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    METAL ALKYL-ARENES AND PROCESSES FOR THE PREPARATION THEREOF
    3.
    发明申请
    METAL ALKYL-ARENES AND PROCESSES FOR THE PREPARATION THEREOF 有权
    金属碱金属及其制备方法

    公开(公告)号：US20130296592A1

    公开(公告)日：2013-11-07

    申请号：US13996842

    申请日：2011-12-23

    Applicant: Guido Pampaloni ,  Filippo Renili ,  Anna Sommazzi ,  Fabio Marchetti ,  Francesco Masi ,  Mario Polesello

    Inventor： Guido Pampaloni ,  Filippo Renili ,  Anna Sommazzi ,  Fabio Marchetti ,  Francesco Masi ,  Mario Polesello

    IPC: C07F19/00

    CPC classification number: C07F19/00 ,  B01J31/122 ,  C07F7/003 ,  C08F4/42 ,  C08F10/00 ,  C08F4/659

    Abstract: Metal alkyl-arene having general formula (I) or (Ia): M (η6-arene)2Al1XrRs (I) M (η6-arene)AlqXrRs (Ia) wherein: —M represents zirconium (Zr), hafnium (Hf), or mixtures thereof, preferably zirconium; —arene represents a benzene, or a benzene 10 substituted with from 1 to 6 linear or branched C1-C6 alkyl groups, or mixtures thereof; —X represents a halogen atom selected from chlorine, bromine, fluorine, iodine, preferably chlorine; —R represents a linear or branched C1-C15 alkyl group; —q is a number ranging from 2 to 6, preferably 3 for a metal alkyl-arene having general formula (I), 2 for a metal alkyl-arene having general formula (Ia); —r is a number ranging from 1 to 20, preferably 9 for a metal alkyl-arene having general formula (I), 6 for a metal alkyl-arene having general formula (Ia); —s is a number ranging from 1 to 6, preferably 2. Said metal alkyl-arene can be advantageously used for the preparation of solid components of catalysts for the (co)polymerization of α-olefins.

    Abstract translation: 具有通式（I）或（Ia）的金属烷基芳烃：M（eta6-芳烃）2Al1XrRs（I）M（eta6-芳烃）AlqXrRs（Ia）其中：-M代表锆（Zr），铪（Hf） 或其混合物，优选锆; 芳烃代表苯，或被1至6个直链或支链C 1 -C 6烷基取代的苯10，或其混合物; -X表示选自氯，溴，氟，碘，优选氯的卤素原子; -R表示直链或支链的C 1 -C 15烷基; 对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，-q为2至6的数，优选3。 对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，-r为1至20，优选9。 -s是1至6的数，优选2.所述金属烷基芳烃可有利地用于制备用于α-烯烃的（共）聚合的催化剂的固体组分。

    Catalytic composition for the (co) polymerization of &agr;-olefins
    6.
    发明授权
    Catalytic composition for the (co) polymerization of &agr;-olefins 有权
    α-烯烃（共）聚合的催化组合物

    公开(公告)号：US06831034B2

    公开(公告)日：2004-12-14

    申请号：US10670211

    申请日：2003-09-26

    Applicant: Francesco Masi ,  Anna Sommazzi ,  Roberto Santi

    Inventor： Francesco Masi ,  Anna Sommazzi ,  Roberto Santi

    IPC: C08F464

    CPC classification number: C08F10/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65925 ,  C08F4/6592 ,  C08F4/65927 ,  C08F4/76 ,  C08F2500/03 ,  C08F210/14

