公开(公告)号：US09340693B2

公开(公告)日：2016-05-17

申请号：US14004729

申请日：2012-03-27

Applicant: Akio Maeda ,  Satoshi Mori ,  Masashi Ikeda ,  Toshiyuki Takabayashi ,  Takashi Iwata ,  Hirotaka Iijima

Inventor： Akio Maeda ,  Satoshi Mori ,  Masashi Ikeda ,  Toshiyuki Takabayashi ,  Takashi Iwata ,  Hirotaka Iijima

IPC: B41J2/01 ,  C09D11/38 ,  C09D11/101 ,  B41J11/00 ,  C09D11/12 ,  B41M7/00

CPC classification number: C09D11/38 ,  B41J11/0015 ,  B41M7/0081 ,  C09D11/101 ,  C09D11/12

Abstract: The purpose of the present invention is to provide an actinic ray curable inkjet ink which, in an inkjet printing method, is capable of having both high pinning characteristics and high ejection characteristics. In order to achieve the above purpose, this actinic ray curable inkjet ink includes an actinic ray curable compound, ketone wax, and ester wax, and reversibly goes through a sol-gel phase transition depending on the temperature.

Abstract translation: 本发明的目的是提供一种能够具有高钉扎特性和高喷射特性的喷墨印刷方法的光化射线固化型喷墨油墨。 为了达到上述目的，该光化射线固化型喷墨油墨包括光化学射线固化性化合物，酮蜡，酯蜡，根据温度可逆地经历溶胶 - 凝胶相变。

公开(公告)号：US09016846B2

公开(公告)日：2015-04-28

申请号：US13817375

申请日：2011-07-13

Applicant: Masashi Ikeda ,  Hirotaka Iijima ,  Toshiyuki Takabayashi ,  Tomoe Sekiguchi ,  Akio Maeda

Inventor： Masashi Ikeda ,  Hirotaka Iijima ,  Toshiyuki Takabayashi ,  Tomoe Sekiguchi ,  Akio Maeda

IPC: B41J2/01 ,  C09D11/101 ,  B41J2/21 ,  C09D11/322 ,  C09D11/40 ,  B41J11/00

CPC classification number: C09D11/101 ,  B41J2/2107 ,  B41J11/002 ,  C09D11/322 ,  C09D11/40

Abstract: Provided are an actinic energy radiation curable ink, which can achieve a high fineness and natural glossiness when recording is carried out onto a non-absorptive recording medium such as a film or a laminated paper or a slightly absorptive recording medium such as a coated paper; and an actinic energy radiation curable inkjet recording method. This actinic energy radiation curable ink, which is to be used in inkjet recording, is characterized by: said actinic energy radiation curable ink undergoing reversible sol/gel phase transition depending on temperature; said actinic energy radiation curable ink containing from 1% or more by mass to less than 10% by mass of a gelling agent; and, at temperature Tm (° C.) that is separately defined, the storage elastic modulus (G′) of the actinic energy radiation curable ink being from 0.1 or more Pa to less than 1000 Pa and the storage elastic modulus (G′) being smaller than the loss elastic modulus (G″) thereof.

Abstract translation: 提供了一种光化能辐射固化油墨，其可以在诸如膜或层压纸之类的非吸收性记录介质或诸如涂布纸的轻微吸收记录介质上进行记录时获得高的细度和自然的光泽度; 和光化能辐射固化喷墨记录方法。 用于喷墨记录的光化学能量辐射固化油墨的特征在于：所述光化学能量辐射固化油墨根据温度经历可逆的溶胶/凝胶相变; 所述光化学能量射线固化油墨含有1质量％以上至小于10质量％的胶凝剂; 并且在分别限定的温度Tm（℃）下，光化性能量射线固化型油墨的储能弹性模量（G'）为0.1Pa以上且小于1000Pa，储能弹性模量（G' 小于其损耗弹性模量（G“）。

公开(公告)号：US20120327157A1

公开(公告)日：2012-12-27

申请号：US13581363

申请日：2011-03-09

Applicant: Hirotaka Iijima ,  Toshiyuki Takabayashi ,  Akio Maeda

Inventor： Hirotaka Iijima ,  Toshiyuki Takabayashi ,  Akio Maeda

IPC: B41J2/015 ,  C08F2/46 ,  C09D11/10 ,  C09D133/14

CPC classification number: B41J11/002 ,  B41J2/14209 ,  B41J2/2107 ,  B41J11/0015 ,  B41M7/0081 ,  C09D11/101

