨硼烷可以使用在氨硼烷和强氧化剂之间的放热反应期间产生的热量暴露并热分解。 可以通过在包含能够保持热量的材料的容器或反应器中进行反应来保持热量。 从氨硼烷与过氧化氢的反应和未反应的氨硼烷的热分解得到高重量氢气产率。 使用该方法和系统的氢气生产可产生至少约10％的高重量氢含量。

公开(公告)号：US20100055517A1

公开(公告)日：2010-03-04

申请号：US12546047

申请日：2009-08-24

申请人： Ighor K. Uzhinsky ,  Gary K. Lund ,  John C. Leylegian ,  Florin Girlea ,  Jason S. Tyll ,  Lawrence G. Piper ,  Marten Byl ,  Wallace Chinitz

发明人： Ighor K. Uzhinsky ,  Gary K. Lund ,  John C. Leylegian ,  Florin Girlea ,  Jason S. Tyll ,  Lawrence G. Piper ,  Marten Byl ,  Wallace Chinitz

IPC分类号： H01M8/04 ,  C01B13/02 ,  C01B3/04 ,  B01J19/00 ,  H01M8/18

CPC分类号： C01B3/065 ,  C01B13/0214 ,  C01B13/0233 ,  C01B2203/066 ,  C01B2210/0062 ,  H01M8/04111 ,  H01M8/0606 ,  H01M8/0612 ,  H01M8/065 ,  H01M2008/1293 ,  H01M2250/20 ,  Y02E60/362 ,  Y02E60/364 ,  Y02E60/525 ,  Y02T90/32

摘要： Methods and systems of providing a source of hydrogen and oxygen with high volumetric energy density, as well as a power systems useful in non-air breathing engines such as those in, for example, submersible vehicles, is disclosed. A hydride reactor may be utilized in forming hydrogen from a metal hydride and a peroxide reactor may be utilized in forming oxygen from hydrogen peroxide. The high temperature hydrogen and oxygen may be converted to water using a solid oxide fuel cell, which serves as a power source. The power generation system may have an increased energy density in comparison to conventional batteries. Heat produced by exothermic reactions in the hydride reactor and the peroxide reactor may be transferred and utilized in other aspects of the power generation system. High temperature water produced during by the peroxide reactor may be used to fuel the hydride reactor.

摘要翻译： 公开了提供具有高体积能量密度的氢和氧源的方法和系统，以及在非空气呼吸发动机（例如潜水车辆）中有用的动力系统。 氢化物反应器可用于从金属氢化物形成氢气，并且过氧化物反应器可用于从过氧化氢形成氧气。 可以使用用作电源的固体氧化物燃料电池将高温氢和氧转化为水。 与常规电池相比，发电系统可能具有增加的能量密度。 在氢化物反应器和过氧化物反应器中通过放热反应产生的热可以转移并用于发电系统的其它方面。 过氧化物反应器产生的高温水可用于燃料氢化物反应器。