公开(公告)号：US07405251B2

公开(公告)日：2008-07-29

申请号：US10512733

申请日：2003-05-15

申请人： David Joseph Romenesko ,  Randall Gene Schmidt ,  Atsushi Togashi ,  Gary Michael Wieber

发明人： David Joseph Romenesko ,  Randall Gene Schmidt ,  Atsushi Togashi ,  Gary Michael Wieber

IPC分类号： C08L83/05 ,  C08L69/00 ,  C08L55/02

CPC分类号： C08L101/00 ,  C08G77/12 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/44 ,  C08G77/70 ,  C08L83/04 ,  C08L2666/14 ,  C08L2666/02

摘要： This invention relates to a flame retardant composition comprising: (a) 81 to 99.99 weight percent of a thermoplastic resin, thermoset resin, thermoplastic resin blend, or thermoset resin blend which upon burning forms a char and (b) 0.01-19 weight percent of a silsesquioxane resin having a weight average molecular weight of greater than 300.

摘要翻译： 本发明涉及一种阻燃剂组合物，其包含：（a）81至99.99重量％的热塑性树脂，热固性树脂，热塑性树脂共混物或热固树脂共混物，其在燃烧时形成炭，（b）0.01-19重量％ 重均分子量大于300的倍半硅氧烷树脂。

公开(公告)号：US5916952A

公开(公告)日：1999-06-29

申请号：US975031

申请日：1997-11-20

申请人： David Joseph Romenesko ,  Steven Patrick Mullan

发明人： David Joseph Romenesko ,  Steven Patrick Mullan

IPC分类号： C08K3/36 ,  C08K5/5419 ,  C08L71/12 ,  C08L83/04 ,  C08K3/00

CPC分类号： C08L71/123

摘要： A free-flowing silicone rubber powder, having an average particle size of 1 to 1000 microns and prepared by mixing a polydiorganosiloxane with a silica filler, is uniformly dispersed in a poly(phenylene ether) resin using conventional equipment, such as a single screw or, preferably, a twin screw extruder. When employed at relatively low concentrations, such as about 0.2 to 3 parts by weight of powder per 100 parts by weight of resin, a significant improvement in the processability is obtained, while modification at higher levels, such as 5 to 20 parts by weight of powder per 100 parts by weight of the resin results in a resin composition having greatly augmented impact resistance.

摘要翻译： 将平均粒度为1-1000微米并通过将聚二有机硅氧烷与二氧化硅填料混合而制备的自由流动的硅橡胶粉末使用常规设备如单螺杆或均匀分散在聚苯醚树脂中， ，优选双螺杆挤出机。 当以相对低的浓度使用例如每100重量份树脂约0.2-3重量份的粉末时，可获得加工性的显着改善，而在较高水平下进行改性，例如5至20重量份 粉末每100重量份的树脂导致具有极大增强的耐冲击性的树脂组合物。

公开(公告)号：US5789473A

公开(公告)日：1998-08-04

申请号：US404739

申请日：1995-01-24

申请人： Dale Earl Hauenstein ,  David Joseph Romenesko

发明人： Dale Earl Hauenstein ,  David Joseph Romenesko

IPC分类号： C08L23/00 ,  C08J3/20 ,  C08L23/02 ,  C08L23/08 ,  C08L83/04 ,  C08L87/00 ,  C08J5/32

CPC分类号： C08L23/02 ,  C08L23/06 ,  C08L23/0815 ,  C08L2207/066 ,  C08L83/04 ,  Y10T428/31855 ,  Y10T428/31913

摘要： There is disclosed a polyolefin composition which can be extruded at relatively high rates to provide extrudate having a low surface roughness (sharkskin), said composition comprising (A) 100 parts by weight of a polyolefin resin; and (B) 0.01 to 1 part by weight of a hydroxy-functional diorganopolysiloxane process aid, said diorganopolysiloxane having a number average molecular weight of at least 10,000. In particularly preferred embodiments, a hydroxy-functional diorganopolysiloxane in combination with a low density polyethylene is used as a process aid for linear low density polyethylene.