Abstract: Disclosed is a printed matter production process comprising ejecting droplets of an actinic ray curable inkjet ink in a heated state through a head to supply the droplets onto a recording medium, thereby forming an image, the actinic ray curable inkjet ink containing a polymerizable compound, a photopolymerization initiator and a gelling agent, having a viscosity of from 60 to 200 mPasecond at 25° C. and at a shear rate of 1000/second and showing a phase transition at a temperature of not lower than 25° C., characterized in that the actinic ray curable inkjet ink contains a bifunctional polymerizable compound with a molecular weight of not lower than 400 and with a viscosity at 25° C. of not more than 100 mPasecond in an amount of not less than 75% by mass of the total amount of the polymerizable compound. The process excels in ink ejection properties, enables high speed printing, and provides a printed matter having an image with high precision image quality, excellent stability and reduced deformation.

Abstract translation: 公开了一种印刷品生产方法，包括通过头喷射处于加热状态的光化可辐射固化喷墨油墨的液滴，以将液滴供应到记录介质上，从而形成图像，含有可聚合化合物的光化可固化喷墨油墨， 光聚合引发剂和胶凝剂，其粘度在25℃和剪切速率为1000 /秒时为60至200mPas，并且在不低于25℃的温度下显示出相变，其特征在于： 光化学射线固化喷墨油墨含有分子量不低于400的双官能聚合性化合物，在25℃下的粘度不大于100mPas，其量不小于总量的75质量％ 的可聚合化合物。 该方法在喷墨性能方面优异，能够进行高速印刷，并提供具有高精度图像质量，优异的稳定性和变形减小的图像的印刷品。

公开(公告)号：US20110216124A1

公开(公告)日：2011-09-08

申请号：US13127150

申请日：2009-10-17

Applicant: Akio Maeda ,  Hirotaka Iijima

Inventor： Akio Maeda ,  Hirotaka Iijima

IPC: B41J2/015 ,  C08F20/58 ,  C08G69/26 ,  C08F20/54

CPC classification number: C09D11/322 ,  C09D11/101

Abstract: Disclosed is an actinic energy radiation curable inkjet ink which can be printed on various types of recording media, has excellent printed image quality and excellent fixability particularly on coated printing paper, and is improved in storage stability and ejection stability. Also disclosed is an inkjet recording method using the actinic energy radiation curable inkjet ink. The actinic energy radiation curable inkjet ink is characterized by containing a compound represented by Formula (1) or a compound represented by Formula (2) in an amount of not less than 0.1% by mass and less than 20% by mass based on a total mass of the ink.

Abstract translation: 公开了可以印刷在各种类型的记录介质上的光化能量辐射固化喷墨油墨，具有优异的印刷图像质量和优异的定影性，特别是在涂布的打印纸上，并且提高了储存稳定性和喷射稳定性。 还公开了使用光化性能量辐射固化型喷墨油墨的喷墨记录方法。 光化性能量射线固化型喷墨油墨的特征在于，含有式（1）表示的化合物或式（2）所示的化合物的含量相对于总计为0.1质量％以上且小于20质量％ 质量的墨水。

公开(公告)号：US20080178761A1

公开(公告)日：2008-07-31

申请号：US12017411

申请日：2008-01-22

Applicant: Atsushi TOMOTAKE ,  Hirotaka IIJIMA

Inventor： Atsushi TOMOTAKE ,  Hirotaka IIJIMA

IPC: B05D5/12 ,  C23C20/02

CPC classification number: C23C18/06 ,  C23C18/08 ,  C23C18/161 ,  C23C18/1692 ,  C23C18/2006 ,  C23C18/30 ,  C23C18/31 ,  C23C18/34 ,  C23C18/40 ,  C23C18/44 ,  H05K3/105 ,  H05K2203/013 ,  H05K2203/1105 ,  H05K2203/121 ,  H05K2203/125

Abstract: An objective is to provide plate making printing exhibit conductivity and flexibility with respect to a flexible substrate, and to provide a method of forming metal patterns via non-plate making printing, and a metal salt mixture usable for the method. Also disclosed is a method of forming a metal pattern possessing the steps of conducting patterning on a substrate with a metal salt mixture for the metal pattern formation possessing a metal salt and a reducing agent, and having a viscosity of 3-50 mPa·s at 25 ° C., and forming the metal pattern via heating to a temperature of 80-400° C.

