摘要:
The present invention relates to a process for preparing polyether polyols, in which at least one hydroxyl-comprising fatty acid ester and/or at least one hydroxyl-modified fatty acid ester is reacted with the aid of a double metal cyanide catalyst in at least two process sections with in each case a mixture of ethylene oxide and at least one further alkylene oxide different from ethylene oxide.
摘要:
The invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein a mixture of bi) from 25 to 70% by weight, based on the weight of the components bi), bii), biii) and biv), of a hydroxyl-comprising natural oil or fat or a reaction product of a hydroxyl-comprising natural oil or fat with alkylene oxides, bii) from 3 to 30% by weight, based on the weight of the components bi), bii), biii) and biv), of at least one polyether alcohol which has a hydroxyl number of from 100 to 800 mg KOH/g and a functionality of from 3 to 5 and is selected from the group consisting of polyether alcohols prepared by addition of alkylene oxides onto an amine, biii) 20-50% by weight, based on the weight of the components bi), bii), biii) and biv), of at least one polyether alcohol which has a hydroxyl number of from 10 to 80 mg KOH/g and a functionality of from 2 to 5 and can be prepared by addition of ethylene oxide and propylene oxide onto H-functional starter substances, where the proportion of ethylene oxide is 5-25% by weight, based on the weight of the polyether alcohol, and at least part of the ethylene oxide is added on at the end of the polyether chain, biv) >0-8% by weight, based on the weight of the components bi), bii), biii) and biv), of at least one polyether alcohol having a functionality of 2-4, a hydroxyl number of 15-60 mg KOH/g and a content of ethylene oxide of >50% by weight, based on the weight of the polyether alcohol, as compounds having at least two hydrogen atoms which are reactive toward isocyanate groups.
摘要:
Polyurethane foams having a density of less than 200 g/l are prepared by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms reactive with isocyanate groups, the polyisocyanates a) being aromatic di- or polyisocyanates and the compounds b) having at least two hydrogen atoms reactive with isocyanate groups containing at least one acrylate polyol.
摘要:
Reticulated flexible polyurethane foams are prepared by reacting organic and/or modified organic polyisocyanates (a) with a polyetherol mixture (b) and, if required, further compounds (c) having hydrogen atoms reactive toward isocyanates, in the presence of water and/or other blowing agents (d), catalysts (e) and further assistants and additives (f), by a process in which the polyetherol mixture (b) comprises b1) at least one difunctional or polyfunctional polyetherol having an OH number of from 20 to 150 mg KOH/g, based on propylene oxide and/or butylene oxide and ethylene oxide and having an ethylene oxide content of more than 40% by weight, based on the total amount of alkylene oxide used, (b1.1) and, if required, further difunctional or polyfunctional polyetherols having an OH number of from 20 to 150 mg KOH/g, based on propylene oxide and/or butylene oxide and ethylene oxide and having an ethylene oxide content of not more than 40% by weight, based on the total amount of alkylene oxide used, which have a content of primary OH groups of more than 40%, (b1.2), with total amounts of the component (b1) of at least 70% by weight, based on the total weight of the component (b), (b1.1) being present in amounts of at least 50% by weight, based on the total weight of the component (b), and b2) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and having an OH number of more than 25 mg KOH/g, in amounts of not more than 30% by weight, based on the total weight of the component (b), and silicone stabilizers are used in amounts of from 0.02 to 5% by weight, based on the total weight of the components (b) to f). The reticulated flexible polyurethane foams themselves prepared in this manner are used for upholstery purposes, for cavity filling and as support medium and filter medium.
摘要:
A process for the preparation of flame-resistant soft polyurethane foams which produce less smoke in the event of fire involves reacting a) an organic polyisocyanate and/or a modified organic polyisocyanate with b) a high-molecular-weight compound containing at least two reactive hydrogen atoms and, if desired, c) a chain extender and/or crosslinking agent, in the presence of d) a mixture of flameproofing agents which contains: di) melamine dii) expandable graphite and, if desired, diii) at least one further flameproofing agent, preferably a modified or unmodified ammonium polyphosphate, e) a blowing agent, f) a catalyst and, if desired, g) assistants and/or additives, and melamine/expandable graphite/polyether-polyol dispersions which are suitable for this purpose.
摘要:
The invention relates to a process for the preparation of CFC-free, flexible polyurethane foams or molded foams by reactingA) liquid polyisocyanate mixtures containing bonded urethane groups and having a content of NCO groups of from 20 to 30% by weight, these mixtures themselves being prepared by reacting a mixture of diphenylmethane diisocyanates and polyphenyl-polymethylene polyisocyanates (crude diphenylmethane diisocyanate) with a polyether-polyol mixture, having a hydroxyl number of from 120 to 25, of at least one polyoxypropylene glycol and at least one trifunctional polyoxypropylene-polyoxyethylene glycol having a content of ethylene oxide units of from 90 to 10% by weight or by reacting 4,4'-diphenylmethane diisocyanate (diphenylmethyl diisocyanate) or an diphenylmethane diisocyanate isomer mixture with said polyether-polyol mixture to give an NCO-containing quasi-prepolymer and diluting this quasi-prepolymer with crude diphenylmethane diisocyanate, withB) relatively high-molecular-weight polyhydroxyl compounds.
