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1.发明申请HETEROGENEOUS, COMPOSITE, CARBONACEOUS CATALYST SYSTEM AND METHODS THAT USE CATALYTICALLY ACTIVE GOLD 有权异构体，复合材料，碳纳米管催化剂体系和使用催化活性金的方法公开(公告)号：US20110280781A1
公开(公告)日：2011-11-17
申请号：US13167388
申请日：2011-06-23
申请人： John T. Brady , Marvin E. Jones , Larry A. Brey , Gina M. Buccellato , Craig S. Chamberlain , John S. Huberly , Allen R. Siedle , Thomas E. Wood , Badri Veeraraghavan , Duane D. Fansler
发明人： John T. Brady , Marvin E. Jones , Larry A. Brey , Gina M. Buccellato , Craig S. Chamberlain , John S. Huberly , Allen R. Siedle , Thomas E. Wood , Badri Veeraraghavan , Duane D. Fansler
CPC分类号： A62D3/38 , B01D53/864 , B01D2255/106 , B01D2257/502 , B01J23/52 , B01J35/0013 , Y10S977/90
摘要： Heterogeneous catalyst systems, methods of making these systems, and methods of using these systems, wherein catalytically active gold is deposited onto composite support media. The composite support media is formed by providing nanoporous material on at least a portion of the surfaces of carbonaceous host material. In representative embodiments, relatively fine, nanoporous guest particles are coated or otherwise provided on surfaces of relatively coarser activated carbon particles. Catalytically active gold may be deposited onto one or both of the guest or host materials either before or after the guest and host materials are combined to from the composite host material. PVD is the preferred catalyst system of depositing gold.
摘要翻译： 非均相催化剂体系，制备这些体系的方法以及使用这些体系的方法，其中将催化活性金沉积在复合载体介质上。 复合载体介质通过在碳质主体材料的至少一部分表面上提供纳米多孔材料而形成。 在代表性的实施方案中，相对较细的纳米多孔客体颗粒被涂覆或以其它方式提供在相对较粗的活性炭颗粒的表面上。 催化活性金可以在客体和主体材料组合之前或之后沉积到客体或主体材料中的一个或两个上，以形成复合主体材料。 PVD是沉积金的优选催化剂体系。
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2.发明授权Catalysts, activating agents, support media, and related methodologies useful for making catalyst systems especially when the catalyst is deposited onto the support media using physical vapor deposition 有权催化剂，活化剂，载体介质和相关方法可用于制备催化剂体系，特别是当使用物理气相沉积将催化剂沉积到载体介质上时公开(公告)号：US07989384B2
公开(公告)日：2011-08-02
申请号：US12756635
申请日：2010-04-08
申请人： Larry A. Brey , Thomas E. Wood , Gina M. Buccellato , Marvin E. Jones , Craig S. Chamberlain , Allen R. Siedle
发明人： Larry A. Brey , Thomas E. Wood , Gina M. Buccellato , Marvin E. Jones , Craig S. Chamberlain , Allen R. Siedle
IPC分类号： B01J21/18 , B01J23/00 , B01J23/02 , B01J23/06 , B01J23/04 , C01D7/37 , C01B31/20 , C01B31/32
CPC分类号： B01J23/52 , A62D3/38 , A62D9/00 , B01D53/44 , B01D53/62 , B01D53/944 , B01D53/945 , B01D2255/106 , B01D2257/502 , B01J21/04 , B01J21/18 , B01J23/02 , B01J23/66 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/023 , B01J37/0238 , B01J37/0248 , B01J37/347 , B01J37/349 , B82Y30/00 , Y02A50/2324 , Y02A50/2341 , Y02T10/22 , Y10S977/90 , Y10S977/903 , Y10S977/904 , Y10S977/963
摘要： Use of physical vapor deposition methodologies to deposit nanoscale gold on activating support media makes the use of catalytically active gold dramatically easier and opens the door to significant improvements associated with developing, making, and using gold-based, catalytic systems. The present invention, therefore, relates to novel features, ingredients, and formulations of gold-based, heterogeneous catalyst systems generally comprising nanoscale gold deposited onto a nanoporous support.