摘要翻译： 公开了可以以相对高的速率挤出以提供具有低表面粗糙度（鲨鱼皮）的挤出物的聚烯烃组合物，所述组合物包含（A）100重量份的聚烯烃树脂; 和（B）0.01至1重量份的羟基官能二有机聚硅氧烷加工助剂，所述二有机聚硅氧烷的数均分子量至少为10,000。 在特别优选的实施方案中，将羟基官能二有机聚硅氧烷与低密度聚乙烯组合用作线性低密度聚乙烯的加工助剂。

公开(公告)号：US06417293B1

公开(公告)日：2002-07-09

申请号：US09728920

申请日：2000-12-04

申请人： Igor Chorvath ,  Craig Steven Gross ,  Kenneth Gerard Gruszynski ,  Michael Kang-Jen Lee ,  Jun Liao ,  Koji Nakanishi ,  Richard Leroy Rabe ,  David Joseph Romenesko

发明人： Igor Chorvath ,  Craig Steven Gross ,  Kenneth Gerard Gruszynski ,  Michael Kang-Jen Lee ,  Jun Liao ,  Koji Nakanishi ,  Richard Leroy Rabe ,  David Joseph Romenesko

IPC分类号： C08L6706

CPC分类号： C08L67/02 ,  C08G77/06 ,  C08G77/12 ,  C08G77/20 ,  C08G77/44 ,  C08K5/0091 ,  C08K5/04 ,  C08K5/16 ,  C08K5/36 ,  C08K5/5419 ,  C08L83/04 ,  C08L83/00 ,  C08L2666/14 ,  C08L2666/28

摘要： The present invention, therefore, relates to a method for preparing a thermoplastic elastomer, said method comprising: (I) mixing (A) a thermoplastic resin comprising more than 50 percent by volume of a polyester resin other than poly(butylene terephthalate), said thermoplastic resin having a softening point of 23° C. to 300° C., (B) a silicone elastomer comprising (B′) 100 parts by weight of a diorganopolysiloxane gum having a plasticity of at least 30 and having an average of at least 2 alkenyl groups in its molecule and, optionally, (B″) up to 200 parts by weight of a reinforcing filler, the weight ratio of said silicone elastomer (B) to said thermoplastic resin (A) being greater than 35:65 to 85:15, (C) 0.01 to 5 parts by weight of a stabilizer for each 100 parts by weight of said thermoplastic resin and said silicone elastomer, (D) an organohydrido silicon compound which contains an average of at least 2 silicon-bonded hydrogen groups in its molecule and (E) a hydrosilation catalyst, components (D) and (E) being present in an amount sufficient to cure said diorganopolysiloxane (B′); and (II) dynamically curing said diorganopolysiloxane (B′).

摘要翻译： 因此，本发明涉及一种制备热塑性弹性体的方法，所述方法包括：（I）混合（A）包含超过50体积％的聚（对苯二甲酸丁二醇酯）以外的聚酯树脂的热塑性树脂，所述 软化点为23℃至300℃的热塑性树脂，（B）含有（B'）100重量份塑性为至少30的二有机基聚硅氧烷胶的硅氧烷弹性体，其平均至少为 2个烯基和任选的（B“）至多200重量份的增强填料，所述硅氧烷弹性体（B）与所述热塑性树脂（A）的重量比大于35:65至大于35:65至 85:15，（C）每100重量份所述热塑性树脂和所述硅氧烷弹性体中的稳定剂0.01至5重量份，（D）平均含有至少2个与硅键合的氢的有机氢化硅化合物 （E）硅氢化催化剂，c 组分（D）和（E）以足以固化所述二有机聚硅氧烷（B'）的量存在; 和（II）动态固化所述二有机聚硅氧烷（B'）。

公开(公告)号：US6013715A

公开(公告)日：2000-01-11

申请号：US34089

申请日：1998-03-03

申请人： Gerald Alphonse Gornowicz ,  Kevin Edward Lupton ,  David Joseph Romenesko ,  Kim Struble ,  Hongxi Zhang

