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公开(公告)号：US20120053360A1
公开(公告)日：2012-03-01
申请号：US13138987
申请日：2010-05-06
Applicant: Evert Jan Ditzel , Bogdan Costin` Gagea
Inventor： Evert Jan Ditzel , Bogdan Costin` Gagea
CPC classification number: C07C51/12 , B01J29/18 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J37/10 , B01J2229/38 , C07C67/37 , C07C57/08 , C07C69/14
Abstract: A process for the production of at least one carbonylation product selected from acetic acid and methyl acetate by carbonylating at least one carbonylatable reactant selected from methanol and reactive derivatives thereof with carbon monoxide in the presence of a catalyst which is a mordenite which has been treated with an aqueous ammonium hydroxide solution and has a silica:alumina molar ratio of at least 10:1.
Abstract translation: 一种生产选自乙酸和乙酸甲酯的至少一种羰基化产物的方法，该方法是在催化剂存在下，将一种选自甲醇及其活性衍生物的至少一种羰基化反应物与一氧化碳进行羰基化反应，该催化剂是已经用 氢氧化铵水溶液，二氧化硅：氧化铝摩尔比至少为10:1。
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公开(公告)号：US08586778B2
公开(公告)日：2013-11-19
申请号：US13138990
申请日：2010-05-06
Applicant: Evert Jan Ditzel , Bogdan Costin Gagea
Inventor： Evert Jan Ditzel , Bogdan Costin Gagea
IPC: C07C67/36
CPC classification number: B01J35/10 , B01J29/18 , B01J2229/18 , B01J2229/38 , C07C51/12 , C07C67/37 , C07C53/08 , C07C69/14
Abstract: A process for the production of acetic acid and/or methyl acetate by carbonylating methanol and/or reactive derivatives thereof with carbon monoxide in the presence of a catalyst which is a mordenite which has been treated with an aqueous basic solution containing at least one of aluminate ions and gallate ions and has a silica:X2O3 molar ratio (wherein X is A1 and/or Ga) of at least 12:1.
Abstract translation: 在催化剂的存在下，使用甲醇和/或其反应性衍生物与一氧化碳羰化来制备乙酸和/或乙酸甲酯的方法，该催化剂是已经用含有至少一种铝酸盐的碱性水溶液处理过的丝光沸石 离子和没食子酸酯离子，并且具有至少12:1的二氧化硅：X 2 O 3摩尔比（其中X是Al和/或Ga）。
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公开(公告)号：US20160009629A1
公开(公告)日：2016-01-14
申请号：US14773220
申请日：2014-03-06
Applicant: Evert Jan DITZEL , Bogdan Costin GAGEA , David John LAW , John Glenn SUNLEY , BP CHEMICALS LIMITED
Inventor： Evert Jan DITZEL , Bogdan Costin GAGEA , David John LAW , John Glenn SUNLEY
CPC classification number: C07C67/37 , B01J29/06 , B01J29/18 , B01J29/185 , B01J29/24 , B01J29/65 , B01J29/70 , B01J29/7015 , B01J29/7026 , B01J29/87 , B01J37/0009 , B01J37/0018 , B01J37/08 , B01J2229/14 , B01J2229/18 , B01J2229/42 , C07C51/09 , C07C69/14
Abstract: A process for preparing methyl acetate by the carbonylation of dimethyl ether with carbon monoxide in the presence of hydrogen and a zeolite catalyst wherein, in a first step the carbonylation is conducted with a carbon monoxide to hydrogen molar ratio of at least 1 and in a second and subsequent step, the carbonylation is conducted with a hydrogen to carbon monoxide molar ratio of greater than 1.
Abstract translation: 一种通过在氢气和沸石催化剂的存在下用一氧化碳羰基化二甲醚的乙酸甲酯的方法，其中在第一步中羰基化是以至少1的一氧化碳与氢的摩尔比进行的， 和随后的步骤，羰基化以氢气与一氧化碳的摩尔比大于1进行。
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公开(公告)号：US20120078005A1
公开(公告)日：2012-03-29
申请号：US13138991
申请日：2010-05-06
Applicant: Gareth Gerald Armitage , Bogdan Costin Gagea , David John Law , John Glenn Sunley
Inventor： Gareth Gerald Armitage , Bogdan Costin Gagea , David John Law , John Glenn Sunley
CPC classification number: C07C51/12 , B01J29/18 , B01J2229/16 , B01J2229/36 , B01J2229/38 , C07C67/37 , C07C57/08 , C07C69/14
Abstract: A process for the production of acetic acid and/or methyl acetate by the carbonylation of methanol, methyl acetate and/or dimethyl ether with carbon monoxide in the presence of a desilicated mordenite catalyst.
