摘要:
The rechargeable lithium battery according to one embodiment includes a negative electrode, a positive electrode, and an electrolyte in a case. The rechargeable lithium battery includes a compound that forms a coordinate covalent bond with anions in at least one of a negative electrode, a positive electrode, an electrolyte, and an inner surface of a case. The rechargeable lithium battery can inhibit electrode corrosion at a high voltage and can be manufactured without requiring additional fabrication processes.
摘要:
The invention relates to an electrolyte for an electrochemical device. This electrolyte includes a first compound that is an ionic metal complex represented by the general formula (1); and at least one compound selected from special second to fourth compounds, fifth to ninth compounds respectively represented by the general formulas Aa+(PF6−)a, Aa+(ClO4−)a, Aa+(BF4−)a, Aa+(AsF6−)a, and Aa+(SbF6−)a, and special tenth to twelfth compounds, The electrolyte is superior in cycle characteristics and shelf life as compared with conventional electrolytes.
摘要:
The invention relates an ionic metal complex represented by the general formula (1): wherein M is an element of groups 3-15 of the periodic table; Aa+ represents a metal ion, onium ion or proton; X1 represents O, S or NR5R6; each of R1 and R2 independently represents H, a halogen, a C1-C10 alkyl group or C1-C10 halogenated alkyl group; R3 represents a C1-C10 alkylene group, C1-C10 halogenated alkylene group, C4-C20 aryl group or C4-C20 halogenated aryl group; R4 represents a halogen, C1-C10 alkyl group, C1-C10 halogenated alkyl group, C4-C20 aryl group, C4-C20 halogenated aryl group or X2R7; X2 represents O, S or NR5R6; each of R5 and R6 represents H or a C1-C10 alkyl group; and R7 represents a C1-C10 alkyl group, C1-C10 halogenated alkyl group, C4-C20 aryl group or C4-C20 halogenated aryl group. The ionic metal complex can be used as a supporting electrolyte for electrochemical devices, a polymerization catalyst of polyolefins and so forth, or a catalyst for organic synthesis.
摘要:
The invention relates to a method for producing a sulfonimide or its alkali metal salt. The method includes the steps of (a) reacting a precursory salt of the sulfonimide with a base contained in a basic aqueous solution, thereby producing a first aqueous solution containing the alkali metal salt and an amine; (b) removing the amine from the first aqueous solution to obtain a second aqueous solution containing the alkali metal salt; and (c) crystallizing the alkali metal salt in the second aqueous solution. The base is potassium hydroxide, sodium hydroxide or lithium hydroxide. The base is added to the second aqueous solution to generate the crystallization. The precursory salt is formed when the sulfonimide is reacted with a tertiary amine or a heterocyclic amine. The alkali metal salt is produced easily and economically in an industrial scale production with high purity and high yield.
摘要:
A separator for a rechargeable lithium battery include a substrate including a plurality of first pores and a porous layer on the substrate, the porous layer including a plurality of second pores, the second pores having a larger average size than the first pores. A rechargeable lithium battery may include the separator.
摘要:
The invention relates to an electrolyte for an electrochemical device. This electrolyte includes a first compound that is an ionic metal complex represented by the general formula (1); and at least one compound selected from special second to fourth compounds, fifth to ninth compounds respectively represented by the general formulas Aa+(PF6−)a, Aa+(ClO4−)a, Aa+(BF4−)a, Aa+(AsF6−)a, and Aa+(SbF6−)a, and special tenth to twelfth compounds, The electrolyte is superior in cycle characteristics and shelf life as compared with conventional electrolytes.
摘要:
The invention relates to an electrolyte for an electrochemical device. This electrolyte includes an ionic metal complex represented by the general formula (1): wherein M is an element of groups 3-15 of the periodic table; Aa+ represents a metal ion, onium ion or proton; X1 represents O, S or NR5R6; each of R1 and R2 independently represents H, a halogen, a C1-C10 alkyl group or C1-C10 halogenated alkyl group; R3 represents a C1-C10 alkylene group, C1-C10 halogenated alkylene group, C4-C20 aryl group or C4-C20 halogenated aryl group; R4 represents a halogen, C1-C10 alkyl group, C1-C10 halogenated alkyl group, C4-C20 aryl group, C4-C20 halogenated aryl group or X2R7; X2 represents O, S or NR5R6; each of R5 and R6 represents H or a C1-C10 alkyl group; and R7 represents a C1-C10 alkyl group, C1-C10 halogenated alkyl group, C4-C20 aryl group or C4-C20 halogenated aryl group. The electrolyte has high heat resistance and hydrolysis resistance as compared with conventional electrolytes.
摘要:
A disassembly procedure of a fuel cell places a sloped edge of a cracking tool on a bottom of a recess. The bottom of the recess as a point of application, an opening edge of the recess where a flat side of the cracking tool is placed, is a point of support, and force is applied at a base end of the cracking tool. Leverage is applied to the point of application by an external force creating a crack starts in a separator. The crack goes from the point of application toward a position outside electrodes of an MEA (membrane electrode assembly) but inside sealing members. The procedure then removes the broken separator to expose the MEA outside and cuts off an electrolyte membrane along a cut line CL outside the electrodes but inside the sealing members.
摘要:
A disassembly procedure of a fuel cell 10 first provides a cracking tool 12 having a sloped edge and places the sloped edge of the cracking tool 12 on a bottom of a recess 11. The disassembly procedure subsequently sets the bottom of the recess 11 where the sloped edge of the cracking tool 12 is placed, as a point of application, an opening edge of the recess 11 where a flat side of the cracking tool 12 is placed, as a point of support, and a base end of the cracking tool 12 where a force is applied, as a point of power, and applies an external force to the point of application by the principle of leverage. A crack starts from the point of application in a separator 6. The crack goes from the point of application toward a position outside electrodes 4 and 5 of an MEA (membrane electrode assembly) 2 but inside sealing members 8. The procedure then removes the broken separator 6 to expose the MEA 2 outside and cuts off an electrolyte membrane 3 along a cut line CL outside the electrodes 4 and 5 but inside the sealing members 8.
摘要:
The invention relates to a process for synthesizing an ionic metal complex represented by the general formula (1) or (5). This process includes reacting in an organic solvent a compound (corresponding to ligand of the complex) represented by the general formula (2) or (6) with a halogen-containing compound represented by the general formula (3) or (4), in the presence of a reaction aid containing an element selected from the group consisting of elements of groups 1-4 and 11-14 of the periodic table. It is possible by this process to easily and efficiently synthesize the ionic metal complex, which can be used as a supporting electrolyte for electrochemical devices, a polymerization catalyst of polyolefins and so forth, or a catalyst for organic synthesis.