公开(公告)号：US07981372B2

公开(公告)日：2011-07-19

申请号：US12086194

申请日：2006-11-24

申请人： Yoshinori Yamazaki ,  Saburo Maruko ,  Shingo Komori

发明人： Yoshinori Yamazaki ,  Saburo Maruko ,  Shingo Komori

IPC分类号： B01J8/04

CPC分类号： C01B3/38 ,  B01J8/0446 ,  B01J8/0496 ,  B01J2208/00309 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/066 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1217 ,  C01B2203/1235 ,  C01B2203/1252

摘要： An oxidative autothermal reformer including a reforming layer at least partially filled with a reforming catalyst for producing a reformed gas composed mainly of hydrogen through a reforming reaction by contacting a mixture of a hydrocarbon or an aliphatic alcohol and steam with the reforming catalyst; and an oxidative exothermic layer at least partially filled with an oxidation catalyst for generating heat by oxidizing a part of the reformed gas, in which the reforming layer is disposed at an upstream side of the oxidative exothermic layer; the reforming layer and the oxidative exothermic layer are in the form of a cylinder and have a triple circular tube structure formed by disposing an inner reforming layer, an oxidative exothermic layer and an outer reforming layer from the inside in a radial direction in this order; and at least a part of the reforming catalyst filled in the inner reforming layer and the outer reforming layer contains Ru metal.

摘要翻译： 一种氧化自热重整器，其包括至少部分填充有重整催化剂的重整层，所述重整催化剂用于通过使烃或脂族醇和蒸汽的混合物与所述重整催化剂接触而通过重整反应来主要由氢气组成的重整气体; 以及至少部分填充有氧化催化剂的氧化性放热层，所述氧化催化剂通过氧化部分所述重整气体而发生热量，其中所述重整层设置在所述氧化性放热层的上游侧; 重整层和氧化性放热层为圆柱形，并具有通过沿径向从内侧设置内部重整层，氧化性放热层和外部重整层而形成的三重圆形管状结构。 并且填充在内部重整层和外部重整层中的重整催化剂的至少一部分含有Ru金属。

公开(公告)号：US07938955B2

公开(公告)日：2011-05-10

申请号：US11793209

申请日：2005-12-21

申请人： Yasuhiro Araki ,  Katsuaki Ishida

发明人： Yasuhiro Araki ,  Katsuaki Ishida

IPC分类号： C10G45/04 ,  C07C7/12

CPC分类号： C10G25/00 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J35/0006 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2300/308 ,  C10G2400/06

摘要： Provided are a method for producing a super-low sulfur gas oil blending component or a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm, under relatively mild conditions, without greatly increasing the hydrogen consumption and without remarkably decreasing the aromatic content; and a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm which exhibits a high heating value, is excellent in fuel economy and output power, and is free from an adverse effect on a sealing rubber member or the like used in the fuel injection system and thus does not cause the leakage of a fuel. A method for producing a super-low sulfur gas oil blending component or a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm is also disclosed.

摘要翻译： 提供一种在相对温和的条件下生产硫含量小于5质量ppm的超低硫油混合组分或超低硫油组合物的方法，而不会大大增加氢消耗并且不显着降低 芳香含量; 硫含量低于5质量ppm的超低硫磺油组合物，具有高的发热量，燃料经济性和输出功率优异，并且对密封橡胶构件等没有不利影响 在燃料喷射系统中使用，因此不会导致燃料泄漏。 还公开了一种硫含量小于5质量ppm的超低硫油混合组分或超低硫含硫油组合物的制备方法。

公开(公告)号：US20090000990A1

公开(公告)日：2009-01-01

申请号：US10586606

申请日：2005-01-27

申请人： Yasuhiro Toida

发明人： Yasuhiro Toida

IPC分类号： C10G17/02

CPC分类号： B01J27/053 ,  B01J23/30 ,  C10G2300/1051 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2400/08

摘要： A method of desulfurizing/refining a hydrocarbon oil by which sulfur compounds are diminished to an extremely low concentration at a relatively low equipment cost and operating cost. The method of desulfurizing/refining a hydrocarbon oil comprises bringing a hydrocarbon oil containing at least one sulfur compound selected from the group consisting of thiophene compounds, benzothiophene compounds, and dibenzothiophene compounds and optionally further containing aromatic hydrocarbons into contact with a solid acid catalyst and/or an activated carbon having a transition metal oxide supported thereon to thereby desulfurize the oil. The solid acid catalyst preferably is a solid ultrastrong-acid catalyst selected among sulfuric acid radical/zirconia, sulfuric acid radical/alumina, sulfuric acid radical/tin oxide, sulfuric acid radical/iron oxide, tungstic acid/zirconia, and tungstic acid/tin oxide.

