公开(公告)号：US08398948B2

公开(公告)日：2013-03-19

申请号：US10551484

申请日：2004-03-31

申请人： Beyong-Hwan Ryu ,  Ki-Jeong Kong ,  Hyun-Ju Chang ,  Young-Min Choi ,  Jae-do Lee ,  Ha-Kyun Jung ,  Chang-Gyoun Kim ,  Han-Sung Park

发明人： Beyong-Hwan Ryu ,  Ki-Jeong Kong ,  Hyun-Ju Chang ,  Young-Min Choi ,  Jae-do Lee ,  Ha-Kyun Jung ,  Chang-Gyoun Kim ,  Han-Sung Park

IPC分类号： C01B31/0246 ,  B82Y40/00

CPC分类号： B01J23/74 ,  B01J23/755 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/166 ,  C01B2202/36 ,  D01F9/12 ,  Y02P20/544

摘要： This invention relates to a method to induce growth of carbon nanotubes using a liquid phased-hydrocarbon based material under a critical range of equilibrating between liquid and gas phases, thereby easily manipulating a required carbon source. This invention also relates to a method to facilitate easy generation of a carbon backbone of the carbon nanotube because the reaction is performed in the presence of a metal nanoparticle or a metal compound capable of spontaneously generating a seed catalyst which stimulates the growth of carbon nanotubes as well as secures safety enough for the industrial application by using a mild reaction condition within the critical range. Accordingly, this invention can produce the carbon nanotube with high transition efficiency under a mild condition with a relatively lower temperature and pressure than those in conventional gas phased-methods without using a costly equipment, thereby cost-effectively producing the carbon nanotube in large quantities.

摘要翻译： 本发明涉及在液相和气相之间的平衡临界范围内使用液相烃基材料诱导碳纳米管生长的方法，从而容易地操纵所需的碳源。 本发明还涉及一种促进碳纳米管碳骨架容易生成的方法，因为反应是在能够自发产生刺激碳纳米管生长的种子催化剂的金属纳米颗粒或金属化合物的存在下进行的， 以及通过在临界范围内使用温和的反应条件来确保工业应用的安全性。 因此，本发明可以在没有使用昂贵的设备的情况下，在比常规气相分离方法相对较低的温度和温度的温和条件下生产具有高过渡效率的碳纳米管，从而大量地成本有效地制造碳纳米管。

公开(公告)号：US20070160522A1

公开(公告)日：2007-07-12

申请号：US10551484

申请日：2004-03-31

申请人： Beyong-Hwan Ryu ,  Ki-Jeong Kong ,  Hyun-Ju Chang ,  Young-Min Choi ,  Jae-do Lee ,  Ha-Kyun Jung ,  Chang-Gyoun Kim ,  Han-Sung Park

发明人： Beyong-Hwan Ryu ,  Ki-Jeong Kong ,  Hyun-Ju Chang ,  Young-Min Choi ,  Jae-do Lee ,  Ha-Kyun Jung ,  Chang-Gyoun Kim ,  Han-Sung Park

IPC分类号： D01F9/12

CPC分类号： B01J23/74 ,  B01J23/755 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/166 ,  C01B2202/36 ,  D01F9/12 ,  Y02P20/544

摘要： This invention relates to a method to induce growth of carbon nanotubes using a liquid phased-hydrocarbon based material under a critical range of equilibrating between liquid and gas phases, thereby easily manipulating a required carbon source. This invention also relates to a method to facilitate easy generation of a carbon backbone of the carbon nanotube because the reaction is performed in the presence of a metal nanoparticle or a metal compound capable of spontaneously generating a seed catalyst which stimulates the growth of carbon nanotubes as well as secures safety enough for the industrial application by using a mild reaction condition within the critical range. Accordingly, this invention can produce the carbon nanotube with high transition efficiency under a mild condition with a relatively lower temperature and pressure than those in conventional gas phased-methods without using a costly equipment, thereby cost-effectively producing the carbon nanotube in large quantities.

摘要翻译： 本发明涉及在液相和气相之间的平衡临界范围内使用液相烃基材料诱导碳纳米管生长的方法，从而容易地操纵所需的碳源。 本发明还涉及一种促进碳纳米管碳骨架容易生成的方法，因为反应是在能够自发产生刺激碳纳米管生长的种子催化剂的金属纳米颗粒或金属化合物的存在下进行的， 以及通过在临界范围内使用温和的反应条件来确保工业应用的安全性。 因此，本发明可以在没有使用昂贵的设备的情况下，在比常规气相分离方法相对较低的温度和温度的温和条件下生产具有高过渡效率的碳纳米管，从而大量地成本有效地制造碳纳米管。

公开(公告)号：US08030507B2

公开(公告)日：2011-10-04

申请号：US12407526

申请日：2009-03-19

申请人： Chang Gyoun Kim ,  Taek-Mo Chung ,  Young Kuk Lee ,  Ki-Seok An ,  Sun Sook Lee ,  Beyong Hwan Ryu ,  Se Jin Jang

