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公开(公告)号：US07235595B2
公开(公告)日：2007-06-26
申请号：US10910212
申请日：2004-08-03
IPC分类号： F21V7/22
CPC分类号： C09D5/004 , C08F265/04 , C08F265/06 , C08F291/00 , C09D151/003 , C08F212/08 , C08F2/22 , C08L2666/04
摘要： An aqueous traffic paint including hard-soft polymer particles, polyfunctional amine, and volatile base is provided. The hard-soft polymer particles, which contain soft polymer and hard polymer, have a hydrophobicity characterized by a Hansch parameter of at least 3. Also provided is a method of producing a traffic marking on a road surface using the aqueous paint. The aqueous traffic paint is suitable for application to road surfaces, including oily road surfaces, and may be applied at temperatures below 15° C.
摘要翻译： 提供了包含硬质聚合物颗粒，多官能胺和挥发性碱的含水交通漆。 包含软聚合物和硬聚合物的硬质聚合物颗粒具有由Hansch参数至少为3表征的疏水性。还提供了使用水性涂料在路面上生成交通标记的方法。 含水交通漆适用于路面，包括油性路面，可在低于15°C的温度下使用
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2.发明授权Polyurethane coating compositions comprising isocyanurate compositions from bis(isocyanatomethyl) cyclohexane and tertiary amine catalysts 有权包含来自双（异氰酸甲酯基）环己烷和叔胺催化剂的异氰脲酸酯组合物的聚氨酯涂料组合物公开(公告)号：US08841380B2
公开(公告)日：2014-09-23
申请号：US13297499
申请日：2011-11-16
申请人： Donald C. Schall , Jia Tang
发明人： Donald C. Schall , Jia Tang
IPC分类号： C08F8/30 , C08F20/00 , C08G18/00 , C08G18/08 , C08G18/18 , C08G18/20 , C08G18/22 , C08G18/28 , C08G63/00 , C08G73/00 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/163 , C08G18/1808 , C08G18/1816 , C08G18/2063 , C08G18/222 , C08G18/6216 , C08G18/792 , C09D175/04
摘要： The present invention provides high solids, two-component polyurethane compositions comprising, as one component, polyisocyanate compositions having one or more isocyanurate made from bis(isocyanatomethyl)-cyclohexane, as a second component, one or more high solids polyol, and in either component, one or more tertiary amine catalyst. Optionally, the compositions further comprise one or more zinc amine catalyst. The compositions provide coatings, which exhibit an excellent balance of pot life and dry to touch or tack free time, as well as early rain resistance and hardness, while enabling a lower volatile organic content (VOC) of the compositions for comparable performance.
摘要翻译： 本发明提供了高固含量的双组分聚氨酯组合物，其包含作为一种组分的具有一种或多种由双（异氰酸酯基甲基） - 环己烷，作为第二组分，一种或多种高固含量多元醇制成的异氰脲酸酯的多异氰酸酯组合物， ，一种或多种叔胺催化剂。 任选地，组合物还包含一种或多种锌胺催化剂。 组合物提供涂层，其表现出适用期的平衡以及干触摸或无粘性时间，以及早期耐雨性和硬度，同时使组合物的挥发性有机成分（VOC）具有相当的性能。
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3.发明授权Two component polyurethane coating compositions comprising isocyanurate compositions from bis(isocyanatomethyl) cyclohexane and from aliphatic diisocyanates 有权包含来自双（异氰酸甲酯基）环己烷和脂族二异氰酸酯的异氰脲酸酯组合物的双组分聚氨酯涂料组合物公开(公告)号：US08802771B2
公开(公告)日：2014-08-12
申请号：US13297388
申请日：2011-11-16
申请人： John N. Argyropoulos , Debkumar Bhattacharjee , Donald C. Schall , Allen Xu , Aaron Yang , Louie Luo
发明人： John N. Argyropoulos , Debkumar Bhattacharjee , Donald C. Schall , Allen Xu , Aaron Yang , Louie Luo
CPC分类号： C09D175/06 , C08G18/022 , C08G18/1875 , C08G18/36 , C08G18/4063 , C08G18/4277 , C08G18/4288 , C08G18/6216 , C08G18/6659 , C08G18/722 , C08G18/757 , C08G18/792
摘要： The present invention provides two-component polyurethane compositions comprising, as one component, polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane or, preferably, a mixture of two or more of these, and of the isocyanurate of hexamethylene diisocyanate (HDI trimer), and, as the other component, a mix of a soft polyol having a hydroxyl functionality of from 2.5 to 5.0 and a molecular weight of from 500 to 3,000, and a hard polyol. Such compositions provide coatings, especially clear topcoats, which exhibit excellent scratch and mar and solvent resistance in addition to a good balance of hardness and flexibility without the need for increasing the volatile organic content (VOC) of the compositions. Also provided are compositions of a polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane with soft polyol which have lower VOCs.