Abstract translation: 在脱盐丝光沸石催化剂存在下，通过甲醇，乙酸甲酯和/或二甲醚与一氧化碳羰基化生产乙酸和/或乙酸甲酯的方法。
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Patent Agency Ranking
公开(公告)号：US20130125630A1
公开(公告)日：2013-05-23
申请号：US13812292
申请日：2011-07-29
Applicant: Ian Ralph Collins , John William Couves , Bogdan Costin Gagea , Arnaud Lager , Kevin John Webb
Inventor： Ian Ralph Collins , John William Couves , Bogdan Costin Gagea , Arnaud Lager , Kevin John Webb
IPC: G01N1/00
CPC classification number: G01N1/00 , E21B43/20 , G01N15/082
Abstract: The invention relates to an apparatus for simultaneously injecting fluids into a plurality of samples of porous media, comprising: a plurality of holders for the samples of porous media, each holder comprising a sleeve and first and second platens, the first platen having an inlet for an injection fluid and the second platen having an outlet for a produced fluid, and the samples of porous media being arranged, in use, in each of the holders such that the first platen and second platen of each holder contact a first and second end of the sample of porous medium respectively, the inlet of each first platen being in fluid communication with an injection line for injecting fluid into the sample of porous medium arranged in the holder, the outlet of each second platen being in fluid communication with a dedicated effluent line for removing fluid produced from the sample of porous medium arranged in the holder, on-line and/or off-line analytical means for analyzing the fluids injected into each of the samples of porous media, on-line and/or off-line means for analyzing the fluids removed from each of the samples of porous media. A method of simultaneously injecting injection fluid into the samples of porous media is also provided.
Abstract translation: 本发明涉及一种用于同时将流体注入到多孔介质的多个样品中的装置，包括：用于多孔介质样品的多个保持器，每个保持器包括套筒和第一和第二压板，第一压板具有用于 注射流体和第二压板具有用于产生的流体的出口，并且多孔介质样品在使用中被布置在每个保持器中，使得每个保持器的第一压板和第二压板接触第一和第二端 分别为多孔介质的样品，每个第一压板的入口与注射管路流体连通，用于将流体注入布置在保持器中的多孔介质的样品中，每个第二压板的出口与专用流出液流体连通 用于去除由布置在保持器中的多孔介质的样品产生的流体，用于分析注入到e中的流体的在线和/或离线分析装置 多孔介质的样品，在线和/或离线装置，用于分析从多孔介质的每个样品中去除的流体。 还提供了将注入流体同时注入到多孔介质样品中的方法。
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公开(公告)号：US09261435B2
公开(公告)日：2016-02-16
申请号：US13812292
申请日：2011-07-29
Applicant: Ian Ralph Collins , John William Couves , Bogdan Costin Gagea , Arnaud Lager , Kevin John Webb
Inventor： Ian Ralph Collins , John William Couves , Bogdan Costin Gagea , Arnaud Lager , Kevin John Webb
CPC classification number: G01N1/00 , E21B43/20 , G01N15/082
Abstract: The invention relates to an apparatus for simultaneously injecting fluids into a plurality of samples of porous media, comprising: a plurality of holders for the samples of porous media, each holder comprising a sleeve and first and second platens, the first platen having an inlet for an injection fluid and the second platen having an outlet for a produced fluid, and the samples of porous media being arranged, in use, in each of the holders such that the first platen and second platen of each holder contact a first and second end of the sample of porous medium respectively, the inlet of each first platen being in fluid communication with an injection line for injecting fluid into the sample of porous medium arranged in the holder, the outlet of each second platen being in fluid communication with a dedicated effluent line for removing fluid produced from the sample of porous medium arranged in the holder, on-line and/or off-line analytical means for analyzing the fluids injected into each of the samples of porous media, on-line and/or off-line means for analyzing the fluids removed from each of the samples of porous media. A method of simultaneously injecting injection fluid into the samples of porous media is also provided.