摘要翻译： 在相对低的设备成本和操作成本下，硫化合物在其中降低至极低浓度的烃油的脱硫/精炼方法。 烃油的脱硫/精制方法包括将含有选自噻吩化合物，苯并噻吩化合物和二苯并噻吩化合物中的至少一种硫化合物的烃油和任选地进一步含有芳族烃与固体酸催化剂和/ 或负载有过渡金属氧化物的活性炭，从而使油脱硫。 固体酸催化剂优选为选自硫酸根/氧化锆，硫酸根/氧化铝，硫酸根/氧化锡，硫酸根/氧化铁，钨酸/氧化锆和钨酸/锡的固体超强酸催化剂 氧化物。

公开(公告)号：US07335618B2

公开(公告)日：2008-02-26

申请号：US10310903

申请日：2002-12-06

申请人： Hiroki Koyama ,  Toru Saito ,  Yoshiki Iwata ,  Chikanori Nakaoka

发明人： Hiroki Koyama ,  Toru Saito ,  Yoshiki Iwata ,  Chikanori Nakaoka

IPC分类号： B01J21/00 ,  B01J29/00 ,  C01G45/00 ,  C01G39/00

CPC分类号： C10G45/04 ,  B01J23/85 ,  B01J23/8877 ,  B01J23/94 ,  B01J35/023 ,  B01J35/10 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0036 ,  C10G45/08 ,  C22B7/009 ,  C22B34/22 ,  C22B34/225 ,  Y02P10/214 ,  Y02P10/23

摘要： A heavy oil is hydrorefined using a hydrorefining catalyst. A spent hydrorefining catalyst whose activity has decreased is heat treated (S1) and pulverized to obtained a regenerated powder (S2). This regenerated powder is fractionated according to its metal content (S3), formed (S6), dried (S7), and calcined (S7) to manufacture a regenerated catalyst whose volume of pores with a diameter of 50 to 2000 nm is at least 0.2 ml/g, and whose volume of pores with a diameter over 2000 nm is no more than 0.1 mL/g. Using this regenerated catalyst, a heavy oil containing at least 45 wt ppm vanadium and nickel as combined metal elements is hydrodemetalized, and the vanadium and nickel are recovered from the used regenerated catalyst (SS1). Through hydrorefining, the metal components are recovered more efficiently, and the spent catalyst can be reused to manufacture a regenerated catalyst that exhibits high reaction, activity.

摘要翻译： 使用加氢精制催化剂对重油进行加氢精制。 热处理的活性降低的预加氢精制催化剂（S1）粉碎，得到再生粉末（S 2）。 根据其形成的（S 6）的金属含量（S 3），干燥（S 7）和煅烧（S 7）将该再生粉末分馏，制造直径为50〜2000nm的孔体积的再生催化剂 至少0.2ml / g，其体积的直径大于2000nm的孔不超过0.1mL / g。 使用这种再生催化剂，将含有至少45重量ppm的钒和镍作为组合金属元素的重油加氢脱矿，并且从使用的再生催化剂（SS 1）中回收钒和镍。 通过加氢精制，更有效地回收金属成分，废旧催化剂可以再利用来制造出具有高反应活性的再生催化剂。

公开(公告)号：US20070261994A1

公开(公告)日：2007-11-15

申请号：US11793209

申请日：2005-12-21

申请人： Yasuhiro Araki ,  Katsuaki Ishida

发明人： Yasuhiro Araki ,  Katsuaki Ishida

IPC分类号： C10G45/60

CPC分类号： C10G25/00 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J35/0006 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2300/308 ,  C10G2400/06

摘要： Provided are a method for producing a super-low sulfur gas oil blending component or a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm, under relatively mild conditions, without greatly increasing the hydrogen consumption and without remarkably decreasing the aromatic content; and a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm which exhibits a high heating value, is excellent in fuel economy and output power, and is free from an adverse effect on a sealing rubber member or the like used in the fuel injection system and thus does not cause the leakage of a fuel. A method for producing a super-low sulfur gas oil blending component or a super-low sulfur gas oil composition having a sulfur content of less than 5 mass ppm is also disclosed.