Abstract translation: 目的是提供相对于柔性基板显示出导电性和柔性的制版印刷品，并提供通过非印版印刷形成金属图案的方法和可用于该方法的金属盐混合物。 还公开了一种形成金属图案的方法，该金属图案具有以下步骤：用金属盐混合物在基底上进行图案化，所述金属盐混合物具有金属盐和还原剂，并且具有3-50mPa.s的粘度 25℃，通过加热形成金属图案至80-400℃。

公开(公告)号：US06561638B1

公开(公告)日：2003-05-13

申请号：US10146858

申请日：2002-05-15

Applicant: Hirotaka Iijima ,  Naoki Sato ,  Kenzo Kasahara

Inventor： Hirotaka Iijima ,  Naoki Sato ,  Kenzo Kasahara

IPC: G01D1100

CPC classification number: C09D11/322

Abstract: An ink-jet recording method comprising the step of adhering a dispersion ink comprised of a colorant dispersed in a solvent onto recording medium having a fine particle and a water-soluble binder, wherein the relation the center-line average surface roughness RaA in &mgr;m at the non-image area of the recording medium and the center-line average surface roughness RaB in &mgr;m at the image area of the recording medium is represented by Expression 1 is described. 0.7≦RaB/RaA≦1.8  Expression 1. According to the above, an ink-jet recording method and a recording matter excellent in the glossiness feel, smoothness feel and texture can be provided.

Abstract translation: 一种喷墨记录方法，包括将由分散在溶剂中的着色剂组成的分散油墨粘附到具有细颗粒和水溶性粘合剂的记录介质上的步骤，其中，将在中间线平均表面粗糙度RaA 描述记录介质的非图像区域和记录介质的图像区域处的母体中心线平均表面粗糙度RaB由表达式1表示。根据上述，喷墨记录方法和记录 可以提供光泽感觉优异的光滑感和质感。

公开(公告)号：US09062223B2

公开(公告)日：2015-06-23

申请号：US13807134

申请日：2011-06-23

Applicant: Masashi Ikeda ,  Hirotaka Iijima ,  Hisashi Mori

Inventor： Masashi Ikeda ,  Hirotaka Iijima ,  Hisashi Mori

IPC: C09D11/00 ,  C09D11/30 ,  B41J11/00 ,  B41J2/21 ,  C09D11/326 ,  C09D11/38 ,  B41M5/00

CPC classification number: C09D11/30 ,  B41J2/2107 ,  B41J11/002 ,  B41M5/0011 ,  C09D11/326 ,  C09D11/38

Abstract: Disclosed is an aqueous inkjet ink which may contain water, a pigment, an organic or an inorganic acid, an amine, a resin that has a higher pKa than the organic or the inorganic acid, and a cross-linking agent. The aqueous inkjet ink exhibits excellent abrasion resistance even in cases where the drying time is short, while having high bleeding resistance and high storage stability. Also disclosed is a method for forming an inkjet image.

Abstract translation: 公开了一种水性喷墨油墨，其可以含有水，颜料，有机或无机酸，胺，具有比有机或无机酸更高的pKa的树脂和交联剂。 即使在干燥时间短，同时具有高耐渗透性和高储存稳定性的情况下，水性喷墨油墨也显示优异的耐磨性。 还公开了一种形成喷墨图像的方法。

公开(公告)号：US08733922B2

公开(公告)日：2014-05-27

申请号：US13641615

申请日：2011-04-11

Applicant: Makoto Kaga ,  Hirotaka Iijima

Inventor： Makoto Kaga ,  Hirotaka Iijima

IPC: B41J2/01 ,  G01D11/00

CPC classification number: B41M7/0081 ,  B41M7/009 ,  C09D7/43 ,  C09D11/101 ,  C09D11/38

Abstract: Provided is a print preparation method possessing an ejection step in which liquid drops of actinic energy radiation curable type ink-jet ink each containing a polymerizable compound, a photo-polymerizable initiator and a gelling agent are injected from an ink-jet recording head to supply the actinic energy radiation curable type ink-jet ink onto a recording medium, and an actinic energy radiation exposure step, wherein the print preparation method further comprises step (A) in which the recording medium is exposed to electromagnetic waves having a longer wavelength than a wavelength of an absorption wavelength of the photo-polymerization initiator contained in the actinic energy radiation curable type ink-jet ink from a side of a surface on which the image is formed, before conducting the actinic energy radiation exposure step, the print preparation method by which a print having images exhibiting excellent image wear resistance, gloss evenness and image density evenness is provided.

