公开(公告)号：US20050284544A1

公开(公告)日：2005-12-29

申请号：US11153332

申请日：2005-06-16

申请人： Kenji Yamamoto ,  Eiichiro Yoshikawa ,  Takashi Yashiki

发明人： Kenji Yamamoto ,  Eiichiro Yoshikawa ,  Takashi Yashiki

IPC分类号： C23C26/00 ,  C22C14/00 ,  C22C21/02 ,  C23C2/12 ,  C23C8/10 ,  C23C10/18 ,  C23C10/48 ,  C23C18/02 ,  C23C18/08 ,  C23C18/12 ,  C23C18/48 ,  C23C20/02 ,  C23C24/08 ,  C23C28/00 ,  C23C28/04 ,  C23C30/00 ,  F01N13/00 ,  F01N13/16 ,  C23C22/54

CPC分类号： C23C18/02 ,  C23C2/12 ,  C23C2/26 ,  C23C8/40 ,  C23C10/18 ,  C23C18/04 ,  C23C18/1216 ,  C23C18/1241 ,  C23C24/00

摘要： Disclosed are a surface-treated titanium material that is excellent in oxidation resistance and allows the excellent oxidation resistance to last for a long period of time and the surface treatment itself to be applied safely at a low cost; the production method thereof; and an exhaust system thereof. A surface-treated titanium material produced by forming an oxidation-resistant baked film 5 μm or more in thickness on a substrate comprising commercially pure titanium or titanium-base alloy, and said baked film is formed by filling the gaps among particles comprising Al alloy containing Si by 10 at % or less or commercially pure aluminum with chemical compounds comprising a metallic element M (M represents one or more of Ti, Zr, Cr, Si and Al) and C and/or O.

摘要翻译： 公开了耐氧化性优异且耐久性优异的表面处理钛材料，能够以低成本安全地进行表面处理。 其生产方法; 及其排气系统。 通过在包含商业纯钛或钛基合金的基材上形成5μm以上的耐氧化烘烤膜而制造的表面处理钛材料和所述烘烤膜通过填充包含含有 Si为10原子％以下或商业纯铝，其中化学化合物包含金属元素M（M表示Ti，Zr，Cr，Si和Al中的一种或多种）和C和/或O。

公开(公告)号：US20050244668A1

公开(公告)日：2005-11-03

申请号：US10509028

申请日：2003-03-25

申请人： Toshio Narita ,  Takumi Nishimoto

发明人： Toshio Narita ,  Takumi Nishimoto

IPC分类号： C22F1/18 ,  C22C14/00 ,  C23C10/16 ,  C23C10/28 ,  C23C10/32 ,  C23C10/48 ,  C23C10/56 ,  C23C10/58 ,  C23C28/00 ,  B32B15/00 ,  C23C16/00

CPC分类号： C23C28/021 ,  C22C14/00 ,  C23C10/16 ,  C23C10/56 ,  C23C28/028 ,  Y10T428/12458 ,  Y10T428/12743 ,  Y10T428/12806

摘要： Disclosed is a heat-resistant Ti alloy material excellent in high-temperature corrosion resistance and oxidation resistance, which comprises a base made of a heat-resistant Ti alloy and a surface layer formed on the surface of the base. The surface layer has a multilayer structure including an inner layer and an outer layer. The inner layer has three coexistent phases consisting of a β phase, a γ phase and a Laves phase in the phase diagram of a Ti—Al—Cr based alloy, and the outer layer is made of an Al—Ti—Cr based alloy having an Al concentration of 50 atomic % or more. The heat-resistant Ti alloy material is produced by subjecting a substrate made of a heat-resistant Ti alloy to a Cr diffusion treatment at a temperature within a β single-phase region in the phase diagram of a Ti—Al—Cr based alloy, precipitating a γ phase and a Laves phase from the β phase during a cooling process to form the inner layer with three coexistent phases consisting of the β, γ and Laves phases, and then subjecting the obtained product to an Al diffusion treatment to form the outer layer. The heat-resistant Ti alloy material can prevent the diffusion of Al from the outer layer to the base and the diffusion of elements of the base to the outer layer while forming a protective Al2O3 film in a self-repairing manner, to provide excellent high-temperature corrosion resistance and oxidation resistance to the heat-resistant Ti alloy base.