摘要翻译： 提供一种在相对温和的条件下生产硫含量小于5质量ppm的超低硫油混合组分或超低硫油组合物的方法，而不会大大增加氢消耗并且不显着降低 芳香含量; 硫含量低于5质量ppm的超低硫磺油组合物，具有高的发热量，燃料经济性和输出功率优异，并且对密封橡胶构件等没有不利影响 在燃料喷射系统中使用，因此不会导致燃料泄漏。 还公开了一种硫含量小于5质量ppm的超低硫油混合组分或超低硫含硫油组合物的制备方法。

公开(公告)号：US07026268B2

公开(公告)日：2006-04-11

申请号：US10468925

申请日：2002-02-28

申请人： Satoshi Furuta ,  Minoru Ogawa

发明人： Satoshi Furuta ,  Minoru Ogawa

IPC分类号： B01J27/053 ,  B01J27/043 ,  B01J27/045 ,  C07C15/00 ,  C07C5/22

CPC分类号： B01J27/053 ,  B01J23/42 ,  B01J29/068 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061

摘要： The present invention provides a concentration distribution for a platinum group metal component in a catalyst with which catalyst activity can be increased, and to provide a method for supporting a platinum group metal with which this concentration distribution can be achieved. The present invention is a solid acid catalyst that is made up of porous catalyst pellets exhibiting solid acid characteristics, and a platinum group metal component supported by these catalyst pellets, and that is used in an acid-catalyzed reaction, in which a quotient of dividing the standard deviation of the concentration in a platinum group metal component concentration distribution in the catalyst by an average concentration is 0.4 or less. The method for preparing this catalyst involves a step of preparing a support solution containing a platinum group metal as a cation, and a step of impregnating crystalline, porous catalyst pellets exhibiting solid acid characteristics with this support solution. The present invention also provides a method for isomerizing a hydrocarbon, wherein a solid acid catalyst is brought into contact with a hydrocarbon including at least 70 wt % of a saturated hydrocarbon component having 4 to 10 carbon atoms.

摘要翻译： 本发明提供催化剂中的铂族金属成分的浓度分布，能够提高催化剂活性，并提供一种能够实现该浓度分布的铂族金属的担载方法。 本发明是一种固体酸催化剂，其由显示固体酸性特征的多孔催化剂颗粒和由这些催化剂颗粒负载的铂族金属组分组成，并用于酸催化反应中，其中分离的商 铂族金属成分浓度分布在催化剂中的浓度的平均浓度的标准偏差为0.4以下。 制备该催化剂的方法包括制备包含铂族金属作为阳离子的载体溶液的步骤，以及用该载体溶液浸渍显示出固体酸特性的结晶多孔催化剂颗粒的步骤。 本发明还提供一种烃的异构化方法，其中固体酸催化剂与包含至少70重量％的具有4-10个碳原子的饱和烃组分的烃接触。

公开(公告)号：US07001503B1

公开(公告)日：2006-02-21

申请号：US09889241

申请日：2000-01-14

申请人： Hiroki Koyama ,  Yuichi Takahashi

发明人： Hiroki Koyama ,  Yuichi Takahashi

IPC分类号： C10G45/02 ,  C10G65/02 ,  B01J8/04

CPC分类号： C10G49/002 ,  C10G65/04

摘要： A unit for hydrorefining of hydrocarbon crude oil comprising sulfur-containing compounds comprises first catalyst layer 33 and second catalyst layer 38, top space 34 for separating vapor component and liquid component, bottom space 36, and valve tray 35 that divides top space 34 and bottom space 36. Hydrogen released from hydrogen nozzle 40 placed in the bottom space is passed through liquid component that has accumulated in the valve tray and stripping of liquid components is performed. Hydrogen released from hydrogen nozzle 40 is again introduced, to second catalyst layer 38 as a cocurrent with the stripped liquid component. By stripping, it is possible to reduce the sulfur content, the nitrogen content and reduce the aromatic content of the hydrocarbon crude oil when compared to the conventional method. Since the hydrorefining unit has a simple structure, the unit can be easily made by modifying existing units.

摘要翻译： 包含含硫化合物的烃原油的加氢精制装置包括第一催化剂层33和第二催化剂层38，用于分离蒸气成分和液体组分的顶部空间34，底部空间36和将塔顶空间34和底部 空间36。 从放置在底部空间的氢喷嘴40释放的氢通过积聚在阀盘中的液体成分，并进行液体成分的剥离。 从氢喷嘴40释放的氢气再次被引入到与汽提的液体组分并流的第二催化剂层38。 通过汽提，与常规方法相比，可以降低烃原油的硫含量，氮含量和降低烃原油的芳烃含量。 由于加氢精制装置具有简单的结构，所以可以通过改变现有的单元容易地制造该装置。

公开(公告)号：US06875730B2

公开(公告)日：2005-04-05

申请号：US10169798

申请日：2001-01-19

申请人： Takashi Kaimai ,  Hitoshi Takahashi ,  Goro Yamamoto ,  Kimiyoshi Namiwa ,  Ayako Saneyoshi

