Curable composition with improved mechanical properties and high transparency

    公开(公告)号:US10961393B2

    公开(公告)日:2021-03-30

    申请号:US16443957

    申请日:2019-06-18

    Abstract: The invention relates to a curable composition comprising a) at least one polymer having at least one terminal group of the general formula (I) -An-R—SiXYZ  (I), wherein A is a divalent or trivalent bonding group containing at least one heteroatom, R is selected from divalent hydrocarbon residues having 1 to 12 carbon atoms, X, Y, Z are, independently of one another, selected from the group consisting of a hydroxyl group and C1 to C8 alkyl, C1 to C8 alkoxy, C1 to C8 acyloxy groups and —CH2—N—R′ wherein N is oxygen, nitrogen or sulfur, preferably oxygen, and R′ is selected from C1 to C8 alkyl groups, preferably a methyl group, wherein X, Y, Z are substituents directly bound with the Si atom or the two of the substituents X, Y, Z form a ring together with the Si atom to which they are bound, and at least one of the substituents X, Y, Z is selected from the group consisting of a hydroxyl group, C1 to C8 alkoxy or C1 to C8 acyloxy groups, and n is 0 or 1; and b) at least one compound of the general formula (II) wherein R1 is same or different and is, independently from one another, selected from the group consisting of a hydrogen atom and hydrocarbon residues having 1 to 12 carbon atoms, R2 is same or different and is, independently from one another, selected from hydrocarbon residues having 1 to 12 carbon atoms, Ar is selected from aryl groups, and n is an integer selected from 3 to 9; and adhesive, sealant, or coating materials comprising the composition and use thereof.

    Silylated polyurethanes and methods for preparing thereof

    公开(公告)号:US10889682B2

    公开(公告)日:2021-01-12

    申请号:US16742988

    申请日:2020-01-15

    Abstract: The present invention discloses silylated polyurethanes obtainable by reacting at least one polyols, at least one polyisocyanates, at least one silicon-containing heterocycle of the general formula (I): wherein R1 is hydrogen; R2 and R3 are same or different and are, independently from one another, selected from a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl residue which may be interrupted by at least one heteroatom; R4 is selected from a linear or branched, substituted or unsubstituted C1-C20 alkylene residue which may be interrupted by at least one heteroatom; R5 and R6 are same or different and are, independently from one another, selected from the group consisting of hydrogen, a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl which may be interrupted by at least one heteroatom, and a C4-C8 cycloalkyl, or R5 and R6 may form a ring, preferably a 4- to 8-membered alkyl ring; and n is 0, 1 or 2, their preparation methods, curable compositions comprising the silylated polyurethanes, and their use as adhesive, sealant, spray foam and/or coating.

    Paramagnetic Titanium Mixtures as Vulcanization Catalysts

    公开(公告)号:US20200291186A1

    公开(公告)日:2020-09-17

    申请号:US16890994

    申请日:2020-06-02

    Abstract: The invention relates to a curable composition comprising a) at least one polymer having at least one silicon-containing group of formula (1) —Si(R1)k(Y)3-k   (1), wherein each R1 is independently selected from a hydrocarbon radical containing 1 to 20 C atoms or a triorganosiloxane group of formula —O—Si(R2)3, wherein each R2 is independently selected from a hydrocarbon radical containing 1 to 20 C atoms; each Y is independently selected from a hydroxy group or a hydrolysable group; and k is 0, 1, or 2; b) at least one mixture of paramagnetic titanium complexes, characterized by a Landé g-factor of less than 2 detected by Electron Paramagnetic Resonance Spectroscopy; c) optionally, at least one compound which has a hydrolysable silicon-containing group and a molecular weight in the range of 100 to 1000 g/mol, an aminosilane preparations containing these compositions thereof.

    Method for Preparing Silicon-Containing Heterocycles

    公开(公告)号:US20200148708A1

    公开(公告)日:2020-05-14

    申请号:US16745609

    申请日:2020-01-17

    Abstract: The present invention relates to a method for preparing silicon-containing heterocycles of the general formula (I) wherein R1 is hydrogen; R2 and R3 are same or different and are, independently from one another, selected from a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl residue which may be interrupted by at least one heteroatom; R4 is selected from a linear or branched C1-C20 alkylene residue which may be interrupted by at least one heteroatom; R5 and R6 are same or different and are, independently from one another, selected from the group consisting of hydrogen, a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl which may be interrupted by at least one heteroatom, and a C4-C8 cycloalkyl, or R5 and R6 may form a ring, a 4- to 8-membered alkyl ring; and n is 0, 1 or 2, 2, said method comprising a one-step reaction of at least one epoxide compound of the general formula (II) and at least one aminoalkoxysilane having a primary amino group in the presence of a catalyst wherein R5 and R6 are the same as defined for the general formula (I) above; as well as the use of the silicon-containing heterocycles of the general formula (I).

    Titanium Complexes as Vulcanization Catalysts

    公开(公告)号:US20180291176A1

    公开(公告)日:2018-10-11

    申请号:US16008390

    申请日:2018-06-14

    Abstract: The invention relates to a curable composition comprising: a) at least one polymer having at least one silicon-containing group of formula —Si(R1)k(Y)3-k as defined herein; b) at least one titanium complex of formula TiL(OR3)2 wherein each R3 is independently selected from a C1-20 alkyl or aryl which may optionally contain one or more heteroatoms, preferably selected from silicon, sulfur, nitrogen or oxygen atoms, wherein preferably R3 is selected from n-butyl or isopropyl, and L is a deprotonated, tridentate ligand, and c) optionally at least one compound which has a hydrolyzable silicon-containing group and a weight average molecular weight in the range of 100 to 1000 g/mol, preparations containing these compositions and use thereof.

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