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71.发明授权
公开(公告)号：US4003823A
公开(公告)日：1977-01-18
申请号：US571912
申请日：1975-04-28
摘要： Processes for the simultaneous desulfurization and hydroconversion of heavy carbonaceous feeds, including various sulfur-containing heavy petroleum oils, are disclosed. These feeds are contacted with alkali metal hydroxides in a conversion zone, in the presence of added hydrogen, and at elevated temperatures, whereby the feeds are substantially desulfurized, while at the same time significant upgrading of these feedstocks is obtained as demonstrated by decreased Conradson carbon, increased API gravity, and the conversion of a substantial portion of the 1,050.degree. F+ portion of the feedstream. In addition, methods for the regeneration of alkali metal hydroxides from the alkali metal salts produced in the conversion zone are disclosed.
摘要翻译： 公开了重质碳质饲料（包括各种含硫重质石油）同时脱硫和加氢转化的方法。 这些进料在转化区，在加入的氢气存在下，在升高的温度下与碱金属氢氧化物接触，从而使进料基本上脱硫，同时，这些原料的显着升级得到，如Conradson碳 ，API重力增加，以及进料流的1,050°F +部分的大部分转化。 此外，公开了在转化区中产生的碱金属盐再生碱金属氢氧化物的方法。
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公开(公告)号：US3929620A
公开(公告)日：1975-12-30
申请号：US52967974
申请日：1974-12-04
申请人： GRACE W R & CO
发明人： PARTHASARATHY R , SCHERZER JULIUS
摘要： A process for hydrocracking hydrocarbon stocks by contacting such stocks under hydrocracking conditions with a nickel oxidetungsten oxide catalyst distended on an ultrastable faujasite base that has been exchanged to incorporate chromium oxide therein. The use of this catalyst allows the refiner to hydrocrack feedstocks that contain large quantities of sulphur and nitrogen compounds. The use of the specially prepared chromium zeolite base also increases the life of the catalyst.
摘要翻译： 通过在加氢裂化条件下使这些原料与氧化镍 - 氧化钨催化剂接触而加氢裂化碳氢化合物原料的方法，所述氧化镍 - 氧化钨催化剂在已经被交换以在其中引入氧化铬的超稳定的八面沸石基体上膨胀。 使用该催化剂允许精炼机加氢裂化含有大量硫和氮化合物的原料。 使用特别制备的铬沸石碱还可增加催化剂的使用寿命。
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公开(公告)号：US3929619A
公开(公告)日：1975-12-30
申请号：US54537175
申请日：1975-01-30
发明人： SINFELT JOHN H , BARNETT ALLAN E , CARTER JAMES L
CPC分类号： C10G47/14 , B01J23/468 , B01J37/22 , C07C4/12 , C07C4/18 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/42 , C07C2523/46 , C10G35/09 , Y02P20/52 , C07C15/02 , C07C15/04 , C07C15/24
摘要： The instant invention relates to a novel hydrocracking process wherein carbon-carbon bonds are ruptured and carbon-hydrogen bonds are formed in the presence of hydrogen and a catalyst comprising platinum, iridium and rhodium supported on an inorganic refractory oxide. This process relates to the dealkylation of alkyl aromatics to form lower molecular weight aromatics, for example, alkylbenzenes such as ethylbenzene, xylene, toluene, etc. may be converted to benzene in the process of the instant invention. The process can also be used to convert a gas-oil fraction to gasoline by converting the higher molecular weight constituents of the gas-oil fraction to lower molecular weight products.
摘要翻译： 本发明涉及一种新型加氢裂化方法，其中碳 - 碳键断裂，在氢存在下形成碳 - 氢键，并且包含负载在无机难熔氧化物上的铂，铱和铑的催化剂。 该方法涉及烷基芳族化合物形成较低分子量芳族化合物的脱烷基化，例如在本发明的方法中可以将烷基苯如乙苯，二甲苯，甲苯等转化为苯。 该方法还可用于通过将瓦斯 - 油馏分的较高分子量成分转化为较低分子量的产物将瓦斯油馏分转化成汽油。
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公开(公告)号：US3919074A
公开(公告)日：1975-11-11
申请号：US49974174
申请日：1974-08-22
发明人： GATSIS JOHN G
CPC分类号： C10G47/00
摘要： A process for the conversion of a hydrocarbonaceous black oil, wherein a heated portion of the charge stock is recycled to the inlet of the charge heater, is disclosed.