摘要翻译： 本发明提供双组分聚氨酯组合物，其包含作为一种组分的一种或多种双（异氰酸甲酯基）环己烷的异氰脲酸酯的多异氰酸酯组合物，或优选其两种或更多种的混合物和六亚甲基二异氰酸酯的异氰脲酸酯（ HDI三聚体），作为另一组分，具有羟基官能度为2.5至5.0，分子量为500至3,000的软多元醇和硬多元醇的混合物。 这种组合物提供除了硬度和柔性的良好平衡之外还具有优异的耐擦伤性和抗溶剂性的涂层，特别是透明的面漆，而不需要增加组合物的挥发性有机物含量（VOC）。 还提供了一种或多种双（异氰酸甲酯基）环己烷与具有较低VOC的软多元醇的异氰脲酸酯的多异氰酸酯组合物的组合物。
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4.发明申请TWO COMPONENT POLYURETHANE COATING COMPOSITIONS COMPRISING ISOCYANURATE COMPOSITIONS FROM BIS(ISOCYANATOMETHYL) CYCLOHEXANE AND FROM ALIPHATIC DIISOCYANATES 有权两种组分聚氨酯涂料组合物，其包含来自BIS（异氰酸酯基）环己烷和来自二异氰酸酯的异氰酸酯组合物公开(公告)号：US20120130016A1
公开(公告)日：2012-05-24
申请号：US13297388
申请日：2011-11-16
申请人： John N. ARGYROPOULOS , Debkumar BHATTACHARJEE , Donald C. SCHALL , Allen XU , Aaron YANG , Louie LUO
发明人： John N. ARGYROPOULOS , Debkumar BHATTACHARJEE , Donald C. SCHALL , Allen XU , Aaron YANG , Louie LUO
IPC分类号： C09D175/06 , C09D175/04
CPC分类号： C09D175/06 , C08G18/022 , C08G18/1875 , C08G18/36 , C08G18/4063 , C08G18/4277 , C08G18/4288 , C08G18/6216 , C08G18/6659 , C08G18/722 , C08G18/757 , C08G18/792
摘要： The present invention provides two-component polyurethane compositions comprising, as one component, polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane or, preferably, a mixture of two or more of these, and of the isocyanurate of hexamethylene diisocyanate (HDI trimer), and, as the other component, a mix of a soft polyol having a hydroxyl functionality of from 2.5 to 5.0 and a molecular weight of from 500 to 3,000, and a hard polyol. Such compositions provide coatings, especially clear topcoats, which exhibit excellent scratch and mar and solvent resistance in addition to a good balance of hardness and flexibility without the need for increasing the volatile organic content (VOC) of the compositions. Also provided are compositions of a polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane with soft polyol which have lower VOCs.