摘要翻译： 本发明公开了一种耐高温耐氧化性优异的耐热性Ti合金材料，其特征在于，包括由耐热Ti合金构成的基体和形成在基材表面的表面层。 表面层具有包括内层和外层的多层结构。 内层在Ti-Al-Cr基合金的相图中具有由β相，γ相和Laves相组成的三个共存相，外层由Al-Ti-Cr基合金制成，其具有 50原子％以上的Al浓度。 耐热性Ti合金材料通过在Ti-Al-Cr系合金的相图中，使耐热Ti合金的基板在β单相区域内的温度下进行Cr扩散处理而制造， 在冷却过程中从β相沉淀出γ相和Laves相，以形成由β，γ和Laves相组成的三个共存相的内层，然后将所得产物进行Al扩散处理以形成外层 层。 耐热Ti合金材料可以防止Al从外层扩散到基底，并且可以在形成保护性Al 2 O 3的同时将基体的元素扩散到外层 以自修复方式，以耐热Ti合金基材提供优异的耐高温耐腐蚀性和抗氧化性。

公开(公告)号：US06844086B2

公开(公告)日：2005-01-18

申请号：US10071130

申请日：2002-02-08

申请人： Theodore Robert Grossman ,  Ronald Gustav Rajala ,  Dwayne Edward Burnett ,  William Scott Walston ,  Wendy Howard Murpjy

发明人： Theodore Robert Grossman ,  Ronald Gustav Rajala ,  Dwayne Edward Burnett ,  William Scott Walston ,  Wendy Howard Murpjy

IPC分类号： C23C10/08 ,  C23C10/20 ,  C23C10/48 ,  F03B3/12 ,  C23C16/00 ,  B23B15/01

CPC分类号： C23C10/48 ,  C23C10/08 ,  C23C10/20 ,  Y02T50/67 ,  Y10T428/12458 ,  Y10T428/12736 ,  Y10T428/12937 ,  Y10T428/12944 ,  Y10T428/26 ,  Y10T428/265

摘要： A coated superalloy article is prepared by furnishing a nickel-base superalloy article substrate having a rhenium content of not less than about 4.0 percent by weight, and thereafter depositing an aluminum-containing coating onto a surface of the article substrate. The aluminum-containing coating includes an additive zone having an average aluminum content of not greater than about 27 percent by weight, and a diffusion zone of interdiffusion with the article substrate. A ratio of a thickness of the additive zone to a thickness of the diffusion zone is not greater than about 3:1, and is preferably about 1:1.

摘要翻译： 通过提供具有不小于约4.0重量％的铼含量的镍基超合金制品基材，然后在制品基材的表面上沉积含铝涂层来制备涂覆的超合金制品。 含铝涂层包括平均铝含量不大于约27重量％的添加剂区域和与制品基材相互扩散的扩散区域。 添加剂区域的厚度与扩散区域的厚度之比不大于约3:1，优选约1:1。

公开(公告)号：US6022632A

公开(公告)日：2000-02-08

申请号：US733590

申请日：1996-10-18

申请人： Walter E. Olson ,  Norman Pietruska ,  Peter Jon Draghi

发明人： Walter E. Olson ,  Norman Pietruska ,  Peter Jon Draghi

IPC分类号： C23C24/08 ,  C23C10/04 ,  C23C10/48 ,  C23C26/00 ,  B32B15/10

CPC分类号： C23C10/48 ,  C23C10/04 ,  C23C26/00 ,  Y10T428/12736 ,  Y10T428/1275 ,  Y10T428/12757

摘要： The invention includes a low activity localized aluminide coating for a metallic article made by positioning a coating material, preferably in the form of a tape, on a portion of the article. The coating material comprises a binder, a halide activator, an aluminum source, and an inert ceramic material. The coating material and the article are heated in an inert atmosphere between about 1800.degree. F. (982.degree. C.) and about 2050.degree. F. (1121.degree. C.) for between about four and about seven hours thereby producing a low activity localized aluminide coating having an outward diffusion aluminide coating microstructure characterized by two distinct zones, an inner diffusion zone and an outer zone including between about 20-28 percent, by weight, aluminum.

摘要翻译： 本发明包括用于金属制品的低活性局部铝化物涂层，其通过将优选为带状的涂层材料定位在制品的一部分上而制成。 涂层材料包括粘合剂，卤化物活化剂，铝源和惰性陶瓷材料。 将涂层材料和制品在约1800°F（982℃）至约2050°F（1121℃）的惰性气氛中加热约4小时至约7小时，从而产生局部 铝化物涂层具有向外扩散的铝化物涂层微结构，其特征在于两个不同的区域，内扩散区和包含约20-28重量％的铝的外区。

