公开(公告)号：US5200436A

公开(公告)日：1993-04-06

申请号：US735652

申请日：1991-07-25

申请人： Ramesh C. Kumar ,  Milton H. Andrus, Jr. ,  Miecyzslaw H. Mazurek

发明人： Ramesh C. Kumar ,  Milton H. Andrus, Jr. ,  Miecyzslaw H. Mazurek

IPC分类号： C08F2/48 ,  C08F293/00 ,  C08G77/22 ,  C08G77/382 ,  C08G77/442

CPC分类号： C08G77/442 ,  C08F293/00 ,  C08G77/22 ,  C08G77/382

摘要： The present invention provides novel siloxane iniferter compounds, block copolymers made therewith, and a method of making the block copolymers. The siloxane iniferter compounds can be represented by the formula ##STR1## wherein T and X are organic groups selected so that the T-X bond is capable of dissociating upon being subjected to an appropriate energy source to form a terminator free radical of the formula T.multidot. and an initiator free radical;R.sub.1, R.sub.2, R.sub.5 and R.sub.6 are monovalent moieties selected from the group consisting of hydrogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy and aryl which can be the same or are different;R.sub.3 and R.sub.4 are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, C.sub.1-4 alkyl, C.sub.1-4 fluoroalkyl including at least one fluorine atom and aryl;Y is selected from the group consisting of --X--T and --Z wherein X and T are defined above and Z is an organic moiety that will not dissociate to form free radicals when subjected to said energy source; andm is an integer of at least 10.

摘要翻译： 本发明提供新的硅氧烷引发剂化合物，由其制备的嵌段共聚物和制备嵌段共聚物的方法。 硅氧烷引发剂化合物可以由下式表示：其中T和X是选择的有机基团，使得TX键能够在经受合适的能量来解离以形成式Tx的终止自由基和 引发剂自由基; R 1，R 2，R 5和R 6是选自氢，C 1-4烷基，C 1-4烷氧基和可以相同或不同的芳基的一价部分; R3和R4是可以相同或不同的一价部分，其选自氢，C 1-4烷基，包括至少一个氟原子和芳基的C 1-4氟代烷基; Y选自-X-T和-Z，其中X和T定义如上，Z是当经受所述能量源时不会离解形成自由基的有机部分; m为10以上的整数。

公开(公告)号：US5057619A

公开(公告)日：1991-10-15

申请号：US660979

申请日：1991-02-26

申请人： Ramesh C. Kumar ,  Milton H. Andrus, Jr. ,  Mieczyslaw H. Mazurek

发明人： Ramesh C. Kumar ,  Milton H. Andrus, Jr. ,  Mieczyslaw H. Mazurek

IPC分类号： C08F293/00 ,  C08G77/22 ,  C08G77/382 ,  C08G77/442

CPC分类号： C08G77/22 ,  C08F293/00 ,  C08G77/382 ,  C08G77/442

摘要： The present invention provides novel siloxane iniferter compounds, block copolymers made therewith, and a method of making the block copolymers. The siloxane iniferter compounds can be represented by the formula ##STR1## wherein T and X are organic groups selected so that the T-X bond is capable of dissociating upon being subjected to an appropriate energy source to form a terminator free radical of the formula T and an initiator free radical.r.sub.1, R.sub.2, R.sub.5 and R.sub.6 are monovalent moieties selected from the group consisting of hydrogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy and aryl which can be the same or are different;R.sub.3 and R.sub.4 are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, C.sub.1-4 alkyl, C.sub.1-4 fluoroalkyl including at least one fluorine atom and aryl;Y is selected from the group consistign of -X-T and -Z wherein X and T are defined above and Z is an organic moiety that will not dissociate to form free radicals when subjected to said energy source; andm is an integer of at least 10.The initiator free radical is capable of initiating free radical polymerization of free radically polymerizable monomer. The terminator free radical is insufficiently capable of initiating free radical polymerization of free radically polymerizable monomer but is capable of rejoining with the initiator free radical or a free radical polymer segment free radically polymerized with the initiator free radical.

摘要翻译： 本发明提供新的硅氧烷引发剂化合物，由其制备的嵌段共聚物和制备嵌段共聚物的方法。 硅氧烷引发剂化合物可以由下式表示：其中T和X是选择的有机基团，使得TX键能够在经受合适的能量来解离以形成式T的终止自由基和 引发剂自由基。 R 1，R 2，R 5和R 6是选自氢，C 1-4烷基，C 1-4烷氧基和可以相同或不同的芳基的一价部分; R3和R4是可以相同或不同的一价部分，其选自氢，C 1-4烷基，包括至少一个氟原子和芳基的C 1-4氟代烷基; Y选自-X-T和-Z组，其中X和T定义如上，Z是当经受所述能源时不会解离形成自由基的有机部分; 并且m是至少10的整数。引发剂自由基能够引发自由基可聚合单体的自由基聚合。 终止子自由基不足以引发游离的可自由基聚合的单体的自由基聚合，但是能够用引发剂自由基重新结合或者与引发剂自由基自由基聚合的自由基聚合物链段。

