UNDERPOTENTIAL DEPOSITION-MEDIATED LAYER-BY-LAYER GROWTH OF THIN FILMS
    72.
    发明申请
    UNDERPOTENTIAL DEPOSITION-MEDIATED LAYER-BY-LAYER GROWTH OF THIN FILMS 有权
    潜在沉积物 - 薄膜的逐层增长

    公开(公告)号:US20110155579A1

    公开(公告)日:2011-06-30

    申请号:US13000800

    申请日:2009-06-23

    Abstract: A method of depositing contiguous, conformal submonolayer-to-multilayer thin films with atomic-level control is described. The process involves the use of underpotential deposition of a first element to mediate the growth of a second material by overpotential deposition. Deposition occurs between a potential positive to the bulk deposition potential for the mediating element where a full monolayer of mediating element forms, and a potential which is less than, or only slightly greater than, the bulk deposition potential of the material to be deposited. By cycling the applied voltage between the bulk deposition potential for the mediating element and the material to be deposited, repeated desorption/adsorption of the mediating element during each potential cycle can be used to precisely control film growth on a layer-by-layer basis. This process is especially suitable for the formation of a catalytically active layer on core-shell particles for use in energy conversion devices such as fuel cells.

    Abstract translation: 描述了一种沉积具有原子级控制的连续的共形亚单层到多层薄膜的方法。 该方法涉及使用第一元素的欠电位沉积来通过超电势沉积介导第二材料的生长。 在形成完整的单层介质元素的中介元件的堆积沉积电位的潜在正电位和小于或仅稍微大于待沉积材料的堆积电位的电位之间发生沉积。 通过在介质元件的体积沉积电位和待沉积的材料之间循环施加的电压,可以使用在每个电位循环期间重复解吸/吸附中间元件以逐层地精确地控制膜生长。 该方法特别适用于在诸如燃料电池的能量转换装置中用于核 - 壳颗粒上的催化活性层的形成。

    Method for fabricating carbon nanotube yarn
    76.
    发明授权
    Method for fabricating carbon nanotube yarn 有权
    碳纳米管制造方法

    公开(公告)号:US07045108B2

    公开(公告)日:2006-05-16

    申请号:US10335283

    申请日:2002-12-31

    Abstract: A method of fabricating a long carbon nanotube yarn includes the following steps: (1) providing a flat and smooth substrate; (2) depositing a catalyst on the substrate; (3) positioning the substrate with the catalyst in a furnace; (4) heating the furnace to a predetermined temperature; (5) supplying a mixture of carbon containing gas and protecting gas into the furnace; (6) controlling a difference between the local temperature of the catalyst and the furnace temperature to be at least 50° C.; (7) controlling the partial pressure of the carbon containing gas to be less than 0.2; (8) growing a number of carbon nanotubes on the substrate such that a carbon nanotube array is formed on the substrate; and (9) drawing out a bundle of carbon nanotubes from the carbon nanotube array such that a carbon nanotube yarn is formed.

    Abstract translation: 制造长碳纳米管纱的方法包括以下步骤:(1)提供平坦且光滑的基材; (2)在基板上沉积催化剂; (3)将基板与催化剂定位在炉中; (4)将炉子加热至预定温度; (5)向炉内供应含碳气体和保护气体的混合物; (6)控制催化剂的局部温度与炉温之间的差为至少50℃; (7)控制含碳气体的分压小于0.2; (8)在基板上生长多个碳纳米管,使得在基板上形成碳纳米管阵列; 和(9)从碳纳米管阵列中抽出一束碳纳米管,形成碳纳米管丝。

    Method for fabricating carbon nanotube yarn
    77.
    发明申请
    Method for fabricating carbon nanotube yarn 有权
    碳纳米管制造方法

    公开(公告)号:US20040053780A1

    公开(公告)日:2004-03-18

    申请号:US10335283

    申请日:2002-12-31

    Abstract: A method of fabricating a long carbon nanotube yarn includes the following steps: (1) providing a flat and smooth substrate; (2) depositing a catalyst on the substrate; (3) positioning the substrate with the catalyst in a furnace; (4) heating the furnace to a predetermined temperature; (5) supplying a mixture of carbon containing gas and protecting gas into the furnace; (6) controlling a difference between the local temperature of the catalyst and the furnace temperature to be at least 50null C.; (7) controlling the partial pressure of the carbon containing gas to be less than 0.2; (8) growing a number of carbon nanotubes on the substrate such that a carbon nanotube array is formed on the substrate; and (9) drawing out a bundle of carbon nanotubes from the carbon nanotube array such that a carbon nanotube yarn is formed.

    Abstract translation: 制造长碳纳米管纱的方法包括以下步骤:(1)提供平坦且光滑的基材; (2)在基板上沉积催化剂; (3)将基板与催化剂定位在炉中; (4)将炉子加热至预定温度; (5)向炉内供应含碳气体和保护气体的混合物; (6)控制催化剂的局部温度与炉温之间的差为至少50℃; (7)控制含碳气体的分压小于0.2; (8)在基板上生长多个碳纳米管,使得在基板上形成碳纳米管阵列; 和(9)从碳纳米管阵列中抽出一束碳纳米管,形成碳纳米管丝。

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