摘要翻译： 公开了一种将含碳原料的加热部分再循环到充电加热器的入口的烃黑色油的转化方法。
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公开(公告)号：US3793191A
公开(公告)日：1974-02-19
申请号：US3793191D
申请日：1972-04-06
CPC分类号： C10G65/10 , C10G2400/10
摘要： A process for manufacturing a lubricating oil comprising a first step of passing a deasphalted crude oil distillation residue containing by weight at least 85 percent of constituents boiling above 500*C and at least 75 percent of consituents boiling above 525*C, with hydrogen over a hydrogenating catalyst with a cracking carrier at 330*-450*C, at a hydrogen partial pressure of 80-240 kg/cm2, at such a flow rate that the hydrocarbons in the resulting product boiling below 525*C amount to 70-95 percent of the initial weight of such hydrocarbons, separating the products boiling below 525*C, and recovering a first lubricating oil fraction of high V.I. and a second step of passing at least a portion of the products boiling above 525*C over a similar catalyst, at the same temperature and pressure ranges of the first step, at such a flow rate that the major part of the first zone heavy products are converted to products boiling below 525*C and separating therefrom, by distillation, a second lubricating oil fraction.
摘要翻译： 一种制造润滑油的方法，包括第一步骤，将脱沥青原油蒸馏残余物通过重量百分比至少85％的沸点高于500℃的组分和至少75％的沸点高于525℃的成分， 在330-450℃，氢分压为80-240kg / cm2的氢气催化剂下，使得所得产物中沸点低于525℃的烃为70-95％ 的这种烃的初始重量，分离沸点低于525℃的产物，并回收高VI的第一润滑油馏分 以及第二步骤，在相同的温度和压力范围的第一步骤的相同温度和压力范围内，使沸点高于525℃的产物的至少一部分通过类似的催化剂，以使得第一区重质产物的主要部分 转化成沸点低于525℃的产物，并通过蒸馏分离出第二润滑油馏分。
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公开(公告)号：US3773656A
公开(公告)日：1973-11-20
申请号：US3773656D
申请日：1971-12-01
申请人： DOW CHEMICAL CO
摘要： Heavy hydrocarbon feed oils such as heavy gas oils, residium, topped crude oils and the like are hydrocracked by mixing hydrogen with the feed oil in the ratio of hydrogen to feed oil in the range from 4000 to 10,000 SCF of hydrogen per barrel of feed oil and contacting this mixture under hydro-treating conditions with a supported micro-spherical catalyst having 5-20 weight per cent tungsten and 0.5 to 5.0 weight per cent rhenium. Increased isoparaffin and aromatic content in the cracked product is obtained.
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77.发明授权
公开(公告)号：US3709814A
公开(公告)日：1973-01-09
申请号：US3709814D
申请日：1970-03-06
申请人： CHEVRON RES
发明人： JAFFE J
CPC分类号： C10G65/10 , B01J29/076 , C10G47/18 , C10G69/00
摘要： A HYDROFINING-HYDROCRACKING PROCESS WHICH COMPRISES CONTACTING A HYDROCARBON FEED CONTAINING MORE THAN 50 PARTS PER MILLION OF ORGANIC NITROGEN AND CONTAINING SUBSTANTIAL AMOUNTS OF MATERIALS BOILING ABOVE 200* F., SAID FEED BEING SELECTED FROM THE GROUP CONSISTING OF PETROLEUM DISTILLATES, SOLVENT-DEASPHALTED PETROLEUM RESIDUA, SHALE OILS AND COAL TAR DISTALLATES, IN A REACTION ZONE WITH HYDROGEN AND A CATALYST, AT HYDROFINING-HYDROCRACKING CONDITIONS INCLUDING A TEMPERATURE IN THE RANGE 400* TO 950* F., A PRESSURE IN THE RANGE 800 TO 3500 P.S.I.G., A LIQUID HOURLY SPACE VELOCITY IN THE RANGE 0.1 TO 5.0, AND A TOTAL HYDROFGEN SUPPLY RATE OF 200 TO 20.000 S.D.F. OF HYDROGEN PER BARREL OF FEEDSTOCK, REMOVING AMMONIA FROM THE EFFLUENT FROM SAID REACTION ZONE, AND RECOVERING HYDROFINED AND HYDROCRACKED PRODUCTS FROM SAID REACTION ZONE, SAID CATALYST COMPRISING: (A) A GEL MATRIX COMPRISING: (A) AT LEAST 15 WEIGHT PERCENT SILICA, (B) ALUMINA, IN AN AMOUNT PROVIDING AN ALUMINATO-SILICA WEIGHT RATIO OF 15/85 TO 80/20, (C) NICKEL OR COBALT, OR THE COMBINATION THEREOF, IN THE FORM OF METAL, OXIDE, SULFIDE OR ANY COMBINATION THEREOF, IN AN AMOUNT OF 1 TO 10 WEIGHT PERCENT, BASED ON SAID MATRIX, CALCULATED AS METAL, (D) MOLYBDENUM OR TUNGSTEN, OR THE COMBINATION THEREOF, IN THE FORM OF METAL, OXIDE, SULFIDE OR ANY COMBINATION THEREOF, IN AN AMOUNT OF 5 TO 25 WEIGHT PERCENT, BASED ON SAID MATRIX, CALCULATED AS METAL; (B) A CRYSTALLINE ZEOLITIC MOLECULAR SIEVE: (A) CONTAINING FROM 0.1 TO 2.0 WEIGHT PERCENT PALLADIUM, CALCULATED AS METAL, (B) CONTAINING LESS THAN 5 WEIGHT PERCENT SODIUM, (C) BEING IN PARTICULATE FORM AND BEING DISPERSED THROUGHOUT SAID MATRIX BY COGELATION OF SAID MATRIX AROUND SAID SIEVE; SAID CATALYST COMPOSITE BEING FURTHER CHARACTERIZED BY IN AVERAGE PORE DIAMETER BELOW 100 ANGTROMS AND A SURFACE AREA ABOVE 200 SQUARE METERS PER GRAM.
