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公开(公告)号:US20210277242A1
公开(公告)日:2021-09-09
申请号:US17329449
申请日:2021-05-25
Applicant: Henkel AG & Co. KGaA
Inventor: Therese Hemery , Adrian Duracu , Johann Klein
IPC: C08L83/04 , C08G77/16 , C08G77/20 , C08G77/08 , C08K5/29 , C08K5/57 , C08K5/544 , C08F230/08 , C09J183/04
Abstract: The invention relates to curable polyorganosiloxanes with special silicon-containing terminal groups and curable compositions based on these polyorganosiloxanes, a special capped adhesion promoter, and a curing catalyst. These compositions have improved adhesion properties and excellent storage stability. The invention also relates to the use thereof.
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公开(公告)号:US10961393B2
公开(公告)日:2021-03-30
申请号:US16443957
申请日:2019-06-18
Applicant: Henkel AG & Co. KGaA
Inventor: Jan-Erik Damke , Christina Despotopoulou , Ralf Baetzgen , Johann Klein
IPC: C08G77/18 , C08L83/06 , C08L71/02 , C09D171/02 , C09D183/06 , C09J171/02 , C09J183/06 , C09K3/10 , C08G77/00 , C09D183/04 , C08L83/04 , C08G65/336
Abstract: The invention relates to a curable composition comprising a) at least one polymer having at least one terminal group of the general formula (I) -An-R—SiXYZ (I), wherein A is a divalent or trivalent bonding group containing at least one heteroatom, R is selected from divalent hydrocarbon residues having 1 to 12 carbon atoms, X, Y, Z are, independently of one another, selected from the group consisting of a hydroxyl group and C1 to C8 alkyl, C1 to C8 alkoxy, C1 to C8 acyloxy groups and —CH2—N—R′ wherein N is oxygen, nitrogen or sulfur, preferably oxygen, and R′ is selected from C1 to C8 alkyl groups, preferably a methyl group, wherein X, Y, Z are substituents directly bound with the Si atom or the two of the substituents X, Y, Z form a ring together with the Si atom to which they are bound, and at least one of the substituents X, Y, Z is selected from the group consisting of a hydroxyl group, C1 to C8 alkoxy or C1 to C8 acyloxy groups, and n is 0 or 1; and b) at least one compound of the general formula (II) wherein R1 is same or different and is, independently from one another, selected from the group consisting of a hydrogen atom and hydrocarbon residues having 1 to 12 carbon atoms, R2 is same or different and is, independently from one another, selected from hydrocarbon residues having 1 to 12 carbon atoms, Ar is selected from aryl groups, and n is an integer selected from 3 to 9; and adhesive, sealant, or coating materials comprising the composition and use thereof.
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63.
公开(公告)号:US20210040269A1
公开(公告)日:2021-02-11
申请号:US17075482
申请日:2020-10-20
Applicant: Henkel AG & Co. KGaA
Inventor: Marta Woznicka , Swarup Ghosh , Marion Marquardt , Esteban Mejia , Udo Kragl , Christina Despotopoulou , Jan-Erik Damke , Johann Klein
Abstract: The present invention is directed to a hydroxyl-functionalized polyether-polysiloxane block copolymer of the structure A(-X—B)n wherein: A represents said polysiloxane block; B represents said polyether block; X is a linker group characterized by including the moiety Si—C—C— of which said Si is the terminal silicon atom of the polysiloxane block A; and, n is an integer of from 2 to 4, said block copolymer being further characterized by a terminal unsaturation of less than 0.04 meq/g, preferably less than 0.03 meq/g and more preferably less than 0.025 meq/g and the method for producing thereof.
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公开(公告)号:US10889682B2
公开(公告)日:2021-01-12
申请号:US16742988
申请日:2020-01-15
Applicant: Henkel AG & Co. KGaA
Inventor: Jan-Erik Damke , Johann Klein , Esteban Mejia , Rok Brisar
IPC: C08G18/28 , C08G18/10 , C08G18/24 , C08G18/48 , C08G18/75 , C09D175/04 , C09J175/04
Abstract: The present invention discloses silylated polyurethanes obtainable by reacting at least one polyols, at least one polyisocyanates, at least one silicon-containing heterocycle of the general formula (I): wherein R1 is hydrogen; R2 and R3 are same or different and are, independently from one another, selected from a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl residue which may be interrupted by at least one heteroatom; R4 is selected from a linear or branched, substituted or unsubstituted C1-C20 alkylene residue which may be interrupted by at least one heteroatom; R5 and R6 are same or different and are, independently from one another, selected from the group consisting of hydrogen, a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl which may be interrupted by at least one heteroatom, and a C4-C8 cycloalkyl, or R5 and R6 may form a ring, preferably a 4- to 8-membered alkyl ring; and n is 0, 1 or 2, their preparation methods, curable compositions comprising the silylated polyurethanes, and their use as adhesive, sealant, spray foam and/or coating.