发明人： Gerald Alphonse Gornowicz ,  Kevin Edward Lupton ,  David Joseph Romenesko ,  Kim Struble ,  Hongxi Zhang

IPC分类号： C08L23/02 ,  C08L23/04 ,  C08L67/02 ,  C08L83/04 ,  C08K3/00

CPC分类号： C08L23/02 ,  C08L23/04 ,  C08L23/10 ,  C08L67/02 ,  C08L2312/00 ,  C08L83/04

摘要： There is disclosed a method for preparing a thermoplastic elastomer, said method comprising:(I) mixing(A) a thermoplastic resin selected from the group consisting of a polyolefin and a poly(butylene terephthalate),(B) a diorganopolysiloxane having a plasticity of at least 30 and having an average of at least 2 alkenyl radicals in its molecule,(C) an organohydrido silicon compound which contains an average of at least 2 silicon-bonded hydrogen groups in its molecule,(D) optionally, a reinforcing filler and(E) a hydrozilation catalyst; and(II) dynamically curing said diorganopolysiloxane (B), wherein the amount of said diorganopolysiloxane (B) used is such that at least one property of the thermoplastic elastomer selected from tensile strength or elongation is at least 25% greater than the respective property for a corresponding simple blend wherein said diorganopolysiloxane is not cured.

摘要翻译： 公开了一种制备热塑性弹性体的方法，所述方法包括：（I）将（A）选自聚烯烃和聚（对苯二甲酸丁二醇酯）的热塑性树脂混合，（B）具有可塑性的二有机聚硅氧烷 至少30，并且在其分子中平均具有至少2个烯基，（C）有机氢化硅化合物，其在其分子中平均含有至少2个与硅键合的氢基团，（D）任选的增强填料和 （E）氢化齐平催化剂; 和（II）动态固化所述二有机聚硅氧烷（B），其中使用的所述二有机基聚硅氧烷（B）的量使得选自拉伸强度或伸长率的热塑性弹性体的至少一种性质比相对于 相应的简单混合物，其中所述二有机聚硅氧烷不固化。

公开(公告)号：US5844031A

公开(公告)日：1998-12-01

申请号：US704061

申请日：1996-08-28

申请人： Wei Chen ,  Hongxi Zhang ,  Kevin Edward Lupton ,  David Joseph Romenesko ,  Randall Gene Schmidt

发明人： Wei Chen ,  Hongxi Zhang ,  Kevin Edward Lupton ,  David Joseph Romenesko ,  Randall Gene Schmidt

IPC分类号： C08J3/07 ,  C08L23/00 ,  C08L83/04 ,  C08L101/00 ,  C08K5/24

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/26 ,  C08G77/46 ,  C08G77/70 ,  C08G77/80

摘要： A method of dispersing silicone compositions in organic thermoplastic materials is disclosed. The novel compositions produced by the method of the invention have a fine and relatively uniform dispersion or organosilicone in an organic thermoplastic. An organosilicone resin (A) and a predominantly linear silicone fluid (B) are first blended to substantial homogeneity to form an organosilicone alloy therefrom. The organosilicone alloy exhibits thermoplastic behavior and has a temperature-dependent complex viscosity .eta.*.sub.Si (T) associated therewith. Likewise the organic thermoplastic materials have a temperature-dependent complex viscosity, .eta.*.sub.OTP (T), associated therewith. The organic thermoplastic and the organosilicone alloy are thereafter mixed at a predetermined mixing temperature, T.sub.m, and a predetermined shear strain rate. The organic thermoplastic material and the organosilicone alloy are both in a flowable state at T.sub.m. The value of T.sub.m is selected to be about .+-.30.degree. C. of a temperature, T.sub.0, wherein the absolute value of {72*.sub.OTP (T.sub.0)-.eta.*.sub.Si (T.sub.0)} is at its lowest value, at the predetermined shear strain rate.