公开(公告)号：US5002361A

公开(公告)日：1991-03-26

申请号：US468676

申请日：1990-01-23

申请人： Ronald N. DeMartino ,  Hyun-Nam Yoon ,  James B. Stamatoff

发明人： Ronald N. DeMartino ,  Hyun-Nam Yoon ,  James B. Stamatoff

IPC分类号： C08F8/30 ,  C08G65/22 ,  C08G77/382 ,  C09K19/38 ,  C09K19/40

CPC分类号： C08F8/30 ,  C08G65/22 ,  C08G77/382 ,  C09K19/3833 ,  C09K19/3852 ,  C09K19/388 ,  C09K19/408

摘要： This invention provides polymeric thin film optical waveguide media which exhibit nonlinear optical response, and which have utility as an optical waveguide component in all-optical and electrooptical light switch and light modulator devices. An invention waveguide medium consists of a thin film of an amorphous organic polymer as illustrated by the following structure: ##STR1##

摘要翻译： 本发明提供了具有非线性光学响应的​​聚合物薄膜光波导介质，其在全光和电光开关和光调制器装置中具有作为光波导部件的功能。 发明的波导介质由无定形有机聚合物的薄膜组成，如以下结构所示： + TR

公开(公告)号：US4988743A

公开(公告)日：1991-01-29

申请号：US170952

申请日：1988-03-21

申请人： Richard P. Eckberg

发明人： Richard P. Eckberg

IPC分类号： C08F299/08 ,  C07C17/12 ,  C08F290/00 ,  C08G77/38 ,  C08G77/382 ,  C08L83/06 ,  C08L83/07

CPC分类号： C08L83/06 ,  C07C17/12 ,  C08G77/38 ,  C08G77/382 ,  Y10S522/904

摘要： Polysiloxane is produced containing both acrylic or methacrylic and benzoyl functions which is self-sensitized to UV radiation.

公开(公告)号：US4962177A

公开(公告)日：1990-10-09

申请号：US347705

申请日：1989-05-05

申请人： Peter Y. K Lo

发明人： Peter Y. K Lo

IPC分类号： C08G77/382 ,  C09K11/06

CPC分类号： C09K11/06 ,  C08G77/382

摘要： A fluorescent "film prepared by reacting a polyfunctional acrylate with a fluorescent" compound formed by reacting at least one aminofunctional organosilicon compound with at lesat one optical brightener having the formula ##STR1## and wherein R denotes anilino, sulfanilic acid, metanilic acid, or anilin-2,5-disulfonic acid, and R' is methoxy, methylamino, N-methyl-N-hydroxyethylamino, bis(hydroxyethyl)amino, morpholino, anilino, or diethylamino.

摘要翻译： 通过使多官能丙烯酸酯与荧光的“通过使至少一种氨基官能的有机硅化合物与一种具有式”IMAGE“1的荧光增白剂的反应物形成的化合物反应制备的荧光”膜，其中R表示苯胺基，对氨基苯磺酸，邻苯二甲酸或 苯胺基-2,5-二磺酸，R'是甲氧基，甲基氨基，N-甲基-N-羟乙基氨基，双（羟乙基）氨基，吗啉代，苯胺基或二乙基氨基。

公开(公告)号：US4908459A

公开(公告)日：1990-03-13

申请号：US291927

申请日：1988-12-29

申请人： Yoshikuni Deguchi ,  Hiroshi Iwarkiri ,  Kazunari Iwamoto ,  Kazuya Yonezawa

发明人： Yoshikuni Deguchi ,  Hiroshi Iwarkiri ,  Kazunari Iwamoto ,  Kazuya Yonezawa

IPC分类号： C07F7/08 ,  C08G59/02 ,  C08G59/30 ,  C08G77/382

CPC分类号： C08G59/02 ,  C07F7/0847 ,  C08G59/302 ,  C08G59/306 ,  C08G77/382

摘要： A novel glycidyl sulfonamide compound having a (poly)siloxane main chain of its molecule is used alone or in admixture with an epoxy resin to give a cured material being excellent in flexibility, elongation and impact strength without deteriorating thermal resistance, chemical resistance and water absorption thereof. An epoxy resin composition or a resin composition for an epoxy paint containing a glycidyl sulfonamide compound, the epoxy resin and a curing agent for epoxy resin provides a cured material or a coating film having the above-mentioned excellent properties. A process for preparing a glycidyl sulfonamide compound characterized in that subjecting an amine modified silicone having a (poly)siloxane main chain of its molecule to condensation reaction with a sulfonyl chloride to give a sulfonamide compound, which is subjected to an addition reaction with an epihalohydrin to give the glycidyl sulfonamide compound.