Abstract translation: 提供一种具有喷射步骤的打印制备方法，其中从喷墨记录头喷射各自含有可聚合化合物，光聚合引发剂和胶凝剂的光化能辐射可固化型喷墨油墨的液滴，以供应 光化能量射线固化型喷墨油墨到记录介质上，以及光化能量辐射曝光步骤，其中打印制备方法还包括步骤（A），其中记录介质暴露于波长比 在进行光化能量辐射曝光步骤之前，从形成有图像的表面一侧的光聚合引发剂的光吸收引发剂的吸收波长的波长，印刷准备方法 提供了具有优异的图像耐磨性，光泽均匀性和图像密度均匀性的图像的印刷。

公开(公告)号：US20130106945A1

公开(公告)日：2013-05-02

申请号：US13807134

申请日：2011-06-23

Applicant: Masashi Ikeda ,  Hirotaka Iijima ,  Hisashi Mori

Inventor： Masashi Ikeda ,  Hirotaka Iijima ,  Hisashi Mori

IPC: C09D11/00

CPC classification number: C09D11/30 ,  B41J2/2107 ,  B41J11/002 ,  B41M5/0011 ,  C09D11/326 ,  C09D11/38

Abstract: Disclosed is an aqueous inkjet ink which may contain water, a pigment, an organic or an inorganic acid, an amine, a resin that has a higher pKa than the organic or the inorganic acid, and a cross-linking agent. The aqueous inkjet ink exhibits excellent abrasion resistance even in cases where the drying time is short, while having high bleeding resistance and high storage stability. Also disclosed is a method for forming an inkjet image.

Abstract translation: 公开了一种水性喷墨油墨，其可以含有水，颜料，有机或无机酸，胺，具有比有机或无机酸更高的pKa的树脂和交联剂。 即使在干燥时间短，同时具有高耐渗透性和高储存稳定性的情况下，水性喷墨油墨也显示优异的耐磨性。 还公开了一种形成喷墨图像的方法。

公开(公告)号：US20130038668A1

公开(公告)日：2013-02-14

申请号：US13641615

申请日：2011-04-11

Applicant: Makoto Kaga ,  Hirotaka Iijima

Inventor： Makoto Kaga ,  Hirotaka Iijima

IPC: B41J2/01

CPC classification number: B41M7/0081 ,  B41M7/009 ,  C09D7/43 ,  C09D11/101 ,  C09D11/38

Abstract: Provided is a print preparation method possessing an ejection step in which liquid drops of actinic energy radiation curable type ink-jet ink each containing a polymerizable compound, a photo-polymerizable initiator and a gelling agent are injected from an ink-jet recording head to supply the actinic energy radiation curable type ink-jet ink onto a recording medium, and an actinic energy radiation exposure step, wherein the print preparation method further comprises step (A) in which the recording medium is exposed to electromagnetic waves having a longer wavelength than a wavelength of an absorption wavelength of the photo-polymerization initiator contained in the actinic energy radiation curable type ink-jet ink from a side of a surface on which the image is formed, before conducting the actinic energy radiation exposure step, the print preparation method by which a print having images exhibiting excellent image wear resistance, gloss evenness and image density evenness is provided.

Abstract translation: 提供一种具有喷射步骤的打印制备方法，其中从喷墨记录头喷射各自含有可聚合化合物，光聚合引发剂和胶凝剂的光化能辐射可固化型喷墨油墨的液滴，以供应 光化能量射线固化型喷墨油墨到记录介质上，以及光化能量辐射曝光步骤，其中打印制备方法还包括步骤（A），其中记录介质暴露于波长比 在进行光化能量辐射曝光步骤之前，从形成有图像的表面一侧的光聚合引发剂的光吸收引发剂的吸收波长的波长，印刷准备方法 提供了具有优异的图像耐磨性，光泽均匀性和图像密度均匀性的图像的印刷。