公开(公告)号：US5856027A

公开(公告)日：1999-01-05

申请号：US829093

申请日：1997-03-31

申请人： Kenneth S. Murphy

发明人： Kenneth S. Murphy

IPC分类号： F02C7/00 ,  C23C10/48 ,  C23C14/08 ,  C23C14/14 ,  C23C16/12 ,  C23C16/30 ,  C23C28/00 ,  B32B15/04 ,  B05D3/02 ,  C23C10/60 ,  C23C16/56

CPC分类号： C23C28/02 ,  C23C14/083 ,  C23C16/12 ,  C23C28/042 ,  C23C28/42 ,  Y10S428/938 ,  Y10T428/12549 ,  Y10T428/1259 ,  Y10T428/12618 ,  Y10T428/12931

摘要： A thermal barrier protected nickel based or cobalt based superalloy component for use in a gas turbine engine includes a thermal barrier coating system having a multi-layered structure. The first bondcoat layer of the thermal barrier coating system comprises a chemical vapor deposited, platinum modified diffusion aluminide layer on the superalloy component (substrate). The diffusion aluminide layer includes an inner diffusion zone proximate the substrate and an outer layer region comprising a platinum modified (platinum-bearing) intermediate phase of aluminum and at least one of nickel and cobalt depending on the superalloy composition. The intermediate phase is a non-ordered solid solution having a range of compositions and is free of other phase constituents. The intermediate phase has an average aluminum concentration in the range of about 18 to about 28% by weight, an average platinum concentration in the range of about 8 to about 35% by weight, and an average nickel concentration in the range of about 50 to 60% by weight and is non-stoichiometric relative to intermetallic compounds of aluminum and nickel, aluminum and cobalt, and aluminum and platinum. An adherent alpha alumina layer is thermally grown on the diffusion aluminide layer and receives an outer ceramic thermal barrier layer deposited thereon.

摘要翻译： 用于燃气涡轮发动机的耐热保护的镍基或钴基超级合金部件包括具有多层结构的热障涂层系统。 热障涂层系统的第一粘合涂层包括在超合金部件（基底）上的化学气相沉积的铂改性扩散铝化物层。 扩散铝化物层包括靠近衬底的内部扩散区域和包含铝的铂改性（含铂负载）中间相以及镍和钴中的至少一种的外层区域，这取决于超级合金组成。 中间相是具有一定范围的组成并且不含其它相成分的无序固溶体。 中间相的平均铝浓度在约18至约28重量％的范围内，平均铂浓度在约8至约35重量％的范围内，平均镍浓度在约50至 60重量％，相对于铝和镍，铝和钴的金属间化合物以及铝和铂而言是非化学计量的。 在扩散铝化物层上热生长粘附的α氧化铝层并且接收其上沉积的外部陶瓷热障壁。

公开(公告)号：US5716720A

公开(公告)日：1998-02-10

申请号：US407224

申请日：1995-03-21

申请人： Kenneth S. Murphy

发明人： Kenneth S. Murphy

IPC分类号： F02C7/00 ,  C23C10/48 ,  C23C14/08 ,  C23C14/14 ,  C23C16/12 ,  C23C16/30 ,  C23C28/00 ,  B32B15/04 ,  B05D3/02 ,  C23C10/60 ,  C23C16/56

CPC分类号： C23C28/02 ,  C23C14/083 ,  C23C16/12 ,  C23C28/042 ,  C23C28/42 ,  Y10S428/938 ,  Y10T428/12549 ,  Y10T428/1259 ,  Y10T428/12618 ,  Y10T428/12931

摘要： A thermal barrier protected nickel based or cobalt based superalloy component for use in a gas turbine engine includes a thermal barrier coating system having a multi-layered structure. The first bondcoat layer of the thermal barrier coating system comprises a chemical vapor deposited, platinum modified diffusion aluminide layer on the superalloy component (substrate). The diffusion aluminide layer includes an inner diffusion zone proximate the substrate and an outer layer region comprising a platinum modified (platinum-bearing) intermediate phase of aluminum and at least one of nickel and cobalt depending on the superalloy composition. The intermediate phase is a non-ordered solid solution having a range of compositions and is free of other phase constituents. The intermediate phase has an average aluminum concentration in the range of about 18 to about 26% by weight, an average platinum concentration in the range of about 8 to about 35% by weight, and an average nickel concentration in the range of about 50 to 60% by weight and is non-stoichiometric relative to intermetallic compounds of aluminum and nickel, aluminum and cobalt, and aluminum and platinum. An adherent alpha alumina layer is thermally grown on the diffusion aluminide layer and receives an outer ceramic thermal barrier layer deposited thereon.