发明人： Takashi Kaimai ,  Hitoshi Takahashi ,  Goro Yamamoto ,  Kimiyoshi Namiwa ,  Ayako Saneyoshi

IPC分类号： C10M107/34 ,  C10M129/06 ,  C10M129/16 ,  C10M129/76 ,  C10M133/12 ,  C10M133/38 ,  C10M133/40 ,  C10M135/32 ,  C10M169/04 ,  C10M171/00 ,  C10M171/02 ,  C10N20/00 ,  C10N20/02 ,  C10N30/00 ,  C10N30/06 ,  C10N30/10 ,  C10N30/12 ,  C10N30/14 ,  C10N40/30 ,  C10M111/00 ,  C10M140/00

CPC分类号： C10M169/04 ,  C10M171/008 ,  C10M2207/021 ,  C10M2207/026 ,  C10M2207/046 ,  C10M2207/283 ,  C10M2209/1033 ,  C10M2209/1045 ,  C10M2209/1055 ,  C10M2209/1065 ,  C10M2209/1085 ,  C10M2215/064 ,  C10M2215/223 ,  C10M2219/108 ,  C10M2223/041 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/305 ,  C10N2240/30

摘要： A lubricant for a refrigerator using ammonia as the refrigerant, which contains an additive selected from antioxidant, anti-wear additive and metal deactivator, and the polyether compound represented by the following general formula (1) or (2): X{—O—(AO)n—H}p  (1) X{—O—(AO1)a—(AO2)b—H}p  (2)

摘要翻译： 含有选自抗氧化剂，抗磨添加剂和金属钝化剂的添加剂的氨气作为制冷剂的冷冻机用润滑剂，以及由下述通式（1）或（2）表示的聚醚化合物：

公开(公告)号：US20020120099A1

公开(公告)日：2002-08-29

申请号：US09945237

申请日：2001-08-31

申请人： Japan Energy Corporation

发明人： Norikazu Nishino ,  Minoru Yoshida ,  Sueharu Horinouchi ,  Yasuhiko Komatsu

IPC分类号： A61K038/12 ,  C07K005/12

CPC分类号： C07K5/126 ,  A61K38/00

摘要： The present invention provides a cyclic tetrapeptide derivative represented by the following general formula (I) or a pharmaceutically acceptable salt thereof: 1 wherein each of R21 and R22 independently denotes hydrogen, a linear C1-C6-alkyl group to which a non-aromatic cycloalkyl group or an optionally substituted aromatic ring may be attached, or a branched C3-C6-alkyl group to which a non-aromatic cycloalkyl group or an optionally substituted aromatic ring may be attached; and each of R1 and R3 independently denotes a linear C1-C5-alkylene group which may have a C1-C6 side chain, in which the side chain may form a condensed ring structure on the alkylene chain. The present invention also provides a histone deacetylase inhibitor, an MHC class-I molecule expression-promoting agent and a pharmaceutical composition, each of which comprises the above cyclic tetrapeptide derivative or pharmaceutically acceptable salt thereof as an active ingredient.

摘要翻译： 本发明提供由以下通式（I）表示的环状四肽衍生物或其药学上可接受的盐：其中R 21和R 22各自独立地表示氢，非芳族环烷基的直链C 1 -C 6 - 烷基 或者可以连接任选取代的芳环，或者可以连接非芳族环烷基或任选取代的芳环的支链C 3 -C 6 - 烷基; R 1和R 3各自独立地表示可以具有C 1 -C 6侧链的直链C 1 -C 5亚烷基，其中侧链可以在亚烷基链上形成稠环结构。 本发明还提供了组蛋白脱乙酰酶抑制剂，MHC I类分子表达促进剂和药物组合物，其各自包含上述环状四肽衍生物或其药学上可接受的盐作为活性成分。

公开(公告)号：US20020060308A1

公开(公告)日：2002-05-23

申请号：US09994684

申请日：2001-11-28

申请人： CATALYSTS AND CHEMICALS INC., FAR EAST, JAPAN ENERGY CORPORATION

发明人： Tsuneyoshi Takase ,  Nobuyashi Hayashi ,  Yasushi Shioya ,  Kaoru Fujiwara ,  Mitsuhiro Ohashi

IPC分类号： C09K003/00

CPC分类号： C10G25/003 ,  B01J20/06

摘要： The invention has an object to provide a solid chloride absorbent which can efficiently absorb inorganic chlorides such as hydrogen chloride flowing out from a process in which a heavy naphtha and the like are treated and inorganic chloride derived from crude oil, and which is difficult to powder and soften after absorbing the chlorides. The solid chloride absorbent according to the invention comprises zinc oxide, a porous refractory inorganic matter and an inert binder, has a long life, and hardly releases the absorbed chlorides.