Process for the preparation of dimethylketene and then of polydimethylketene fro isobutyric anhydride
    74.
    发明申请
    Process for the preparation of dimethylketene and then of polydimethylketene fro isobutyric anhydride 失效
    制备二甲基烯酮,然后由异丁酸酐制备聚二甲基乙烯酮的方法

    公开(公告)号:US20060270878A1

    公开(公告)日:2006-11-30

    申请号:US10545977

    申请日:2004-02-20

    申请人: Serge Hub

    发明人: Serge Hub

    IPC分类号: C07C45/87

    CPC分类号: C08F16/36 C07C45/89 C07C49/88

    摘要: The present invention relates to a process for the preparation of dimethylketene (DMK) and then of polydimethylketene (PDMK) by polymerization of DMK. More specifically, the DMK is obtained by pyrolysis by isobutyric anhydride (IBAN), the latter decomposing under the effect of heat (pyrolysis) to give isobutyric acid (IBA) and DMK. One mole of pyrolyzed IBAN gives one mole of IBA and one mole of DMK.

    摘要翻译: 本发明涉及通过DMK的聚合制备二甲基烯酮(DMK),然后制备聚二甲基烯酮(PDMK)的方法。 更具体地说,DMK是通过异丁酸酐(IBAN)的热解得到的,后者在热(热解)的作用下分解,得到异丁酸(IBA)和DMK。 1摩尔热解的IBAN得到1摩尔IBA和1摩尔DMK。

    Reduction of alkyl-aryl polymeric ketones using a metal alkoxide
    75.
    发明授权
    Reduction of alkyl-aryl polymeric ketones using a metal alkoxide 失效
    使用金属醇盐还原烷基 - 芳基聚合酮

    公开(公告)号:US06222009B1

    公开(公告)日:2001-04-24

    申请号:US09365529

    申请日:1999-08-02

    IPC分类号: C08F606

    CPC分类号: C08F8/04 C08F16/36

    摘要: The present invention is directed to a process for producing a polymeric alkyl-aryl alcohol resin, and to resins produced by the process of the invention. In the process of the invention (which uses a Meerwein-Pondorff-Verley reduction), a mixture of a polymeric alkyl-aryl ketone resin and a metal alkoxide reducing agent is combined in a solvent. The mixture is refluxed to form a polymeric metal alkoxide intermediate and a ketone (which is removed from the mixture to allow the reaction to go to completion). The solvent reacts with the metal alkoxide intermediate to form a polymeric alkyl-aryl alcohol. Preferably, the metal alkoxide reducing agent is aluminum isopropoxide, and the solvent is isopropyl alcohol, the use of which may result in the regeneration of the aluminum isopropoxide when the polymeric alkyl-aryl alcohol is formed. The invention is also directed to a process for making a non-aqueous ink and to inks formed with the process of the invention. In the process, a polymeric alkyl-aryl alcohol, as described above, is formed, and blended with at least one solvent, a novalac resin, a lubricant, such as a sesquloleate, and a pigment to form the ink. Useful ink solvents include, but are not limited to, glycols, glycol ethers, cyclic amides, alcohols, and mixtures thereof.

    摘要翻译: 本发明涉及一种生产聚合烷基 - 芳基醇树脂的方法,以及通过本发明方法生产的树脂。 在本发明的方法(其使用Meerwein-Pondorff-Verley还原)中,将聚合烷基 - 芳基酮树脂和金属醇盐还原剂的混合物在溶剂中合并。 将混合物回流以形成聚合金属醇盐中间体和酮(其从混合物中除去以使反应完成)。 溶剂与金属醇盐中间体反应形成聚合的烷基 - 芳基醇。 优选地,金属醇盐还原剂是异丙醇铝,并且溶剂是异丙醇,当形成聚合的烷基 - 芳基醇时,其可能导致异丙醇铝的再生。 本发明还涉及制备非水性油墨和用本发明方法形成的油墨的方法。 在此过程中,形成如上所述的聚合物烷基 - 芳基醇,并与至少一种溶剂,诺瓦克树脂,润滑剂如四倍体和颜料共混以形成油墨。 有用的油墨溶剂包括但不限于二醇,二醇醚,环状酰胺,醇及其混合物。

    Monoadduct monomers and polyadduct polymers from divinyl ketones
    77.
    发明授权
    Monoadduct monomers and polyadduct polymers from divinyl ketones 失效
    来自二乙烯基酮的单加成单体和聚加成物聚合物

    公开(公告)号:US4672136A

    公开(公告)日:1987-06-09

    申请号:US813327

    申请日:1985-12-24

    摘要: Included are monoadduct monomers made from divinyl ketones wherein only one vinyl bond therein has added to it a nucleophilic precursor. Nucleophilic precursors include phenols, thiols, secondary amines, amino acids, hydrocarbyl phosphites and phosphite esters, organic bis(phosphonites, the bisulfite anion and others.Polyadduct polymers made from the monoadduct monomers. The polyadduct polymers may be homo- or copolymers and may contain a pendant nucleophile residue.

    摘要翻译: 包括由二乙烯基酮制成的单加成单体,其中只有一个乙烯基键加入亲核前体。 亲核前体包括苯酚,硫醇,仲胺,氨基酸,亚磷酸亚烃酯和亚磷酸酯,有机双(亚膦酸酯,亚硫酸氢盐阴离子等),由单加成单体制成的聚加聚物聚合物可以是均聚物或共聚物, 侧链亲核残基。

    Polymers of monomers containing active methylene groups and other
ethylenically unsaturated monomers
    78.
    发明授权
    Polymers of monomers containing active methylene groups and other ethylenically unsaturated monomers 失效
    含有活性亚甲基和其它烯属不饱和单体的单体的聚合物

    公开(公告)号:US3939130A

    公开(公告)日:1976-02-17

    申请号:US497803

    申请日:1974-08-15

    摘要: Disclosed herein is a polymer comprisingA. from about 1 to 100% by weight of a polymerized monomer containing at least one active methylene group and having the formula ##EQU1## wherein n is 0 or 1, R is hydrogen or methyl, R' is substituted or unsubstituted arylenethylene having the structure ##EQU2## wherein Ar is arylene, R.sup.2 is hydrogen, alkyl, aryl, or cycloalkyl, R.sup.3 is alkoxy or amino when n is equal to 0, and R.sup.3 is alkyl, alkoxy, amino, cycloalkyl or aryl when n is equal to 1; andB. from 0 to about 99% by weight of at least one additional polymerized ethylenically unsaturated monomer.

    摘要翻译: 本文公开了一种聚合物,其包含约1至100重量%的包含至少一个活性亚甲基并且具有式R OO的聚合单体的聚合物;平行CH 2 = C-R 1)n C-CH 2 -C 其中n为0或1,R为氢或甲基,R'为具有结构-Ar-CH 2 -CH 2 - 的取代或未取代的芳亚乙烯基,其中Ar为亚芳基,R 2为氢,烷基,芳基或环烷基,R 3 当n等于0时,是烷氧基或氨基,当n等于1时,R 3是烷基,烷氧基,氨基,环烷基或芳基; 和B为0至约99重量%的至少一种另外的聚合烯属不饱和单体。