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公开(公告)号：US3706658A
公开(公告)日：1972-12-19
申请号：US3706658D
申请日：1970-08-21
申请人： UNION OIL CO
发明人： HASS ROBERT H , REEG CLOYD P
CPC分类号： C10G47/00
摘要： HYDROCARBONS CONTAINING SUBSTANTIAL AMOUNTS OF ORGANONITROGEN COMPOUNDS ARE SUBJECTED TO HYDROCRACKING, HYDROFINING, HYDROGENATION AND THE LIKE IN THE PRESENCE OF HYDROGEN OVER A CATALYST COMPRISING ALUMINA AND COMBINATIONS THEREOF WITH SILICA, ZIRCONIA, MAGNESIA AND THE LIKE, SUCH AS ALUMINOSILICATES, WITH OR WITHOUT ACTIVE METAL COMPONENTS, IN THE PRESENCE OF CONTROLLED MINOR AMOUNTS OF WATER FOLLOWED BY THE DISCONTINUANCE OF WATER ADDITION. FURTHER ADVANTAGE IS REALIZED BY CYCLING WATER ADDITION AND DELETION TO PROMOTE EVEN HIGHER AVERAGE SYSTEM ACTIVITIES.
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公开(公告)号：US3657111A
公开(公告)日：1972-04-18
申请号：US3657111D
申请日：1970-02-24
发明人： GLEIM WILLIAM K T
CPC分类号： C10G45/16 , C10G2300/107
摘要： A catalytic slurry hydrorefining process of a hydrocarbonaceous charge stock containing hydrocarbon-insoluble asphaltenes is effected by dissolving in the charge stock an oxyvanadate salt having the following structural formula: (N(R)4)3V0(X)5 wherein ''''X'''' is a cyano, or thiocyano radical, and ''''R'''' is hydrogen, or an alkyl group containing up to 10 carbon atoms. The slurry is formed in situ at hydrorefining conditions with hydrogen containing hydrogen sulfide resulting in colloidally dispersed vanadium sulfide.
摘要翻译： 含有烃不溶性沥青质的含烃原料的催化浆料加氢精制方法是通过将具有下列结构式的氧钒酸盐溶解在电荷原料中：[N（R）4] 3 V 0（X）5，其中“X”为 氰基或硫氰基，“R”是氢或含有至多10个碳原子的烷基。 在加氢精制条件下，用含硫化氢的氢气原位形成浆料，得到胶体分散的硫化钒。
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公开(公告)号：US3642610A
公开(公告)日：1972-02-15
申请号：US3642610D
申请日：1969-09-05
CPC分类号： C10G47/12 , C10G2400/10
摘要： A high-viscosity-index mineral lubricating oil is produced by treating, for instance, a deasphalted residuum or a raw, heavy lubricating distillate oil in a two-stage process. The feedstock is first catalytically hydrocracked, then catalytically hydrogenated and can be fractionated and dewaxed to produce a finished product. Catalysts such as nickel-tungstate on boriaalumina and nickel-molybdate on alumina are employed in the two stages, respectively. The catalysts are preferably used in sulfided form.
摘要翻译： 高粘度指数的矿物润滑油是通过在两阶段工艺中处理例如脱沥青残渣或粗，重润滑的馏出油来生产的。 原料首先被催化加氢裂化，然后进行催化氢化，并可以分馏和脱蜡以产生成品。 在两个阶段中分别使用催化剂，例如在氧化铝上的氧化铈 - 氧化铝上的镍 - 钨酸盐和钼酸镍。 催化剂优选以硫化形式使用。
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