Abstract translation: 本发明涉及一种用于同时将流体注入到多孔介质的多个样品中的装置，包括：用于多孔介质样品的多个保持器，每个保持器包括套筒和第一和第二压板，第一压板具有用于 注射流体和第二压板具有用于产生的流体的出口，并且多孔介质样品在使用中被布置在每个保持器中，使得每个保持器的第一压板和第二压板接触第一和第二端 分别为多孔介质的样品，每个第一压板的入口与注射管路流体连通，用于将流体注入布置在保持器中的多孔介质的样品中，每个第二压板的出口与专用流出液流体连通 用于去除由布置在保持器中的多孔介质的样品产生的流体，用于分析注入到e中的流体的在线和/或离线分析装置 多孔介质的样品，在线和/或离线装置，用于分析从多孔介质的每个样品中去除的流体。 还提供了将注入流体同时注入到多孔介质样品中的方法。
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公开(公告)号：US08809573B2
公开(公告)日：2014-08-19
申请号：US13138991
申请日：2010-05-06
Applicant: Gareth Gerald Armitage , Bogdan Costin Gagea , David John Law , John Glenn Sunley
Inventor： Gareth Gerald Armitage , Bogdan Costin Gagea , David John Law , John Glenn Sunley
CPC classification number: C07C51/12 , B01J29/18 , B01J2229/16 , B01J2229/36 , B01J2229/38 , C07C67/37 , C07C57/08 , C07C69/14
Abstract: A process for the production of acetic acid and/or methyl acetate by the carbonylation of methanol, methyl acetate and/or dimethyl ether with carbon monoxide in the presence of a desilicated mordenite catalyst.
Abstract translation: 在脱盐丝光沸石催化剂存在下，通过甲醇，乙酸甲酯和/或二甲醚与一氧化碳羰基化生产乙酸和/或乙酸甲酯的方法。
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公开(公告)号：US08692015B2
公开(公告)日：2014-04-08
申请号：US13138987
申请日：2010-05-06
Applicant: Evert Jan Ditzel , Bogdan Costin Gagea
Inventor： Evert Jan Ditzel , Bogdan Costin Gagea
CPC classification number: C07C51/12 , B01J29/18 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J37/10 , B01J2229/38 , C07C67/37 , C07C57/08 , C07C69/14
Abstract: Process for the production of at least one carbonylation product selected from acetic acid and methyl acetate, by carbonylating at least one carbonylatable reactant selected from methanol and reactive derivatives thereof with carbon monoxide in the presence of a catalyst. The catalyst is a mordenite which has been treated with an aqueous ammonium hydroxide solution and has a silica:alumina molar ratio of at least 10:1, and the reactive derivatives are selected from methyl acetate and dimethyl ether.
Abstract translation: 通过在催化剂存在下，将选自甲醇及其活性衍生物的至少一种羰基化反应物与一氧化碳羰基化，从而生产选自乙酸和乙酸甲酯的至少一种羰基化产物的方法。 该催化剂是已经用氢氧化铵水溶液处理的二氧化硅：氧化铝摩尔比至少为10:1的丝光沸石，反应性衍生物选自乙酸甲酯和二甲醚。
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公开(公告)号：US20120101298A1
公开(公告)日：2012-04-26
申请号：US13138990
申请日：2010-05-06
Applicant: Evert Jan Ditzel , Bogdan Costin Gagea
Inventor： Evert Jan Ditzel , Bogdan Costin Gagea
CPC classification number: B01J35/10 , B01J29/18 , B01J2229/18 , B01J2229/38 , C07C51/12 , C07C67/37 , C07C53/08 , C07C69/14
Abstract: A process for the production of acetic acid and/or methyl acetate by carbonylating methanol and/or reactive derivatives thereof with carbon monoxide in the presence of a catalyst which is a mordenite which has been treated with an aqueous basic solution containing at least one of aluminate ions and gallate ions and has a silica:X2O3 molar ratio (wherein X is A1 and/or Ga) of at least 12:1.
Abstract translation: 在催化剂的存在下，使用甲醇和/或其反应性衍生物与一氧化碳羰化来制备乙酸和/或乙酸甲酯的方法，该催化剂是已经用含有至少一种铝酸盐的碱性水溶液处理过的丝光沸石 离子和没食子酸酯离子，并且具有至少12:1的二氧化硅：X 2 O 3摩尔比（其中X是Al和/或Ga）。
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