NOVEL HYDROCARBON FOAMS WITH Z-1,1,1,4,4,4-HEXAFLUORO-2-BUTENE

    公开(公告)号:US20190256679A1

    公开(公告)日:2019-08-22

    申请号:US16333785

    申请日:2017-09-20

    IPC分类号: C08J9/14 C08L75/04

    摘要: According to one embodiment of the present invention, predominantly closed cell polymer foams are provided which comprise less than 13.5% Z-1336mzz, carbon dioxide and one or more of methyl formate, methylal and trans-dichloroethylene and has a k factor of less than 0.147 BTU-in/hr-ft2-° F. The cellular polymer foam is foamed polyurethane or foamed polyisocyanurate, depending on the identity of the polyisocyanate and active hydrogen-containing compound reactants and their relative amounts. “Active hydrogen” means that the hydrogen is reactive with the isocyanate of the polyisocyanate reactant. The active hydrogen-containing compound contains at least two groups that contain active hydrogen (atoms) that is reactive with isocyanate. The polyurethane and polyisocyanurate reaction products (foamed) resulting from the process of the present invention are polymers. The reaction product can be a mixture of these polymers.

    HFO-1234ZE copolymers
    63.
    发明授权

    公开(公告)号:US10364311B2

    公开(公告)日:2019-07-30

    申请号:US15532063

    申请日:2015-12-01

    摘要: The present invention provides 1,3,3,3-tetrafluoropropene (HFO-1234ze) copolymers comprising 1,3,3,3-tetrafluoropropene and one or more comonomers selected from the group consisting of vinyl fluoride (VF), vinylidene fluoride (VF2), tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE), hexafluoropropylene (HFP), and perfluoro(alkyl vinyl ether) (PAVE), wherein said alkyl contains 1 to 5 carbon atoms, the copolymers being a fluoroplastic or a fluoroelastomer, depending upon monomer content.

    COMPOSITIONS COMPRISING 2,3-DICHLORO-1,1,1-TRIFLUOROPROPANE, 2-CHLORO-1,1,1-TRIFLUOROPROPENE, 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE OR 2,3,3,3-TETRAFLUOROPROPENE

    公开(公告)号:US20190194514A1

    公开(公告)日:2019-06-27

    申请号:US16244609

    申请日:2019-01-10

    IPC分类号: C09K5/04

    摘要: Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, is HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF═CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

    Polysilane compound containing perfluoro(poly)ether group

    公开(公告)号:US10294393B2

    公开(公告)日:2019-05-21

    申请号:US16081824

    申请日:2017-03-02

    摘要: Composition containing at least one fluorinated silane of the formula (I): (Rf)p—Y—(SiQkZ3-k)w  (I) wherein: Rf represents monovalent R1f(OC4F8)a—(OC3F6)b—(OC2F4)c—(OCF2)d wherein a, b, c, and d independently represent an integer of from 3 to 200 inclusive, and the sum of a, b, c, and d is at least 1; R1f is fluorinated alkyl group, linear or branched, with 1-4 carbons; Y represents a polyvalent organic group, Q represents a hydrolyzable group, a hydroxyl group, or alkyloxy group and is capable of forming a siloxane bond with Si atoms located at the terminal of the molecular chain of formula (I) or other active sites of the treated surface, Z is a monovalent alkyl group, or hydrogen; p is 1 or 2, w is 2-14, p+w is 3 to 15, and k is from 1 to 3.

    Azeotrope-like compositions of HFO-E-1,3,4,4,4-Pentafluoro-3-trifluoromethyl-1-butene and E-1-Chloro-3,3,3-trifluoropropene and uses thereof

    公开(公告)号:US10293197B2

    公开(公告)日:2019-05-21

    申请号:US15023966

    申请日:2014-10-07

    发明人: Mark L Robin

    摘要: Azeotrope-like compositions are disclosed. The azeotrope-like compositions are mixtures of HFO-E-1,3,4,4,4-Pentafluoro-3-trifluoromethyl-1-butene and E-1-Chloro-3,3,3-trifluoropropene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as dielectrics.

    COMPOSITIONS COMPRISING TETRAFLUOROPROPENE AND METHODS OF USE THEREOF

    公开(公告)号:US20190119542A1

    公开(公告)日:2019-04-25

    申请号:US16217620

    申请日:2018-12-12

    摘要: The present invention relates to a composition comprising HFO-1234yf, or trans-HFO-1234ze, or a mixture thereof; HFC-32; and HFC-152a, HFO-1243zf, or a mixture thereof, wherein said composition is selected from the group consisting of: (I) a first composition, wherein said HFO-1234yf or trans-HFO-1234ze or a mixture thereof is at least 56 weight percent of said first composition; (II) a second composition, wherein said HFC-32 is at most 29 weight percent of said second composition; (III) a third composition, wherein said HFC-152a is at least 56 weight percent said third composition; (IV) a fourth composition, wherein said HFC-32 is at least 56 weight percent of said fourth composition; (V) a fifth composition comprising trans-HFO-1234ze, HFC-32, and HFC-152a, HFO-1243zf, or a mixture thereof; and (VI) a sixth composition, wherein said HFO-1243zf or mixture thereof with HFC-152a is at most 20 weight percent of said sixth composition.