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1.发明申请PROCESS FOR THE MANUFACTURE OF A 1,2-EPOXIDE AND A DEVICE FOR CARRYING OUT SAID PROCESS 有权1,2-环氧化物的制造方法和实施方法的装置公开(公告)号：US20130023680A1
公开(公告)日：2013-01-24
申请号：US13574715
申请日：2011-01-26
申请人： Prasad Muppa , Ron Postma , Bart Van Den Berg , Juergen Stock , Holger Wiederhold , Hans Rausch , Jorg Schallenberg , Stefan Bernhardt
发明人： Prasad Muppa , Ron Postma , Bart Van Den Berg , Juergen Stock , Holger Wiederhold , Hans Rausch , Jorg Schallenberg , Stefan Bernhardt
IPC分类号： C07D301/12 , C07D301/03 , B01J19/00
CPC分类号： C07D301/14 , B01D17/0208 , B01F5/061 , B01J4/00 , B01J19/2435 , B01J2219/00094 , B01J2231/72 , C07D301/03 , C07D301/12 , Y02P20/582
摘要： Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.
摘要翻译： 提供了用于形成环氧化合物的装置和方法。 在一个实施方案中，提供了制备环氧化物的方法，包括加入氧化剂，水溶性锰络合物和末端烯烃以形成多相反应混合物，使末端烯烃与氧化剂在多相反应混合物中反应，所述多相反应混合物具有 在水溶性锰络合物的存在下的至少一个有机相，将反应混合物分离成至少一个有机相和水相，并重新使用至少部分水相。 本发明还涉及用于执行上述过程的装置。
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公开(公告)号：US20090036619A1
公开(公告)日：2009-02-05
申请号：US12221234
申请日：2008-07-31
CPC分类号： C08F110/06 , C08F4/65912 , C08F10/06 , C08F4/65927 , C08F2500/02 , C08F2500/03 , C08F2500/23
摘要： Polypropylene wax having a) a dropping or softening point determined by the ring/ball method of greater than 155° C., b) heats of fusion greater than 80 J/g and c) a DSC melting point of >155° C. The waxes of the invention are prepared by reaction of propylene with metallocene compounds at temperatures in the range from 40 to 140° C. and an olefin partial pressure in the range from 1 to 50 bar in the presence of a cocatalyst. They have a content of unsaturated chain ends of less than 10%. They can, for example, be modified by means of a free-radical grafting reaction with polar monomers and are, for example, suitable in unmodified form as dispersants for pigments, as additive in printing inks and surface coatings or toners or in modified form for producing aqueous dispersions or as bonding agents and compatibilizers in plastic compounds.
摘要翻译： 聚丙烯蜡，其具有a）通过环/球法测定的滴定或软化点大于155℃，b）大于80J / g的熔融热，c）DSC熔点> 155℃。 在助催化剂存在下，通过丙烯与金属茂化合物在40〜140℃的温度和1〜50巴的烯烃分压反应制备本发明的蜡。 它们的不饱和链端含量小于10％。 它们可以例如通过与极性单体的自由基接枝反应进行改性，并且例如适合于未改性形式作为颜料的分散剂，作为印刷油墨和表面涂料或调色剂中的添加剂或以改性形式用于 生产水分散体或作为粘合剂和增塑剂在塑料化合物中。
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3.发明授权Process for the manufacture of a 1,2-epoxide and a device for carrying out said process 有权用于制造1,2-环氧化物的方法和用于进行所述方法的装置公开(公告)号：US08859790B2
公开(公告)日：2014-10-14
申请号：US13574715
申请日：2011-01-26
申请人： Prasad Muppa , Ron Postma , Bart Van Den Berg , Juergen Stock , Holger Wiederhold , Hans Rausch , Jorg Schallenberg , Stefan Bernhardt
发明人： Prasad Muppa , Ron Postma , Bart Van Den Berg , Juergen Stock , Holger Wiederhold , Hans Rausch , Jorg Schallenberg , Stefan Bernhardt
IPC分类号： C07D301/12 , B01J23/32 , B01J27/24 , B01D17/02 , B01J19/24 , C07D301/03 , B01J4/00 , B01F5/06
CPC分类号： C07D301/14 , B01D17/0208 , B01F5/061 , B01J4/00 , B01J19/2435 , B01J2219/00094 , B01J2231/72 , C07D301/03 , C07D301/12 , Y02P20/582
摘要： Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.
摘要翻译： 提供了用于形成环氧化合物的装置和方法。 在一个实施方案中，提供了制备环氧化物的方法，包括加入氧化剂，水溶性锰络合物和末端烯烃以形成多相反应混合物，使末端烯烃与氧化剂在多相反应混合物中反应，所述多相反应混合物具有 在水溶性锰络合物的存在下的至少一个有机相，将反应混合物分离成至少一个有机相和水相，并重新使用至少部分水相。 本发明还涉及用于执行上述过程的装置。
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