摘要翻译： 本发明提供双组分聚氨酯组合物，其包含作为一种组分的一种或多种双（异氰酸甲酯基）环己烷的异氰脲酸酯的多异氰酸酯组合物，或优选其两种或更多种的混合物和六亚甲基二异氰酸酯的异氰脲酸酯（ HDI三聚体），作为另一组分，具有羟基官能度为2.5至5.0，分子量为500至3,000的软多元醇和硬多元醇的混合物。 这种组合物提供除了硬度和柔性的良好平衡之外还具有优异的耐擦伤性和抗溶剂性的涂层，特别是透明的面漆，而不需要增加组合物的挥发性有机物含量（VOC）。 还提供了一种或多种双（异氰酸甲酯基）环己烷与具有较低VOC的软多元醇的异氰脲酸酯的多异氰酸酯组合物的组合物。
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5.发明申请High PVC Fast-Drying Aqueous Binder Compositions With Small Particle Binders And Traffic Markings Made Therewith 审中-公开高PVC快干干燥水性粘合剂组合物与小颗粒粘合剂和交通标记公开(公告)号：US20110136936A1
公开(公告)日：2011-06-09
申请号：US12956001
申请日：2010-11-30
CPC分类号： C09D5/004 , C09D5/02 , C09D133/16 , C08L33/14
摘要： The present invention provides fast dry binder compositions comprising one or more anionically stabilized emulsion polymer having a weight average particle size of from 100 to 165 nm, one or more polyamine, one or more volatile base and one or more filler, extender and/or pigment in a composition having a % PVC of from 63 to 80. The invention provides surprisingly stable fast dry binder compositions for such a high extender or filler loading and the compositions dry far faster than binders made with waterborne polymers having a larger particle size. The invention provides high performance traffic paints at a reduced cost in use and coated substrates, such as traffic markings or exterior insulation finishes (EIFS).
摘要翻译： 本发明提供快速干粘合剂组合物，其包含一种或多种重均粒径为100至165nm的阴离子稳定的乳液聚合物，一种或多种多胺，一种或多种挥发性碱和一种或多种填料，增量剂和/或颜料 在具有63至80的％PVC的组合物中。本发明提供令人惊奇的稳定的快速干燥粘合剂组合物用于这种高增量剂或填料负载，并且组合物比具有较大粒度的水性聚合物制备的粘合剂干得更快。 本发明以降低的使用成本和涂覆的基底（例如交通标记或外部绝缘整理剂（EIFS））提供高性能交通涂料。
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6.发明申请Methods for making composites having thermoplastic properties from recycled crosslinked polymer 有权从循环交联聚合物制备具有热塑性的复合材料的方法公开(公告)号：US20100009152A1
公开(公告)日：2010-01-14
申请号：US12456473
申请日：2009-06-17
CPC分类号： C08J3/16 , C08C1/14 , C08F6/22 , C08J11/06 , C08J2300/30 , C08J2319/00 , C08J2321/00 , C08L19/003 , C08L33/12 , C08L101/02 , Y02W30/701 , Y10T428/24355 , Y10T428/24405 , Y10T428/269 , C08L2666/04
摘要： The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 μm or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 μm in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials. In one embodiment, the sheets and films can be formed into laminates.
摘要翻译： 本发明提供了以细碎材料或制品形式制造可成形复合材料的方法，以及通过该方法生产的材料和制品，所述方法包括通过（i）处理水性热塑性丙烯酸或乙烯基聚合物以增加粒径来形成混合物 的重量平均粒径为1μm以上，任选地脱水以形成碎屑混合物; 和（ii）将热塑性丙烯酸或乙烯基聚合物与一种或多种具有10至600μm的筛粒度的废橡胶硫化橡胶组合，其量为15至95重量％。 ％，基于聚合物和橡胶的总重量以形成碎屑浆料，使得（ii）可以在（i）之前，之后，但在任何脱水之前，或在任何脱水之后进行; 和（iii）热塑性加工混合物。 热塑性加工可以直接形成制品，如片材或薄膜。 可塑性复合材料对其他材料具有优异的附着力。 在一个实施例中，片和膜可以形成为层压体。
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7.发明申请Fast-drying aqueous compositions with hollow particle binders and traffic paints made therewith 有权具有中空颗粒粘合剂和交通漆的快干水性组合物公开(公告)号：US20080171810A1
公开(公告)日：2008-07-17
申请号：US12008003
申请日：2008-01-08
IPC分类号： C08F283/00
CPC分类号： C09D133/08 , C08L2207/53 , C09D5/004 , C09D7/68 , C09D7/70
摘要： The present invention provides fast-drying aqueous compositions that lower the cost of making roadway markings without impairing the quality or appearance of the markings made therewith. The aqueous compositions comprise one or more hollow core binder having an average particle size of from 200 to 500 nanometers (nm), preferably from 300 to 470 nm, and made of a first polymer having a glass transition temperature (Tg) of 50° C. or more and containing one or more void, the first polymer being substantially encapsulated by one or more second polymer having a Tg of −30° C. or more, preferably, −20° C. or more. Fast-drying aqueous compositions may be one component or two component compositions. One component compositions comprise one or more volatile base, one or more polyfunctional amine, and one or more hollow core binder with a second polymer chosen from, for example, an anionically stabilized emulsion polymer, a polyamine functional polymer, a polymer having strong pendant cationic groups containing and mixtures thereof. The polyfunctional amine can be part of the hollow core binder. Two component compositions comprise one or more aqueous hollow core binder and an absorber component. The present invention also provides coatings and roadway markings made from the fast-drying aqueous compositions.