摘要翻译： 使用物理气相沉积方法将纳米级金沉积在活化载体介质上，使得催化活性金的使用显着更容易，并为与金基催化体系的开发，制造和使用相关的显着改进打开了大门。 因此，本发明涉及通常包含沉积在纳米多孔载体上的纳米级金的基于金的多相催化剂体系的新颖特征，成分和配方。
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公开(公告)号：US20100050583A1
公开(公告)日：2010-03-04
申请号：US12552367
申请日：2009-09-02
申请人： Lisa M. Croll , Jeffrey R. Dahn , Allen R. Siedle , Jock W.H. Smith , Phillippe Westreich , Thomas E. Wood
发明人： Lisa M. Croll , Jeffrey R. Dahn , Allen R. Siedle , Jock W.H. Smith , Phillippe Westreich , Thomas E. Wood
CPC分类号： B01D53/02 , B01D2253/102 , B01D2255/20761 , B01D2255/20769 , B01D2259/4541 , B01J20/02 , B01J20/0218 , B01J20/0233 , B01J20/0237 , B01J20/0244 , B01J20/0259 , B01J20/0288 , B01J20/0296 , B01J20/08 , B01J20/103 , B01J20/18 , B01J20/20 , B01J20/223 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J2220/66
摘要： A filter for removing contaminants from air. The filter includes (a) a substrate that does not have any volatile ammonia on the surface thereof; (b) copper that has been impregnated onto the substrate; and (c) molybdenum and/or tungsten that has been impregnated onto the substrate. The filter can be made using an aqueous solution(s) that contains one or more of a first copper salt and a second salt that include a polynuclear anion that contains molybdenum, tungsten, or both. Because the metals can be impregnated onto the substrate surface without using an ammonium-based solution, the need to manage ammonia off-gassing is avoided. Further, no volatile ammonia would be present on the resulting substrate surface.
摘要翻译： 用于从空气中去除污染物的过滤器。 过滤器包括（a）在其表面上不具有任何挥发性氨的基底; （b）浸渍在基材上的铜; 和（c）浸渍在基材上的钼和/或钨。 过滤器可以使用含有一种或多种第一铜盐和第二盐的水溶液制备，所述第二种盐包括含有钼，钨或两者的多核阴离子。 由于金属可以浸渍在基板表面上而不使用铵基溶液，所以避免了管理氨气的需要。 此外，在所得基材表面上不会存在挥发性氨。
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公开(公告)号：US4556720A
公开(公告)日：1985-12-03
申请号：US541129
申请日：1983-10-12
IPC分类号： B01J31/00 , C07B31/00 , C07B35/08 , C07B37/10 , C07B41/06 , C07B61/00 , C07C1/00 , C07C2/48 , C07C5/22 , C07C5/25 , C07C11/00 , C07C15/00 , C07C45/00 , C07C45/50 , C07C67/00 , C07F15/00
CPC分类号： C07F15/008 , C07C17/281 , C07C2/48 , C07C45/50 , C07C5/2293 , C07C5/2593 , C07C2531/22 , C07C2531/24
摘要： Coordination compounds of rhodium are solid salts having donor ligands of [(aryl).sub.3 P].sub.3 Rh.sup.+ and a non-coordinated counterion derived from a fluorochemical acid, the salts having the formula:[(aryl).sub.3 P].sub.3 Rh.sup.+ (counterion).sup.-.The salts are prepared by reacting [(aryl).sub.3 P].sub.4 RhH, which is an uncharged rhodium hydride, with a fluorochemical acid selected form acids having the formulae:HC(R)(SO.sub.2 R.sub.f).sub.2, R.sub.f 'SO.sub.3 H, and HN(SO.sub.2 R.sub.f).sub.2wherein R.sub.f and R.sub.f ' are perfluoroalkyl groups and R is lower alkyl substituted or unsubstituted phenyl, hydrogen, Cl, SO.sub.2 R.sub.f or R.sub.f. Carbonylation of the [(aryl).sub.3 P].sub.3 Rh.sup.+ (counterion).sup.- compounds of this invention, e.g., by contacting the salts of the invention with carbon monoxide gas, produces salts having the formula:[(aryl).sub.3 P].sub.3 Rh(CO).sub.n.sup.+ (counterion).sup.-,wherein n is 1 or 2, and (counterion).sup.- is as defined above. These carbonylated derivatives as well as the above-described precursor salts are useful as catalysts in organic transformation reactions, such as isomerization, cyclization and hydroformylation reactions.
