Abstract:
Disclosed are a polymer for a chemically amplified resist represented as and a resist composition using the same. In the above Chemical formula 1, X represents vinyl ether derivatives or olefin derivatives, at least one of R1, R2, R3 and R4 is an alkyl group with 1 to 30 carbon atoms containing at least one functional group of a hydrogen atom, an ether group, an ester group, a carbonyl group, an acetal group, an epoxy group, a nitryl group (—CN), and an aldehyde group, l, m, n, o and p respectively represent repeating units, l represents a real number of 0.05 to 0.5, m and n respectively represent real numbers of 0.1 to 0.7, o and p respectively represent real numbers of 0 to 0.7, and a sum of l, m, n, o and p is 1.
Abstract:
A chemically amplified resist composition consists of an acid generating agent, additive, solvent and a copolymer represented by the following formula: where R1, R2 and R6 are independent of each other and respectively include a hydrogen atom or an alkyl, alkoxymethylene, alkoxyethylene, phenyl, alkoxyalkylene, alkylphenyl, alkoxyphenyl, allyl, benzyl, alkylbenzyl, alkoxybenzyl containing 1 to 34 carbon atoms having or not having an hydroxy, ether, ester, carbonyl, acetal, epoxy, nitrile or aldehyde; R5 is a hydrogen atom, an alkyl or alkoxy group containing 1 to 18 carbon atoms; R7 is a hydrogen atom, an alkyl group containing 1 to 18 carbon atoms, an alkyl group containing alkoxy 1 to 18 carbon atoms or an alkyl group containing ester of 1 to 18 carbon atoms; R3 and R4 are independent and respectively include a hydrogen atom, hydroxy, nitrile, aldehyde, hydroxymethylene, and alkylcarbonyloxy, alky, hydroxyalkylene, alkoxycarbonyl, alkoxymethylene or alkoxyalkanyl group containing 1 to 18 carbon atoms; X is olefin derivatives, vinyl ether derivatives or styrene derivatives containing 1 to 40 carbon atoms, alternatively these derivatives may be comprised of hydroxy, ester, alkoxyalkyloxycarbonyl, ketone or ether; a, b, c, d, e and f are a number represented a repeating unit in the main chain, wherein a+b+c+d+e+f=1, the content of a and b are 0 to 0.7, respectively, (a+b)/(a+b+c+d+e+f)>0.3, and the content of c, d, e and f are 0 to 0.9, respectively; and n is an integer of 0 or 1.
Abstract translation:化学放大抗蚀剂组合物由酸产生剂,添加剂,溶剂和由下式表示的共聚物组成:其中R1,R2和R6彼此独立,分别包括氢原子或烷基,烷氧基亚甲基,烷氧基亚乙基,苯基 烷基苯基,烷氧基苯基,烯丙基,苄基,烷基苄基,含有或不具有羟基,醚,酯,羰基,缩醛,环氧,腈或醛的1至34个碳原子的烷氧基苄基; R5是氢原子,含有1至18个碳原子的烷基或烷氧基; R7是氢原子,含有1至18个碳原子的烷基,含有1至18个碳原子的烷氧基的烷基或含有1至18个碳原子的烷基的酯; R3和R4独立地分别包括含有1至18个碳原子的氢原子,羟基,腈,醛,羟基亚甲基和烷基羰基氧基,烷基,羟基亚烷基,烷氧基羰基,烷氧基亚甲基或烷氧基烷基; X是含有1至40个碳原子的烯烃衍生物,乙烯基醚衍生物或苯乙烯衍生物,或者这些衍生物可以由羟基,酯,烷氧基烷氧基羰基,酮或醚组成。 a,b,c,d,e和f是主链中重复单元的数字,其中a + b + c + d + e + f = 1,a和b的含量分别为0〜0.7 ,(a + b)/(a + b + c + d + e + f)> 0.3,c,d,e和f的含量分别为0〜0.9, n为0或1的整数。
Abstract:
Disclosed are a polymer for a chemically amplified resist represented as and a resist composition using the same. In the above Chemical formula 1, X represents vinyl ether derivatives or olefin derivatives, at least one of R1, R2, R3, and R4 is an alkyl group with 1 to 30 carbon atoms containing at least one functional group of a hydrogen atom, an ether group, an ester group, a carbonyl group, an acetal group, an epoxy group, a nitryl group (—CN), and an aldehyde group, l, m, n, o and p respectively represent repeating units, l represents a real number of 0.05 to 0.5, m and n respectively represent real numbers of 0.1 to 0.7, o and p respectively represent real numbers of 0 to 0.7, and a sum of l, m, n, o and p is 1.