摘要:
The invention provides a method for the preparation of fluorochlorohydrocarbon(FCHC)-free polyurethane soft (molded) foam materials with low density, by reactingA) liquid polyisocyanate mixtures containing bound urethane groups, containing 22 to 30 weight percent of NCO groups, which in turn are prepared by reacting a mixture of diphenylmethane-diisocyanate and polyphenyl-polymethylene-polyisocyanates (raw MDI) with at least one polyoxypropylene-polyoxyethylene-polyol with a functionality between 2.5 and 3.5, a hydroxyl number between 50 and 90 and a polymerized ethylene oxide group concentration ranging from more than 30 to less than 50 weight percent, relative to the weight of the polymerized ethylene oxide and 1,2 propylene oxide groups, or by reacting of 4,4'diphenylmethane-diisocyanate (MDI) or and MDI-isomeric mixture with the above-named polyoxypropylene-polyoxyethylene-polyol to an NCO-group-containing quasi-prepolymer, and diluting this quasi-prepolymer with raw-MDI, withB) higher-molecular polyhydroxyl compounds and, if appropriateC) low-molecular chain lengthening and/or cross-linkage-promoting materialsD) propellants,E) catalysts as well as if appropriate,F) auxiliary materials and/or additives, as well as the polyisocyanate mixtures modified with urethane groups (A) which are utilizable in accordance with the process of the invention.
摘要:
The invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, c) blowing agents, wherein the compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b) comprise b1) from 0 to 90 parts by weight of at least one polyether alcohol consisting of exclusively propylene oxide units or propylene oxide units and not more than 50% by weight, based on the total weight of the alkylene oxides used, of ethylene oxide units in the polyether chain and having a nominal functionality of from 3 to 8 and a hydroxyl number in the range from 100 to 350 mg KOH/g, and b2) from 10 to 100 parts by weight of at least one graft polyol which can be prepared by in-situ polymerization of olefinically unsaturated monomers in at least one polyether alcohol which has exclusively propylene oxide units or propylene oxide units and not more than 50% by weight, based on the total amount of alkylene oxides used, of ethylene oxide units in the polyether chain, a nominal functionality of from 2 to 8 and a hydroxyl number in the range from 100 to 350 mg KOH/g, having a solids content of not more than 60% by weight, based on the total amount of polyols and solids used, where the sum of the parts by weight of b1) and b2) is 100.
摘要:
Invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein as b) a mixture of bi) from 25 to 70% by weight of a hydroxyl-comprising natural oil or fat or a reaction product of a hydroxyl-comprising natural oil or fat with alkylene oxides, bii) from 3 to 30% by weight of at least one polyether having a hydroxyl number of from 100 to 800 mg KOH/g and a functionality of 3-5 selected from the group consisting of polyether prepared by addition of alkylene oxides onto an amine, biii) 20-50% by weight of at least one polyether alcohol having a hydroxyl number of from 10 to 80 mg KOH/g and a functionality of 2-5, where the proportion of ethylene oxide is 5-25% by weight, based on the weight of the polyether alcohol, and at least part of the ethylene oxide is added on at the end of the polyether chain, biv) >0-8% by weight of at least one polyether alcohol having a functionality of 2-4, a hydroxyl number of 15-60 mg KOH/g and a content of ethylene oxide of >50% by weight of the polyether alcohol is used.
摘要:
The invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, c) blowing agents, wherein the compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b) comprise b1) from 70 to 10 parts by weight of at least one polyether alcohol consisting of exclusively polyoxypropylene units or polyoxypropylene units and not more than 20% by weight, based on the total weight of the alkylene oxides used, of polyoxyethylene units in the polyether chain and having a nominal functionality of from 3 to 6 and a hydroxyl number in the range from 100 to 300 mg KOH/g, b2) from 10 to 70 parts by weight of at least one polyetherol consisting of exclusively polyoxypropylene units or polyoxypropylene units and not more than 20% by weight, based on the total amount of alkylene oxides used, of polyoxyethylene units in the polyether chain and having a nominal functionality of 2 and a hydroxyl number in the range from 50 to 350 mg KOH/g, b3) from 10 to 30 parts by weight of at least one polyether alcohol consisting of exclusively ethylene oxide units or ethylene oxide units and not more than 20% by weight, based on the total amount of alkylene oxides used, of polyoxypropylene units in the polyether chain and having a nominal functionality of from 2 to 3 and a hydroxyl number in the range from 50 to 550 mg KOH/g, b4) from 0 to 20 parts by weight of at least one graft polyetherol which can be prepared by in-situ polymerization of olefinically unsaturated monomers in a polyether alcohol consisting of polyoxypropylene units or polyoxypropylene units and not more than 50% by weight, based on the total amount of alkylene oxides used, of polyoxyethylene units in the polyether chain and having a nominal functionality of from 2 to 3 and a hydroxyl number in the range from 20 to 40 mg KOH/g.