    Abstract: Catalytic composition for the (co)polymerization of ethylene and other &agr;-olefins, including a metallocene complex of a metal M of group 4 of the periodic table or the product obtainable from the same combined with a suitable activator, wherein said metallocene complex includes at least one cyclopentadienyl group and at least one unsaturated hydrocarbyl organic group bonded to the metal M, having the following formula (I): -(AxDyUz)RI  (I) wherein: A represents any monomeric unit deriving from a vinylaromatic group polymerizable by means of anionic polymerization, having from 6 to 20 carbon atoms; D represents any monomeric unit deriving from a conjugated diolefin polymerizable by means of anionic polymerization, having from 4 to 20 carbon atoms; U represents any generic optional monomeric unit deriving from an unsaturated compound co-polymerizable with any of the above conjugated diolefins D or vinylaromatic compounds A; RI represents hydrogen or a hydrocarbyl group having from 1 to 20 carbon atoms, each index “x” and “y” can be independently zero or an integer, provided the sum (x+y) is equal to or higher than 2, preferably between 2 and 50, more preferably between 2 and 25; “z” can be zero or an integer ranging from 1 to 20.

    Abstract translation: 乙烯和其它α-烯烃（包括周期表第4族金属M的茂金属络合物）的共聚合的催化组合物或其合适的活化剂得到的产物，其中所述茂金属络合物包括在 至少一个环戊二烯基和至少一个与金属M键合的不饱和烃基有机基团，具有下式（I）：其中：A表示衍生自通过阴离子聚合可聚合的乙烯基芳族基团的任何单体单元，其具有6至20个 碳原子; D表示衍生自具有4至20个碳原子的通过阴离子聚合可共聚的共轭二烯烃的任何单体单元; U表示衍生自与任何上述共轭二烯烃共聚的不饱和化合物的任何通用任选的单体单元 D或乙烯基芳族化合物A; R 1表示氢或具有1至20个碳原子的烃基，ea 如果和（x + y）等于或高于2，优选在2和50之间，更优选在2和25之间，则ch指数“x”和“y”可以独立地为零或整数，“z” 为零或整数范围从1到20。

    Metal complexes comprising a 2,6-diacylpyridine-ligand and their use in the polymerization of ethylene
    7.
    发明授权
    Metal complexes comprising a 2,6-diacylpyridine-ligand and their use in the polymerization of ethylene 有权
    包含2,6-二酰基吡啶 - 配体的金属络合物及其在乙烯聚合中的用途

    公开(公告)号：US06780947B1

    公开(公告)日：2004-08-24

    申请号：US10048921

    申请日：2002-06-12

    Applicant: Anna Sommazzi ,  Barbara Milani ,  Antonio Proto ,  Gianni Corso ,  Giovanni Mestroni ,  Francesco Masi

    Inventor： Anna Sommazzi ,  Barbara Milani ,  Antonio Proto ,  Gianni Corso ,  Giovanni Mestroni ,  Francesco Masi

    IPC: C08F452

    CPC classification number: C07D213/53 ,  C07F15/025 ,  C07F15/065 ,  C08F10/00 ,  C08F4/7044

    Abstract: Organometallic complex having the formula (IAP)M(X)n which can be used for die formation of catalytic systems wherein: M is a metal selected from transition metals and lanthanides, in oxidation state “s” positive and different from zero; each X is independently a group of an anionic nature bound to the metal as an anion in an ionic couple or with a convalent bond of the “&sgr;” type; “n” expresses the number of X groups sufficient for neutralizing the formal “+s” charge of the metal M, and (IAP) represents a neutral bond consisting of a mono-imine of 2,6-diacylpyridine. Said complex is prepared with relatively simple methods and can be used, combined with a suitable co-catalyst, such as for example, an aluminoxane, as a catalyst in normal (co)polymerization processes of &agr;-olefins, and especially ethylene.

    Abstract translation: 具有式（IAP）M（X）n的有机金属络合物，其可用于催化体系的模具形成，其中：M为选自过渡金属和镧系元素的金属，氧化态为“正”且不同于零; 每个X独立地是在离子对中或与“σ”型的共价键作为阴离子结合金属的阴离子性基团; “n”表示足以中和金属M的正式“+ s”电荷的X基团的数目，（IAP）表示由2,6-二酰基吡啶的单亚胺组成的中性键。 所述络合物以相对简单的方法制备，并且可以与合适的助催化剂（例如铝氧烷）一起使用，作为α-烯烃，特别是乙烯的正常（共）聚合方法中的催化剂。

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