公开(公告)号：US4904795A

公开(公告)日：1990-02-27

申请号：US173487

申请日：1988-03-25

申请人： Joseph M. Bohen ,  Gerald H. Reifenberg ,  Daryl L. Stein

发明人： Joseph M. Bohen ,  Gerald H. Reifenberg ,  Daryl L. Stein

IPC分类号： C07D209/48 ,  C07F7/08 ,  C08G77/382 ,  C08K5/3417 ,  C08K5/54

CPC分类号： C07D209/48 ,  C07F7/0854 ,  C08G77/382 ,  C08K5/3417 ,  C08K5/5406

摘要： Novel halogen-substituted phthalimides are provided which are the reaction product of a halogenated phthalic anhydride with an alkoxylated amine or the reaction product of a halogenated phthalic anhydride with a siloxy amine. The halogen-substituted phthalimides are useful in increasing the flame retardancy of thermoplastic and thermosetting resins, and are also effective as processing aids in improving the flowability and moldability of thermoplastic resins during melt processing.

摘要翻译： 提供了新的卤素取代的苯二酰亚胺，其是卤代邻苯二甲酸酐与烷氧基化胺的反应产物或卤代邻苯二甲酸酐与甲硅烷氧基胺的反应产物。 卤素取代的苯二酰亚胺可用于增加热塑性和热固性树脂的阻燃性，并且在熔融加工过程中也可有效地改善热塑性树脂的流动性和成型性。

公开(公告)号：US4868250A

公开(公告)日：1989-09-19

申请号：US822093

申请日：1986-01-24

申请人： Ronald N. DeMartino ,  Hyun-Nam Yoon ,  James B. Stamatoff ,  Alan Buckley

发明人： Ronald N. DeMartino ,  Hyun-Nam Yoon ,  James B. Stamatoff ,  Alan Buckley

IPC分类号： C08G77/38 ,  C08G77/382 ,  C08G77/42 ,  C08G77/44 ,  C09K19/40 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

CPC分类号： C08G77/38 ,  C08G77/382 ,  C09K19/408 ,  G02F1/3617

摘要： This invention provides novel polysiloxane polymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in electrooptic light modulator devices.An invention side chain liquid crystalline polysiloxane polymer is illustrated by the structure: ##STR1##

摘要翻译： 本发明提供了具有非线性光学响应的​​新型聚硅氧烷聚合物，并且其在电光调制器装置中具有作为透明光学部件的功能。 发明侧链液晶聚硅氧烷聚合物由以下结构示出：

公开(公告)号：US4476290A

公开(公告)日：1984-10-09

申请号：US532903

申请日：1983-09-16

申请人： Shuzi Hayase ,  Yasunobu Onishi

发明人： Shuzi Hayase ,  Yasunobu Onishi

IPC分类号： C07F7/10 ,  C08G77/22 ,  C08G77/382 ,  C08L83/08 ,  G03F7/075 ,  C08G77/06

CPC分类号： G03F7/0755 ,  C08G77/22 ,  C08G77/382 ,  C08L83/08 ,  G03F7/0757 ,  Y10S522/904

摘要： Disclosed is a photocurable silicon compound composition which comprises a silicon compound having a silicon atom to which directly bonded is an o-nitrobenzyloxy group represented by the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be same or different and each represents a hydrogen atom, a halogen atom, a nitro group, a cyano group, a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, a substituted or unsubstituted aryl group, an aryloxy group, an acyloxy group having 1 to 5 carbon atoms, a hydroxy group, a mercapto group, an acetyl group or an allyl group,and optionally a silanol-condensing catalyst.

摘要翻译： 公开了一种可光固化的硅化合物组合物，其包含具有直接键合的硅原子的硅化合物，其是由下式表示的邻硝基苄氧基：其中R 1，R 2，R 3和R 4可以相同或不同， 表示氢原子，卤素原子，硝基，氰基，取代或未取代的碳原子数1〜5的烷基，碳原子数1〜5的烷氧基，取代或未取代的芳基，芳氧基 ，具有1至5个碳原子的酰氧基，羟基，巯基，乙酰基或烯丙基，以及任选的硅烷醇缩合催化剂。

公开(公告)号：US4199511A

公开(公告)日：1980-04-22

申请号：US930253

申请日：1978-08-02

申请人： Richard C. McAfee

发明人： Richard C. McAfee

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08G77/382

CPC分类号： C08G77/382 ,  C07F7/0812 ,  C07F7/0854 ,  C07F7/1808

摘要： Chlorendimidosilicon compounds of the formula ##STR1## where R is a monovalent hydrocarbon radical or a substituted monovalent hydrocarbon radical, R' is a divalent hydrocarbon radical or a divalent hydrocarbonoxy radical in which the oxygen is in the form of an ether linkage, R" which may be the same or different is a monovalent hydrocarbon radical or a hydrocarbonoxy radical, x is a number of from 0 to 20,000, y is a number of from 0 to 3, and a process for preparing the same.

摘要翻译： 其中R为单价烃基或取代的单价烃基的式（Ia）的Chlorendimidosilicon化合物，R'为二价烃基或二价烃氧基，其中氧为醚键形式，R“ 单价烃基或烃氧基可以相同或不同，x为0〜20,000的数，y为0〜3的数，以及其制备方法。