摘要翻译： 铑的配位化合物是具有[（芳基）3P] 3Rh +的供体配体和衍生自含氟化合物酸的非配位抗衡离子的固体盐，其具有下式：[（芳基）3 P] 3Rh +（抗衡离子） - 。 通过使不饱和氢化铑的[（芳基）3 P] 4RhH与选自具有下列通式的酸的含氟化合物反应来制备盐：HC（R）（SO 2 R f）2，Rf'SO 3 H和HN（SO 2 R f） 2其中Rf和Rf'是全氟烷基，R是低级烷基取代或未取代的苯基，氢，Cl，SO2Rf或Rf。 [（芳基）3P] 3Rh +（抗衡离子）化合物的羰基化，例如通过使本发明的盐与一氧化碳气体接触，产生具有下式的盐：[（芳基）3 P] 3Rh（CO）n + （抗衡离子） - ，其中n为1或2，和（抗衡离子） - 如上所定义。 这些羰基化衍生物以及上述前体盐可用作有机转化反应中的催化剂，例如异构化，环化和加氢甲酰化反应。
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5.发明授权Palladium (II) bis (hexafluoroacetylacetonate), adducts derived therefrom and uses thereof 失效钯（II）双（六氟乙酰丙酮化物），由其衍生的加合物及其用途
公开(公告)号：US4500569A
公开(公告)日：1985-02-19
申请号：US509956
申请日：1983-06-30
申请人： Allen R. Siedle
发明人： Allen R. Siedle
CPC分类号： C23C18/1879 , B01J23/44 , C07C45/77 , C07C49/92 , C07F15/0066 , C23C18/30
摘要： Preparation of palladium(II) bis(hexafluoroacetylacetonate) and adducts derived therefrom are disclosed, said adducts having the formulaPd(F.sub.6 ACAC).sub.2.L.sub.nwherein L is a Lewis base selected from certain classes, and n is an integer from 1 to 4. These compounds are useful in preparing catalytic and primer surfaces of elemental palladium.
摘要翻译： 公开了二（六氟乙酰基丙酮酸钯（II））和由其衍生的加合物的制备，所述加合物具有式Pd（F6ACAC）2 .Ln，其中L是选自某些类别的路易斯碱，n是1至4的整数。 这些化合物可用于制备元素钯的催化和底漆表面。
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6.发明申请ADDUCTS OF AMINES AND POLYCARBOXYLIC ACIDS, AND FILTER MEDIA COMPRISING SUCH ADDUCTS 有权氨基酸和聚碳酸的添加剂和包含这些添加剂的过滤介质公开(公告)号：US20110171076A1
公开(公告)日：2011-07-14
申请号：US13018863
申请日：2011-02-01
CPC分类号： C08K5/17 , B01J20/20 , B01J20/22 , B01J20/3204 , B01J20/3255 , B01J20/3293
摘要： Herein are disclosed adducts of amines and polycarboxylic acids, and methods of making such adducts. Such adducts can be used to remove cyanogen chloride. Also disclosed are methods of providing such adducts on supports to form filter media. Also disclosed are methods of combining such filter media with catalysts and/or with porous polymeric webs to form filter systems.
摘要翻译： 本文公开了胺和多元羧酸的加合物，以及制备这种加合物的方法。 这种加合物可用于除去氯化氰。 还公开了在载体上提供这种加合物以形成过滤介质的方法。 还公开了将这种过滤介质与催化剂和/或与多孔聚合物网结合以形成过滤系统的方法。
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7.发明授权Adducts of amines and polycarboxylic acids, and filter media comprising such adducts 有权胺和多元羧酸的加合物和包含这种加合物的过滤介质公开(公告)号：US07902115B2
公开(公告)日：2011-03-08
申请号：US12388647
申请日：2009-02-19
CPC分类号： C08K5/17 , B01J20/20 , B01J20/22 , B01J20/3204 , B01J20/3255 , B01J20/3293
摘要： Herein are disclosed adducts of amines and polycarboxylic acids, and methods of making such adducts. Such adducts can be used to remove cyanogen chloride. Also disclosed are methods of providing such adducts on supports to form filter media. Also disclosed are methods of combining such filter media with catalysts and/or with porous polymeric webs to form filter systems.
摘要翻译： 本文公开了胺和多元羧酸的加合物，以及制备这种加合物的方法。 这种加合物可用于除去氯化氰。 还公开了在载体上提供这种加合物以形成过滤介质的方法。 还公开了将这种过滤介质与催化剂和/或与多孔聚合物网结合以形成过滤系统的方法。
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8.发明申请CATALYSTS, ACTIVATING AGENTS, SUPPORT MEDIA, AND RELATED METHODOLOGIES USEFUL FOR MAKING CATALYST SYSTEMS ESPECIALLY WHEN THE CATALYST IS DEPOSITED ONTO THE SUPPORT MEDIA USING PHYSICAL VAPOR DEPOSITION 有权催化剂，活化剂，支持介质和相关方法学有用的制备催化剂体系，特别是当催化剂沉积在使用物理蒸气沉积物的支持介质公开(公告)号：US20100197481A1
公开(公告)日：2010-08-05
申请号：US12756635
申请日：2010-04-08
申请人： LARRY A. BREY , Thomas E. Wood , Gina M. Buccellato , Marvin E. Jones , Craig S. Chamberlain , Allen R. Siedle
发明人： LARRY A. BREY , Thomas E. Wood , Gina M. Buccellato , Marvin E. Jones , Craig S. Chamberlain , Allen R. Siedle
CPC分类号： B01J23/52 , A62D3/38 , A62D9/00 , B01D53/44 , B01D53/62 , B01D53/944 , B01D53/945 , B01D2255/106 , B01D2257/502 , B01J21/04 , B01J21/18 , B01J23/02 , B01J23/66 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/023 , B01J37/0238 , B01J37/0248 , B01J37/347 , B01J37/349 , B82Y30/00 , Y02A50/2324 , Y02A50/2341 , Y02T10/22 , Y10S977/90 , Y10S977/903 , Y10S977/904 , Y10S977/963
摘要： Use of physical vapor deposition methodologies to deposit nanoscale gold on activating support media makes the use of catalytically active gold dramatically easier and opens the door to significant improvements associated with developing, making, and using gold-based, catalytic systems. The present invention, therefore, relates to novel features, ingredients, and formulations of gold-based, heterogeneous catalyst systems generally comprising nanoscale gold deposited onto a nanoporous support.