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公开(公告)号:US20200291186A1
公开(公告)日:2020-09-17
申请号:US16890994
申请日:2020-06-02
Applicant: Henkel AG & Co. KGaA
Inventor: Andrea Gutacker , Jan-Erik Damke , Johann Klein , Esteban Mejia
Abstract: The invention relates to a curable composition comprising a) at least one polymer having at least one silicon-containing group of formula (1) —Si(R1)k(Y)3-k (1), wherein each R1 is independently selected from a hydrocarbon radical containing 1 to 20 C atoms or a triorganosiloxane group of formula —O—Si(R2)3, wherein each R2 is independently selected from a hydrocarbon radical containing 1 to 20 C atoms; each Y is independently selected from a hydroxy group or a hydrolysable group; and k is 0, 1, or 2; b) at least one mixture of paramagnetic titanium complexes, characterized by a Landé g-factor of less than 2 detected by Electron Paramagnetic Resonance Spectroscopy; c) optionally, at least one compound which has a hydrolysable silicon-containing group and a molecular weight in the range of 100 to 1000 g/mol, an aminosilane preparations containing these compositions thereof.
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公开(公告)号:US20200148708A1
公开(公告)日:2020-05-14
申请号:US16745609
申请日:2020-01-17
Applicant: Henkel AG & Co. KGaA
Inventor: Jan-Erik Damke , Johann Klein , Esteban Mejia , Rok Brisar
IPC: C07F7/18
Abstract: The present invention relates to a method for preparing silicon-containing heterocycles of the general formula (I) wherein R1 is hydrogen; R2 and R3 are same or different and are, independently from one another, selected from a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl residue which may be interrupted by at least one heteroatom; R4 is selected from a linear or branched C1-C20 alkylene residue which may be interrupted by at least one heteroatom; R5 and R6 are same or different and are, independently from one another, selected from the group consisting of hydrogen, a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl which may be interrupted by at least one heteroatom, and a C4-C8 cycloalkyl, or R5 and R6 may form a ring, a 4- to 8-membered alkyl ring; and n is 0, 1 or 2, 2, said method comprising a one-step reaction of at least one epoxide compound of the general formula (II) and at least one aminoalkoxysilane having a primary amino group in the presence of a catalyst wherein R5 and R6 are the same as defined for the general formula (I) above; as well as the use of the silicon-containing heterocycles of the general formula (I).
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公开(公告)号:US20200055984A1
公开(公告)日:2020-02-20
申请号:US16663478
申请日:2019-10-25
Applicant: Henkel IP & Holding GmbH , Henkel AG & Co. KGaA
Inventor: Wu Suen , Andrea Keys Eodice , Claudia Meckel-Jonas , Johann Klein
IPC: C08G65/336 , C08J3/24 , C09J171/02 , C09J5/00 , C09K3/10
Abstract: The disclosure relates to moisture curable compositions based on a combination of silane-modified polymer and silane functional additive, their manufacture and use. The silane functional additive is preferably prepared from a water miscible polyol having a functionality of about 2 to about 4 and/or a polyol having a tertiary nitrogen atom in the backbone and a functionality equal or greater than about 2.
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公开(公告)号:US20180291176A1
公开(公告)日:2018-10-11
申请号:US16008390
申请日:2018-06-14
Applicant: Henkel AG & Co. KGaA
Inventor: Andrea Gutacker , Esteban Mejia , Udo Kragl , Johann Klein , Martha Hoehne
Abstract: The invention relates to a curable composition comprising: a) at least one polymer having at least one silicon-containing group of formula —Si(R1)k(Y)3-k as defined herein; b) at least one titanium complex of formula TiL(OR3)2 wherein each R3 is independently selected from a C1-20 alkyl or aryl which may optionally contain one or more heteroatoms, preferably selected from silicon, sulfur, nitrogen or oxygen atoms, wherein preferably R3 is selected from n-butyl or isopropyl, and L is a deprotonated, tridentate ligand, and c) optionally at least one compound which has a hydrolyzable silicon-containing group and a weight average molecular weight in the range of 100 to 1000 g/mol, preparations containing these compositions and use thereof.
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公开(公告)号:US20180016400A1
公开(公告)日:2018-01-18
申请号:US15701930
申请日:2017-09-12
Applicant: Henkel AG & Co. KGaA
Inventor: Andrea Gutacker , Johann Klein , Helene Boudet , Adrian Duracu , Sebastian Kapusta
Abstract: The invention relates to a curable composition, containing (A) at least one polyorganosiloxane, which has at least one hydroxy group bound to a silicon atom, (B) at least one silane of the formula (1): Si(R1)m(R2)n(R3)4-(m+n) (1), as defined herein, (C) at least one aminosilane, and (D) at least one tin compound, whereby the molar ratio of the aminosilane to the tin compound is 1:1 to 50:1, as well as to the preparation and use thereof.
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公开(公告)号:US20180002353A1
公开(公告)日:2018-01-04
申请号:US15702820
申请日:2017-09-13
Applicant: Henkel AG & Co. KGaA
Inventor: Andrea Gutacker , Johann Klein
IPC: C07F7/18 , C08G77/388
CPC classification number: C07F7/1804 , C07F7/0834 , C07F7/1892 , C08G77/16 , C08G77/388 , C08K5/544 , C08K5/5455 , C08K5/57 , C08L83/04
Abstract: The invention relates to a silane of the formula (1), Si(R1)m(R2)n(R3)4-(m+n) (1) as defined herein, where the silane has at least one group of the general formula (3): as defined herein, to a method for preparing the silane, and to curable compositions, containing the silane and at least one polyorganosiloxane.
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