摘要翻译： 本发明提供了快速干燥的含水组合物，其降低了制作道路标记的成本，而不损害由此制成的标记的质量或外观。 含水组合物包含平均粒径为200-500纳米（nm），优选为300-470nm的一种或多种中空芯粘合剂，并由玻璃化转变温度（Tg）为50℃的第一聚合物制成 或更多且含有一个或多个空隙的第一聚合物，所述第一聚合物基本上被Tg为-30℃或更高，优选-20℃或更高的一种或多种第二聚合物包封。 快干水性组合物可以是一种组分或两种组分。 一种组分组合物包含一种或多种挥发性碱，一种或多种多官能胺，以及一种或多种中空芯粘合剂，其具有第二种聚合物，其选自例如阴离子稳定的乳液聚合物，多胺官能聚合物，具有强阳离子阳离子 基团和其混合物。 多官能胺可以是中空芯粘合剂的一部分。 双组分组合物包含一种或多种水性中空芯粘合剂和吸收剂组分。 本发明还提供了由快干水性组合物制成的涂层和道路标记。
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8.发明授权Fast-drying aqueous compositions with hollow particle binders and traffic paints made therewith 有权具有中空颗粒粘合剂和交通漆的快干水性组合物公开(公告)号：US07645815B2
公开(公告)日：2010-01-12
申请号：US12008003
申请日：2008-01-08
IPC分类号： F21V7/22
CPC分类号： C09D133/08 , C08L2207/53 , C09D5/004 , C09D7/68 , C09D7/70
摘要： The present invention provides fast-drying aqueous compositions that lower the cost of making roadway markings without impairing the quality or appearance of the markings made therewith. The aqueous compositions comprise one or more hollow core binder having an average particle size of from 200 to 500 nanometers (nm), preferably from 300 to 470 nm, and made of a first polymer having a glass transition temperature (Tg) of 50° C. or more and containing one or more void, the first polymer being substantially encapsulated by one or more second polymer having a Tg of −30° C. or more, preferably, −20° C. or more. Fast-drying aqueous compositions may be one component or two component compositions. One component compositions comprise one or more volatile base, one or more polyfunctional amine, and one or more hollow core binder with a second polymer chosen from, for example, an anionically stabilized emulsion polymer, a polyamine functional polymer, a polymer having strong pendant cationic groups containing and mixtures thereof. The polyfunctional amine can be part of the hollow core binder. Two component compositions comprise one or more aqueous hollow core binder and an absorber component. The present invention also provides coatings and roadway markings made from the fast-drying aqueous compositions.