摘要翻译： 使用物理气相沉积方法将纳米级金沉积在活化载体介质上，使得催化活性金的使用显着更容易，并为与金基催化体系的开发，制造和使用相关的显着改进打开了大门。 因此，本发明涉及通常包含沉积在纳米多孔载体上的纳米级金的基于金的多相催化剂体系的新颖特征，成分和配方。
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9.发明申请ADDUCTS OF AMINES AND POLYCARBOXYLIC ACIDS, AND FILTER MEDIA COMPRISING SUCH ADDUCTS 有权氨基酸和聚碳酸的添加剂和包含这些添加剂的过滤介质公开(公告)号：US20090215618A1
公开(公告)日：2009-08-27
申请号：US12388647
申请日：2009-02-19
CPC分类号： C08K5/17 , B01J20/20 , B01J20/22 , B01J20/3204 , B01J20/3255 , B01J20/3293
摘要： Herein are disclosed adducts of amines and polycarboxylic acids, and methods of making such adducts. Such adducts can be used to remove cyanogen chloride. Also disclosed are methods of providing such adducts on supports to form filter media. Also disclosed are methods of combining such filter media with catalysts and/or with porous polymeric webs to form filter systems.
摘要翻译： 本文公开了胺和多元羧酸的加合物，以及制备这种加合物的方法。 这种加合物可用于除去氯化氰。 还公开了在载体上提供这种加合物以形成过滤介质的方法。 还公开了将这种过滤介质与催化剂和/或与多孔聚合物网结合以形成过滤系统的方法。
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公开(公告)号：US06630231B2
公开(公告)日：2003-10-07
申请号：US09809446
申请日：2001-03-15
IPC分类号： B32B2704
CPC分类号： B32B5/26 , B32B5/022 , B32B27/32 , B32B27/36 , B32B38/0008 , B32B2255/02 , B32B2255/26 , B32B2260/021 , B32B2262/0253 , B32B2305/20 , B32B2307/412 , B32B2310/0445 , B32B2310/14 , B32B2323/10 , B32B2367/00 , D01D5/423 , Y10T428/24355 , Y10T428/24994 , Y10T428/2904 , Y10T428/2913 , Y10T428/2924 , Y10T428/2929 , Y10T428/2973 , Y10T428/2976 , Y10T442/613
摘要： A composite formed of a polymer matrix phase having a reinforcement phase including polymeric microfibers. The microfibers are preferably formed of a highly oriented polymer, having a high modulus value and a large surface area. The large surface area can serve to tightly bind the microfibers to the polymer matrix phase. The microfibers can be provided as a fully- or partially-microfibrillated film, as a non-woven web of entangled microfibers, or as a pulp having free fibers. The microfibers can be embedded in, or impregnated with, a polymer or polymer precursor. Some composite articles are formed from thermoset resins cured about a highly oriented polypropylene microfiber reinforcement phase, providing a strong, tough, moisture resistant article. One composite includes a matrix and reinforcement formed of the same material type and having substantially equal refractive indices, allowing the composite to be optically clear.
摘要翻译： 由具有包含聚合微纤维的增强相的聚合物基质相形成的复合材料。 微纤维优选由具有高模量值和大表面积的高取向聚合物形成。 大的表面积可用于将微纤维紧密地结合到聚合物基质相。 微纤维可以作为完全或部分微纤化的膜，作为缠结的微纤维的无纺网或作为具有游离纤维的纸浆提供。 微纤维可以嵌入或浸渍聚合物或聚合物前体。 一些复合制品由热固性树脂形成，该热固性树脂围绕高度取向的聚丙烯微纤维增强相固化，提供强的，坚韧的，防潮的制品。 一种复合材料包括由相同材料类型形成并具有基本上相等的折射率的基体和增强材料，允许复合材料是光学透明的。
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