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    Liquid crystal polymer devices and materials
    51.
    发明授权
    Liquid crystal polymer devices and materials 失效
    液晶聚合物器件和材料

    公开(公告)号：US06666989B1

    公开(公告)日：2003-12-23

    申请号：US09622222

    申请日：2000-08-15

    Applicant: Kenneth J Toyne ,  Stephen J Cowling ,  John W Goodby

    Inventor： Kenneth J Toyne ,  Stephen J Cowling ,  John W Goodby

    IPC: C09K1952

    CPC classification number: C09K19/3876 ,  C08G65/18 ,  C08G65/22 ,  C08G65/226 ,  C09K2019/3416 ,  C09K2019/3422 ,  Y10T428/10

    Abstract: Polymeric compounds of general formula (I) where X, X1, X2 are independently straight or branched chain C1-16 alkyl, halogen and H; (a) is a suitable mesogenic group; Z=single covalent bond, oxygen CO2, OCO; n=1-20; Y=oxygen, CO2, OCO, CH2, CHOH, CH2O; m=3-10,000. The compounds are liquid crystal polymers useful in liquid crystal devices, sensors, and in non-linear optical devices. The compounds are prepared by polymerization of the oxitane monomer to obtain the side-chain liquid crystalline polyoxitane compound. In this way the mesogenic groups are spaced on every fourth carbon atom in the polymer chain allowing greater mobility for the mesogenic group.

    Abstract translation: 通式（I）的聚合物，其中X，X 1，X 2独立地为直链或支链C 1-16烷基，卤素和H; （a）是适合的介晶组; Z =单共价键，氧CO 2，OCO; n = 1-20; Y =氧，CO 2，OCO，CH 2，CHOH，CH 2 O; m = 3-10,000。 这些化合物是可用于液晶装置，传感器和非线性光学装置中的液晶聚合物。 所述化合物通过聚合所述肟基单体制备得到侧链液晶聚氧化锡化合物。 以这种方式，介晶基团在聚合物链中的每四个碳原子上间隔开，从而允许介晶基团的更大的迁移率。

    Polymerizable liquid crystalline dioxetanes, their preparation and use
    52.
    发明授权
    Polymerizable liquid crystalline dioxetanes, their preparation and use 失效
    可聚合的液晶二氧杂环丁烷，其制备和用途

    公开(公告)号：US06660344B2

    公开(公告)日：2003-12-09

    申请号：US09969700

    申请日：2001-10-03

    Applicant: Johan Lub

    Inventor： Johan Lub

    IPC: C09K1934

    CPC classification number: C07D305/06 ,  C09K19/38 ,  C09K19/3876 ,  C09K2019/3416 ,  Y10T428/10

    Abstract: New photopolymerizable liquid crystalline dioxetane compounds are provided having the general formula I: wherein R1 and R2 are independently selected from straight or branched C1-C4 alkyl and hydrogen; X and X′ are independently selected from oxygen, sulfur, a single covalent bond, —O—CO—, —CO—O—, and —O—CO—O—; Y and Y′ are spacer groups having each independently 1 to 30 carbon atoms (linear or branched), in which the carbon chain may be interrupted by oxygen in the ether function or by sulfur in the thioether function; Z and Z′ are independently selected from oxygen, sulfur, a single covalent bond, —O—CO—, —CO—O—, and —O—CO—O—; and M is any suitable mesogenic group. Also, compositions are provided containing one or more compounds of formula I, as well as methods of preparing said compounds and compositions. These compounds and compositions show excellent characteristics upon polymerization, such as improved non-shrinking properties, and are useful in a variety of applications, in particular in liquid crystal devices, sensors, and optical precision instruments.

    Abstract translation: 提供具有通式I的新的可光聚合的液晶二氧杂环丁烷化合物：其中R 1和R 2独立地选自直链或支链C 1 -C 4烷基和氢; X和X'独立地选自氧，硫，单个共价键，-O-CO-，-CO-O-和-O-CO-O-; Y和Y'是具有各自独立的1至30个碳原子（直链或支链）的间隔基，其中碳链可以被醚功能中的氧或硫醚官能团中的硫中断; Z和Z'独立地选自氧，硫，单个共价键，-O-CO-，-CO-O-和-O-CO-O-; 并且M是任何合适的介晶基团。此外，提供含有一种或多种式I化合物的组合物，以及制备所述化合物和组合物的方法。 这些化合物和组合物在聚合时显示出优异的特性，例如改进的非收缩性能，并且可用于各种应用，特别是在液晶装置，传感器和光学精密仪器中。