摘要翻译： 公开了将有机硅组合物分散在有机热塑性材料中的方法。 通过本发明的方法生产的新型组合物在有机热塑性塑料中具有精细且相对均匀的分散体或有机硅氧烷。 首先将有机硅氧烷树脂（A）和主要为线性的硅氧烷流体（B）进行共混，从而形成有机硅氧烷合金。 有机硅合金表现出热塑性，并具有与之相关的温度依赖性复数粘度ηa（T）。 类似地，有机热塑性材料具有与之相关的温度依赖性复合物粘度eta * OTP（T）。 然后将有机热塑性塑料和有机硅合金以预定的混合温度Tm和预定的剪切应变速率混合。 有机热塑性材料和有机硅合金在Tm处于可流动状态。 选择Tm的值为约+/- 30℃的温度T0，其中{72 * OTP（T0） - eta * Si（T0）}的绝对值处于其最低值，在 预定的剪切应变速率。

公开(公告)号：US5708085A

公开(公告)日：1998-01-13

申请号：US703161

申请日：1996-08-28

申请人： Dale Earl Hauenstein ,  Caibao Qian ,  David Joseph Romenesko

发明人： Dale Earl Hauenstein ,  Caibao Qian ,  David Joseph Romenesko

IPC分类号： B29B11/14 ,  C08L23/04 ,  C08L23/06 ,  C08L83/04

CPC分类号： C08L23/0815 ,  C08L23/06 ,  C08L2205/03 ,  C08L83/04

摘要： There is disclosed a polyolefin composition which can be extruded at relatively high rates to provide extrudate having improved hydrophobicity, said composition comprising (A) 100 parts by weight of a polythylene resin; and (B) 1 to 5 parts by weight of an interactive diorganopolysiloxane process aid, said diorganopolysiloxane having a number average molecular weight of at least 10,000. In particularly preferred embodiments, an interactive diorganopolysiloxane in combination with a low density polyethylene is used as a process aid for linear low density polyethylene.

摘要翻译： 公开了一种聚烯烃组合物，其可以以相对高的速率挤出以提供具有改善的疏水性的挤出物，所述组合物包含（A）100重量份的聚乙烯树脂; 和（B）1至5重量份的交互式二有机聚硅氧烷加工助剂，所述二有机聚硅氧烷的数均分子量至少为10,000。 在特别优选的实施方案中，将与低密度聚乙烯组合的交互式二有机聚硅氧烷用作线性低密度聚乙烯的加工助剂。

公开(公告)号：US06465552B1

公开(公告)日：2002-10-15

申请号：US09845971

申请日：2001-05-01

申请人： Igor Chorvath ,  Frances Marie Fournier ,  Christopher James Julien ,  Michael Kang-Jen Lee ,  Dawei Li ,  Jun Liao ,  Robert Leo Oldinski ,  Richard Leroy Rabe ,  David Joseph Romenesko ,  Thomas John Tangney ,  Yongjun Lee ,  Koji Nakanishi

发明人： Igor Chorvath ,  Frances Marie Fournier ,  Christopher James Julien ,  Michael Kang-Jen Lee ,  Dawei Li ,  Jun Liao ,  Robert Leo Oldinski ,  Richard Leroy Rabe ,  David Joseph Romenesko ,  Thomas John Tangney ,  Yongjun Lee ,  Koji Nakanishi

IPC分类号： C08K513

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/448 ,  C08G77/455 ,  C08G77/458 ,  C08G77/46 ,  C08L67/02 ,  C08L83/00 ,  C08L2666/14 ,  C08L2666/28

摘要： Thermoplastic elastomers are disclosed which are prepared by; (I) mixing, (A) a thermoplastic resin comprising more than 50 percent by volume of a polyamide or a polyester resin, (B) a silicone base comprising; (B′) 100 parts by weight of a diorganopolysiloxane gum having a plasticity of at least 30 and having an average of at least 2 alkenyl groups per molecule and (B″) 5 to 200 parts by weight of a reinforcing filler, wherein the weight ratio of said silicone base to said polyamide or polyester resin is from 35:65 to 85:15, (C) a compatibilizer, (D) a radical initiator, present in an amount sufficient to cure said diorganopolysiloxane gum, and optionally (E) a stabilizer, (II) dynamically vulcanizing said diorganopolysiloxanes gum, wherein at least one property of the thermoplastic elastomer selected from tensile strength or elongation is at least 25% greater than the respective property for a corresponding simple blend wherein said diorganopolysiloxane is not cured and said thermoplastic elastomer has an elongation of at least 25%.