发明人： Chang Gyoun Kim ,  Taek-Mo Chung ,  Young Kuk Lee ,  Ki-Seok An ,  Sun Sook Lee ,  Beyong Hwan Ryu ,  Se Jin Jang

IPC分类号： C07F7/22

CPC分类号： C07F7/2204

摘要： The present invention relates to novel tin amino-alkoxide complexes and a method for preparing the same, precisely novel tin amino-alkoxide complexes represented by formula 1 and useful as a precursor for tin and tin oxide thin films and a precursor for the production of nano-sized tin and tin oxide particles and a method for preparing the same. In formula 1, A is linear or branched (C2-C10) alkylene substituted or not substituted with halogen; R1 and R2 are independently linear or branched (C1-C7) alkyl substituted or not substituted with halogen. Sn[O-A-NR1R2]2  [Formula 1]

摘要翻译： 本发明涉及新的锡氨基 - 烷氧化物络合物及其制备方法，精细新型的由式1表示的锡氨基 - 醇盐络合物，可用作锡和锡氧化物薄膜的前体和用于生产纳米粒子的前体 锡和锡氧化物颗粒及其制备方法。 在式1中，A是被卤素取代或未被取代的直链或支链（C2-C10）亚烷基; R1和R2独立地是被卤素取代或未被取代的直链或支链（C1-C7）烷基。 Sn [O-A-NR1R2] 2 [式1]

公开(公告)号：US20090275770A1

公开(公告)日：2009-11-05

申请号：US12407526

申请日：2009-03-19

申请人： Chang Gyoun KIM ,  Taek-Mo CHUNG ,  Young Kuk LEE ,  Ki-Seok AN ,  Sun Sook LEE ,  Beyong Hwan RYU ,  Se Jin JANG

发明人： Chang Gyoun KIM ,  Taek-Mo CHUNG ,  Young Kuk LEE ,  Ki-Seok AN ,  Sun Sook LEE ,  Beyong Hwan RYU ,  Se Jin JANG

IPC分类号： C07F7/22

CPC分类号： C07F7/2204

摘要： The present invention relates to novel tin amino-alkoxide complexes and a method for preparing the same, precisely novel tin amino-alkoxide complexes represented by formula 1 and useful as a precursor for tin and tin oxide thin films and a precursor for the production of nano-sized tin and tin oxide particles and a method for preparing the same. In formula 1, A is linear or branched (C2-C10) alkylene substituted or not substituted with halogen; R1 and R2 are independently linear or branched (C1-C7) alkyl substituted or not substituted with halogen. Sn[O-A-NR1R2]2  [Formula 1]

摘要翻译： 本发明涉及新的锡氨基 - 烷氧化物络合物及其制备方法，精细新型的由式1表示的锡氨基 - 醇盐络合物，可用作锡和锡氧化物薄膜的前体和用于生产纳米粒子的前体 锡和锡氧化物颗粒及其制备方法。 在式1中，A是被卤素取代或未被取代的直链或支链（C2-C10）亚烷基; R1和R2独立地是被卤素取代或未被取代的直链或支链（C1-C7）烷基。 Sn [O-A-NR1R2] 2 [式1]

公开(公告)号：US07854826B2

公开(公告)日：2010-12-21

申请号：US11952310

申请日：2007-12-07

申请人： Hye Mi So ,  Jeong O Lee ,  Yong Hwan Kim ,  Ki Hoon Won ,  Hyun Ju Chang ,  Beyong Hwan Ryu ,  Ki Jeong Kong ,  Young Min Choi

发明人： Hye Mi So ,  Jeong O Lee ,  Yong Hwan Kim ,  Ki Hoon Won ,  Hyun Ju Chang ,  Beyong Hwan Ryu ,  Ki Jeong Kong ,  Young Min Choi

IPC分类号： C12M1/00 ,  C12N11/00

CPC分类号： G01N33/5308 ,  B82Y10/00 ,  B82Y30/00 ,  G01N27/4145 ,  G01N27/4146 ,  G01N33/551

摘要： The present invention relates to a carbon nanotube transistor biosensor with aptamers and a method for detecting a target material using the same, more particularly to a carbon nanotube transistor biosensor recognizing the target material, i.e., a specific molecule (such as a protein, a peptide, an amino acid, and an organic/inorganic compound) by using DNA aptamers and a method for screening a target material using the same. In the biosensor of the present invention, the aptamers binding specifically to a particular protein are adsorbed on a carbon nanotube constituting the channel domain of carbon nanotube transistor to easily detect/identify a particular protein via the electric conductivity of carbon nanotube that varies if the particular protein is exposed to corresponding aptamers.

摘要翻译： 本发明涉及具有适体的碳纳米管晶体管生物传感器和使用其的靶材料的检测方法，更具体地说，涉及识别靶材料的碳纳米管晶体管生物传感器，即特定分子（例如蛋白质，肽 ，氨基酸和有机/无机化合物）和使用其的筛选靶材的方法。 在本发明的生物传感器中，特异性结合特定蛋白质的适体被吸附在构成碳纳米管晶体管的沟道区域的碳纳米管上，以容易地通过碳纳米管的电导率来检测/识别特定的蛋白质， 蛋白质暴露于相应的适体。