    FILM USING POLYMERIZABLE LIQUID CRYSTAL COMPOSITION CONTAINING PEELING PREVENTIVE AGENT
    56.
    发明申请
    FILM USING POLYMERIZABLE LIQUID CRYSTAL COMPOSITION CONTAINING PEELING PREVENTIVE AGENT 有权
    使用含聚氨酯预防剂的可聚合液晶组合物的胶片

    公开(公告)号：US20140308462A1

    公开(公告)日：2014-10-16

    申请号：US14220975

    申请日：2014-03-20

    Applicant: JNC PETROCHEMICAL CORPORATION ,  JNC CORPORATION

    Inventor： Kazumi NARA

    IPC: G02F1/1337

    CPC classification number: G02B5/3083 ,  C09K19/28 ,  C09K19/32 ,  C09K19/54 ,  C09K2019/0448 ,  C09K2019/122 ,  C09K2019/2035 ,  C09K2019/2078 ,  C09K2019/3416 ,  C09K2219/03 ,  G02B27/26 ,  G02F2001/133631 ,  Y10T428/10 ,  Y10T428/1005

    Abstract: A problem is, in a liquid crystal film in which an alignment layer and a liquid crystal composition layer having homogeneous alignment are formed on a support substrate, to improve adhesion between the alignment layer and the liquid crystal composition layer, and durability under a severe environment such as high temperature and high humidity. A solution is a non-liquid crystalline polymerizable compound having a radically polymerizable group and a cationically polymerizable group in a molecule is simultaneously used as an antistripping additive in a polymerizable liquid crystal composition layer having homogeneous alignment.

    Abstract translation: 问题在于，在支撑基板上形成具有均匀排列的取向层和液晶组合物层的液晶膜，以提高取向层与液晶组合物层之间的粘附性，以及在恶劣环境下的耐久性 如高温高湿。 溶液是具有自由基聚合性基团和分子内的阳离子聚合性基团的非液晶性聚合性化合物同时用作具有均匀取向的聚合性液晶组合物层中的抗翘曲添加剂。

    Polymerizable oxetane derivative
    58.
    发明授权
    Polymerizable oxetane derivative 有权
    可聚合的氧杂环丁烷衍生物

    公开(公告)号：US08460577B2

    公开(公告)日：2013-06-11

    申请号：US12947192

    申请日：2010-11-16

    Applicant: Mayumi Tanabe ,  Yoshiharu Hirai

    Inventor： Mayumi Tanabe ,  Yoshiharu Hirai

    IPC: C09K19/00 ,  C09K19/06 ,  C09K19/32 ,  C09K19/52 ,  G02F1/1333

    CPC classification number: C07D305/06 ,  C07D303/28 ,  C09K19/2007 ,  C09K19/322 ,  C09K2019/0448 ,  C09K2019/3416 ,  Y10T428/10 ,  Y10T428/1036

    Abstract: The invention provides a compound represented by formula (1). In the formula (1), R1 is hydrogen, methyl or ethyl; X1 is a single bond, —O— or —OCO—; X2 is a single bond, —O—, —COO— or —OCO—; A1 and A2 are each independently a divalent aromatic ring or a divalent cyclohexane ring, and in these rings, arbitrary hydrogen may be replaced by halogen, alkyl having 1 to 3 carbons or halogenated alkyl having 1 to 3 carbons; Z1 is independently a single bond, —O—, —S—, —COO—, —OCO—, —CH2O—, —OCH2—, —CH═CH—COO—, —OCO—CH═CH—, —CH2CH2—COO—, —OCO—CH2CH2—, —CON(R)— or —N(R)CO—; R is hydrogen or methyl; Y is a terpenoid residue or a steroid residue; m is an integer from 0 to 20; and n is an integer from 0 to 3.

    Abstract translation: 本发明提供由式（1）表示的化合物。 在式（1）中，R 1是氢，甲基或乙基; X1是单键，-O-或-OCO-; X2是单键，-O - ， - COO-或-OCO-; A1和A2各自独立地为二价芳环或二价环己烷环，并且在这些环中，任意的氢可以被卤素，具有1至3个碳的烷基或具有1至3个碳的卤代烷基代替; Z 1独立地为单键，-O - ， - S - ， - COO - ， - OCO - ， - CH 2 O - ， - OCH 2 - ， - CH = CH-COO-，-OCO-CH = CH-，-CH 2 CH 2 - COO-，-OCO-CH 2 CH 2 - ， - CON（R） - 或-N（R）CO-; R是氢或甲基; Y是萜类残基或类固醇残基; m为0〜20的整数; n为0〜3的整数。

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