摘要翻译： 用于燃气涡轮发动机的耐热保护的镍基或钴基超级合金部件包括具有多层结构的热障涂层系统。 热障涂层系统的第一粘合涂层包括在超合金部件（基底）上的化学气相沉积的铂改性扩散铝化物层。 扩散铝化物层包括靠近衬底的内部扩散区域和包含铝的铂改性（含铂负载）中间相以及镍和钴中的至少一种的外层区域，这取决于超级合金组成。 中间相是具有一定范围的组成并且不含其它相成分的无序固溶体。 中间相的平均铝浓度在约18至约26重量％的范围内，平均铂浓度在约8至约35重量％的范围内，平均镍浓度在约50至 60重量％，相对于铝和镍，铝和钴的金属间化合物以及铝和铂而言是非化学计量的。 在扩散铝化物层上热生长粘附的α氧化铝层并且接收其上沉积的外部陶瓷热障壁。

公开(公告)号：US5648120A

公开(公告)日：1997-07-15

申请号：US255740

申请日：1994-06-07

申请人： Emile Genieys ,  Abdelghani Saida

发明人： Emile Genieys ,  Abdelghani Saida

IPC分类号： C23C10/48 ,  C21D8/12

CPC分类号： C23C10/48

摘要： In this method, aluminization is performed by using thermochemical treatment, and an aluminum donor piece (6) based on metallic aluminum is placed in the vicinity of the surface to be treated (2), prior to said treatment. Preferably, said piece is provided with a thin metal coating (10) that withstands the treatment temperature. The invention is particularly applicable to protecting cooling channels in the blades of a gas turbine.

摘要翻译： 在该方法中，通过使用热化学处理进行镀铝，并且在所述处理之前将基于金属铝的铝供体片（6）放置在待处理表面（2）附近。 优选地，所述件具有耐受处理温度的薄金属涂层（10）。 本发明特别适用于保护燃气轮机叶片中的冷却通道。

公开(公告)号：US5128179A

公开(公告)日：1992-07-07

申请号：US905247

申请日：1986-09-08

申请人： Alfonso L. Baldi

发明人： Alfonso L. Baldi

IPC分类号： C08J3/09 ,  C23C10/34 ,  C23C10/38 ,  C23C10/48

CPC分类号： C08J3/091 ,  C23C10/34 ,  C23C10/38 ,  C23C10/48 ,  C08J2333/06 ,  H05K2201/0209

摘要： A nickel-base superalloy is subjected to a diffusion chromizing that supplies a chromized diffusion case, the outer surface of which contains excess alphachrome phase, and then contacting the diffusion case with an aqueous solution of alkali metal permanganate and alkali metal hydroxide until the desired amount of alphachrome phase is eliminated.

摘要翻译： 对镍基超级合金进行扩散镀铬处理，该扩散镀铬提供铬化扩散壳体，其外表面含有过量的铝合金相，然后使扩散箱与碱金属高锰酸盐和碱金属氢氧化物的水溶液接触直到所需量 消除了阿尔法相。

公开(公告)号：US4978558A

公开(公告)日：1990-12-18

申请号：US204815

申请日：1988-06-10

申请人： Foster P. Lamm

发明人： Foster P. Lamm

IPC分类号： B29C45/14 ,  B29K23/00 ,  B29K25/00 ,  B29K105/16 ,  B29K105/22 ,  C23C10/04 ,  C23C10/08 ,  C23C10/48

CPC分类号： C23C10/04

摘要： Methods for selectively applying a diffusion aluminide coating to the surface of a metal article while keeping other article surfaces free of the coating are described. The method includes the steps of injection molding a mixture of materials onto the surfaces which are to be kept free of coating; the material comprises solid particles effective in preventing deposition of the coating onto the surfaces and a moldable amorphous thermoplastic resin; it contains no volatilizable solvents. The mixture is applied to the article surface to a thickness of about 5 millimeters. It is useful in pack diffusion as well as vapor phase diffusion aluminide coating operations.

公开(公告)号：US4897315A

公开(公告)日：1990-01-30

申请号：US903831

申请日：1986-09-03

申请人： Dinesh K. Gupta

发明人： Dinesh K. Gupta

IPC分类号： C23C10/02 ,  C23C10/48

CPC分类号： C23C10/48 ,  C23C10/02 ,  Y10T428/12021 ,  Y10T428/12056 ,  Y10T428/12458 ,  Y10T428/12944 ,  Y10T428/24942

摘要： A protective coating system for superalloys is described. The coating is an yttrium enriched aluminide, and can be formed by aluminizing an MCrAlY coated superalloy, wherein during the aluminizing process, aluminum diffuses completely through the MCrAlY coating and into the substrate. The coating system exhibits desirable oxidation resistance and resistance to thermal fatigue cracking.