公开(公告)号：US08859066B2

公开(公告)日：2014-10-14

申请号：US10543319

申请日：2004-01-28

Applicant: Solveig Johansson ,  Christer Lind ,  Cecilia Rydin

Inventor： Solveig Johansson ,  Christer Lind ,  Cecilia Rydin

IPC: B32B1/08 ,  B32B15/085 ,  B32B27/32 ,  C08L23/08 ,  C08F10/02 ,  C09D123/08 ,  C08F110/02 ,  C08F4/659 ,  C08F210/16

CPC classification number: C08F10/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F110/02 ,  C08F210/16 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C09D123/0815 ,  Y10S526/943 ,  Y10T428/1393 ,  Y10T428/31692 ,  Y10T428/31938 ,  C08F4/65925 ,  C08L2666/06 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/13 ,  C08F210/14 ,  C08F2500/05

Abstract: A coating composition, a process for producing it and substrate coated therewith are described. The composition comprises a multimodal ethylene polymer, which contains from 80 to 99.8% by weight of ethylene repeating units and from 0.2 to 20% by weight of C3-C20 α-olefin repeating units, and is a blend of at least a first and a second ethylene polymer prepared by polymerization in the presence of a single site catalyst system.The blend has a density of 0.915-0.955 g/cm3, a melt flow rate, MFR2, of 0.028-1.5 g/10 min., a molecular weight distribution, Mw/Mn, of 3-10, and a CTL 5.0 MPa-value according to ISO 6259 of at least 500 hrs.

Abstract translation: 描述了涂料组合物，其制备方法和涂覆的基材。 该组合物包含多峰乙烯聚合物，其含有80-99.8重量％的乙烯重复单元和0.2-20重量％的C 3 -C 20α-烯烃重复单元，并且是至少第一和第 通过在单一位点催化剂体系存在下聚合制备的第二乙烯聚合物。 共混物的密度为0.915-0.955g / cm3，熔体流动速率，MFR2为0.028-1.5g / 10min，分子量分布，Mw / Mn为3-10，CTL为5.0MPa- 根据ISO 6259的值至少为500小时。

公开(公告)号：US06503993B1

公开(公告)日：2003-01-07

申请号：US09530294

申请日：2000-06-27

Applicant: Päivi Huovinen ,  Pirjo J{umlaut over (aa)}skeläinen ,  Amir Karbasi ,  Christer Lind ,  Bo Malm ,  John Haugen

Inventor： Päivi Huovinen ,  Pirjo J{umlaut over (aa)}skeläinen ,  Amir Karbasi ,  Christer Lind ,  Bo Malm ,  John Haugen

IPC: C08F1006

CPC classification number: C08F297/083 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F297/08 ,  C08L53/00 ,  C08F4/6492 ,  C08F4/6465 ,  C08L2666/02 ,  C08F2500/12 ,  C08F2500/17 ,  C08F210/16 ,  C08F212/00 ,  C08F210/14

Abstract: The present invention concerns nucleated propylene polymers having a xylene soluble fraction at 23° C. of less than 2.5%, a crystallization temperature of over 124 ° C. and a tensile modulus of greater than 2,000 MPa. These polymers can be prepared by nucleating a propylene polymer with a polymeric nucleating agent containing vinyl compound units, and by polymerizing propylene optionally with comonomers in the presence of a Ziegler-Natta catalyst system primarily transesterified with a phthalic acid ester—a lower alcohol pair to provide said propylene polymer. The catalyst contains a strongly coordinating external donor.

Abstract translation: 本发明涉及在23℃下二甲苯可溶组分小于2.5％，结晶温度超过124℃，拉伸模量大于2000MPa的有核丙烯聚合物。 这些聚合物可以通过用含有乙烯基化合物单元的聚合物成核剂将丙烯聚合物成核，并且在主要由邻苯二甲酸酯 - 低级醇对酯交换的齐格勒 - 纳塔催化剂体系存在下，将丙烯任选地与共聚单体聚合， 提供所述丙烯聚合物。 该催化剂含有一个强配位的外部供体

公开(公告)号：US20070003724A1

公开(公告)日：2007-01-04

申请号：US10543319

申请日：2004-01-28

Applicant: Solveig Johansson ,  Christer Lind ,  Cecilia Rydin

Inventor： Solveig Johansson ,  Christer Lind ,  Cecilia Rydin

IPC: B32B1/08 ,  B32B27/32 ,  B32B15/085

CPC classification number: C08F10/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F110/02 ,  C08F210/16 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C09D123/0815 ,  Y10S526/943 ,  Y10T428/1393 ,  Y10T428/31692 ,  Y10T428/31938 ,  C08F4/65925 ,  C08L2666/06 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/13 ,  C08F210/14 ,  C08F2500/05

Abstract: A coating composition, a process for producing it and substrate coated therewith are described. The composition comprises a multimodal ethylene polymer, which contains from 80 to 99.8% by weight of ethylene repeating units and from 0.2 to 20% by weight of C3-C20 α-olefin repeating units, and is a blend of at least a first and a second ethylene polymer that are obtainable by a process comprising at least two steps in which: said first ethylene polymer is prepared by polymerising ethylene and optional comonomer(s) in the presence of a single site catalyst system; and said second ethylene polymer is prepared by polymerising ethylene and optional comonomer(s) in the presence of a single site catalyst system; said steps being performed in any order and the ethylene polymer of each step being present in the following step(s), and producing a blend of from 20 to 80% by weight of said first and from 80 to 20% by weight of said second ethylene polymer, said blend having a density of 0.915-0.955 g/cm3, a melt flow rate, MFR2, of 0.028-1.5 g/10 min., a molecular weight distribution, Mw/Mn, of 3-10, and a CTL 5.0 MPa-value according to ISO 6259 of at least 500 hrs. The substrate coated with the coating composition preferably is a metal pipe.

Abstract translation: 描述了涂料组合物，其制备方法和涂覆的基材。 该组合物包含多峰乙烯聚合物，其含有80至99.8重量％的乙烯重复单元和0.2至20重量％的C 3 -C 20亚甲基 烯属重复单元，并且是至少第一和第二乙烯聚合物的共混物，其可通过包含至少两个步骤的方法获得，其中：所述第一乙烯聚合物通过聚合乙烯和任选的共聚单体 存在单一位点催化剂体系; 并且所述第二乙烯聚合物通过在单位点催化剂体系的存在下聚合乙烯和任选的共聚单体来制备; 所述步骤以任何顺序进行，并且每个步骤的乙烯聚合物存在于以下步骤中，并产生20-80重量％的所述第一和80至20重量％的所述第二个 乙烯聚合物，所述共混物的密度为0.915-0.955g / cm 3，熔体流动速率MFR 2为0.028-1.5g / 10min，a 3-10的分子量分布，M w / M n n，以及根据ISO 6259的CTL5.0MPa值至少为500小时。 涂覆有涂料组合物的基材优选为金属管。