摘要翻译： 本发明提供了快速干燥的含水组合物，其降低了制作道路标记的成本，而不损害由此制成的标记的质量或外观。 含水组合物包含平均粒径为200-500纳米（nm），优选为300-470nm的一种或多种中空芯粘合剂，并由玻璃化转变温度（Tg）为50℃的第一聚合物制成 或更多且含有一个或多个空隙的第一聚合物，所述第一聚合物基本上被Tg为-30℃或更高，优选-20℃或更高的一种或多种第二聚合物包封。 快干水性组合物可以是一种组分或两种组分。 一种组分组合物包含一种或多种挥发性碱，一种或多种多官能胺，以及一种或多种中空芯粘合剂，其具有第二种聚合物，其选自例如阴离子稳定的乳液聚合物，多胺官能聚合物，具有强阳离子阳离子 基团和其混合物。 多官能胺可以是中空芯粘合剂的一部分。 双组分组合物包含一种或多种水性中空芯粘合剂和吸收剂组分。 本发明还提供了由快干水性组合物制成的涂层和道路标记。
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9.发明授权Methods for making composites having thermoplastic properties from recycled crosslinked polymer 有权从循环交联聚合物制备具有热塑性的复合材料的方法公开(公告)号：US08304460B2
公开(公告)日：2012-11-06
申请号：US12456473
申请日：2009-06-17
IPC分类号： C08J11/04
CPC分类号： C08J3/16 , C08C1/14 , C08F6/22 , C08J11/06 , C08J2300/30 , C08J2319/00 , C08J2321/00 , C08L19/003 , C08L33/12 , C08L101/02 , Y02W30/701 , Y10T428/24355 , Y10T428/24405 , Y10T428/269 , C08L2666/04
摘要： The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 μm or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 μm in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials. In one embodiment, the sheets and films can be formed into laminates.
摘要翻译： 本发明提供了以细碎材料或制品形式制造可成形复合材料的方法，以及通过该方法生产的材料和制品，所述方法包括通过（i）处理水性热塑性丙烯酸或乙烯基聚合物以增加粒径来形成混合物 的重均粒径为1μm以上，任选地脱水以形成碎屑混合物; 和（ii）将热塑性丙烯酸或乙烯基聚合物与一种或多种具有10至600μm的筛粒度为15至95重量％的废橡胶硫化橡胶组合。 ％，基于聚合物和橡胶的总重量以形成碎屑浆料，使得（ii）可以在（i）之前，之后，但在任何脱水之前，或在任何脱水之后进行; 和（iii）热塑性加工混合物。 热塑性加工可以直接形成制品，如片材或薄膜。 可塑性复合材料对其他材料具有优异的附着力。 在一个实施例中，片和膜可以形成为层压体。
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10.发明申请POLYURETHANE COATING COMPOSITIONS COMPRISING ISOCYANURATE COMPOSITIONS FROM BIS(ISOCYANATOMETHYL) CYCLOHEXANE AND TERTIARY AMINE CATALYSTS 有权包含异硫氰酸酯组合物的聚氨酯涂料组合物（异氰脲酸酯）环己烷和仲胺催化剂公开(公告)号：US20120130002A1
公开(公告)日：2012-05-24
申请号：US13297499
申请日：2011-11-16
申请人： Donald C. Schall , Jia Tang
发明人： Donald C. Schall , Jia Tang
IPC分类号： C09D175/06 , C09D175/12 , C09D175/08 , C09D133/14
CPC分类号： C08G18/163 , C08G18/1808 , C08G18/1816 , C08G18/2063 , C08G18/222 , C08G18/6216 , C08G18/792 , C09D175/04
摘要： The present invention provides high solids, two-component polyurethane compositions comprising, as one component, polyisocyanate compositions having one or more isocyanurate made from bis(isocyanatomethyl)-cyclohexane, as a second component, one or more high solids polyol, and in either component, one or more tertiary amine catalyst. Optionally, the compositions further comprise one or more zinc amine catalyst. The compositions provide coatings, which exhibit an excellent balance of pot life and dry to touch or tack free time, as well as early rain resistance and hardness, while enabling a lower volatile organic content (VOC) of the compositions for comparable performance.
摘要翻译： 本发明提供了高固含量的双组分聚氨酯组合物，其包含作为一种组分的具有一种或多种由双（异氰酸酯基甲基） - 环己烷，作为第二组分，一种或多种高固含量多元醇制成的异氰脲酸酯的多异氰酸酯组合物， ，一种或多种叔胺催化剂。 任选地，组合物还包含一种或多种锌胺催化剂。 组合物提供涂层，其表现出适用期的平衡以及干触摸或无粘性时间，以及早期耐雨性和硬度，同时使组合物的挥发性有机成分（VOC）具有可比性能。
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