摘要翻译： 公开了热塑性弹性体，其通过以下制备：（I）混合（A）包含超过50体积％的聚酰胺或聚酯树脂的热塑性树脂，（B）包含（B'）100重量份 具有至少30的塑性并且每分子平均具有至少2个烯基的二有机基聚硅氧烷胶的重量和（B“）5至200重量份的增强填料，其中所述硅氧烷基与 所述聚酰胺或聚酯树脂为35:65至85:15，（C）增容剂，（D）自由基引发剂，其量足以固化所述二有机聚硅氧烷胶，和（E）稳定剂，（II） 动态硫化所述二有机聚硅氧烷胶，其中选自拉伸强度或伸长率的热塑性弹性体的至少一种性质相对于相应的简单混合物的相应性能至少大25％，其中所述二有机聚硅氧烷未固化，并且所述热塑性弹性体 tomer的伸长率至少为25％。

公开(公告)号：US06569931B2

公开(公告)日：2003-05-27

申请号：US09848757

申请日：2001-05-03

申请人： Haruhiko Furukawa ,  Yoshitsugu Morita ,  Kevin Edward Lupton ,  David Joseph Romenesko

发明人： Haruhiko Furukawa ,  Yoshitsugu Morita ,  Kevin Edward Lupton ,  David Joseph Romenesko

IPC分类号： C08K554

CPC分类号： C08L23/10 ,  C08L23/16 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00 ,  C08L77/06 ,  C08L77/12 ,  C08L83/04 ,  C08L2205/035 ,  C08L2666/02 ,  C08L83/00

摘要： A thermoplastic elastomer composition, method of preparation, and article prepared therefrom. The thermoplastic elastomer composition comprising (A) a thermoplastic elastomer, (B) a thermoplastic resin which has Rockwell hardness (R scale) exceeding 80 at 25° C., (C) a polydiorganosiloxane which has a Williams plasticity exceeding 100 at 25° C.; and (D) an inorganic filler.

摘要翻译： 热塑性弹性体组合物，制备方法和由其制备的制品。 该热塑性弹性体组合物包含（A）热塑性弹性体，（B）在25℃下具有洛氏硬度（R比例）超过80的热塑性树脂，（C）在25℃下威廉姆斯塑性超过100的聚二有机硅氧烷 。 和（D）无机填料。

公开(公告)号：US06433049B1

公开(公告)日：2002-08-13

申请号：US09880480

申请日：2001-06-13

申请人： David Joseph Romenesko ,  Kiersten Lynn Shephard

发明人： David Joseph Romenesko ,  Kiersten Lynn Shephard

IPC分类号： C08K524

CPC分类号： C08L23/0815 ,  C08G77/12 ,  C08G77/20 ,  C08L23/02 ,  C08L83/04 ,  C08L2201/02 ,  C08L83/00 ,  C08L2666/02 ,  C08L2666/54

摘要： A composition comprising a polyolefin, a polyorganosiloxane having at least two alkenyl groups per molecule, and calcium silicate where the polyorganosiloxane is cured after mixing using an organohydrido silicon compound and a hydrosilation catalyst to create a thermoplastic vulcanizate, provides excellent fire resistance. In particular such compositions when tested by burning at 40 to 88 kW/m2 external flux generate significantly less heat and smoke, and generate tougher chars compared to polyolefins alone, or mixtures of thermoplastic polyolefin resin, polyorganosiloxane and calcium silicate where the composition is not cured after mixing.