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51.发明授权
公开(公告)号：US4178300A
公开(公告)日：1979-12-11
申请号：US957002
申请日：1978-10-31
IPC分类号： C07C53/00 , C07C27/00 , C07C29/00 , C07C29/68 , C07C29/70 , C07C31/30 , C07C31/32 , C07C51/00 , C07C53/126 , C07C67/00 , C07F3/00 , C07F3/02 , C07F7/00 , C11C1/00
CPC分类号： C07C31/30 , C07C29/70 , C07C29/705 , C07C31/32 , C07C53/126 , C07F3/003 , C07F7/006
摘要： A novel process is described for the preparation of novel organic solutions of organooxy magnesium compounds of low viscosity, which solutions are formed in the presence of at least 5 mol % based on the magnesium compound of an organooxy compound of a transition metal of Groups IV through VI of the Periodic Table.
摘要翻译： 描述了一种制备低粘度有机氧化镁化合物的新型有机溶液的新方法，该溶液是在至少5摩尔％存在下形成的，该镁化合物基于镁化合物的IV族过渡金属的有机氧化合物 六，周期表。
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52.发明授权Preparation of ultra-pure compounds corresponding to the formula caal2o4 and mgal2c4 失效与制剂CAAL2O4和MGAL2C4相关的超纯化合物的制备
公开(公告)号：US3786137A
公开(公告)日：1974-01-15
申请号：US3786137D
申请日：1972-04-07
申请人： OWENS ILLINOIS INC
发明人： THOMAS I
CPC分类号： C07F5/069 , B82Y30/00 , C01B13/14 , C01B13/185 , C01F7/162 , C01P2004/32 , C01P2004/50 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C07C29/685 , C07C29/70 , C07C31/30 , C07C31/32
摘要： DOUBLE METAL ALKOXIDES OF THE FORMULA M(AI(OR)4)2 ARE CONVERTED BY PYROLYSIS, OR HYDROLYSIS AND PYROLYSIS, TO ULTRA-PURE COMPOUNDS CORESSPONDING TO THE FORMULA MAI2O4 WHEREIN M IS MAGNESIUM OR CALCIUM AND R IS AN ALKYL GROUP CONTAINING FROM 1 TO 7 CARBON ATOMS.
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53.发明授权
公开(公告)号：US3775069A
公开(公告)日：1973-11-27
申请号：US3775069D
申请日：1972-03-03
发明人： WHITNEY T
摘要： A composition of matter comprising a gelatinous hydrocarbon containing a minor amount of a compound having either the formula MOR or
摘要翻译： 包含含有少量具有式MOR的化合物或与具有式M'（OR'）3的化合物组合的含有少量化合物的凝胶状烃的物质组合物，其中M选自IA族金属; M'是选自IIIA族金属的组; R和R'独立地选自C 1 -C 25直链或支链烃基; R“和R”'相同或不同，其中每个是C 1 -C 16直链或支链烃基; Q是O或N; A是含有2至4个具有0至2个取代基的亚甲基碳原子的烃基，所述取代基选自C1-C6烷基，C3-C6环烷基，苯基，C2-C6烯基，C2-C6炔基 ，Cl，Br，I; n为1〜10的整数， x是整数，并且根据Q的化合价是1或2; y根据Q的化合价是0或1; 与有效量的足以防止水解脱胶的脱水剂或铁粉给组合物提供磁性的组合。
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54.发明授权Simultaneous production of alcoholates and trivalent titanium complexes of beta-diketones 失效乙醇酸盐的同时生产和BETA-DIKETONES的多晶钛复合物
公开(公告)号：US3716567A
公开(公告)日：1973-02-13
申请号：US3716567D
申请日：1970-09-08
申请人： DYNAMIT NOBEL AG
CPC分类号： C07C29/685 , C07C31/28 , C07C31/30 , C07F7/006
摘要： Tetravalent titanium alcoholate-beta diketone complexes, e.g. titanium isopropylate-triacetylacetonate, are reacted with an alkali metal amalgam in a non-polar solvent to reduce the titanium to trivalent state, forming, for example, titanium triacetylacetonate and sodium isopropylate. The sodium isopropylate is a crystalline precipitate which can be removed by filtration; the amalgam can be decanted off and reused, as in alkali metal chloride electrolysis, to restore its alkali metal content so as to be ready for re-cycling.
摘要翻译： 四价钛醇化物-β二酮络合物，例如 异丙酯 - 三乙酰丙酮钛与非极性溶剂中的碱金属汞齐反应以将钛还原成三价态，形成例如三乙酰丙酮钛和异丙醇钠。 异丙醇钠是结晶沉淀物，可通过过滤除去; 可以将碱金属氯化物电解中的汞齐滗析并重复使用，以恢复其碱金属含量，以准备重新循环。
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55.发明授权
公开(公告)号：US3385904A
公开(公告)日：1968-05-28
申请号：US23422262
申请日：1962-10-30
发明人： PAVLIK FRANK J
IPC分类号： C07C29/70 , C07C31/30 , C07C43/13 , C07C59/88 , C07C309/73 , C07D303/48 , C07D307/34 , C07D307/60 , C07F7/02
CPC分类号： C07D307/34 , C07C29/70 , C07C31/30 , C07C43/137 , C07C59/88 , C07C309/73 , C07D303/48 , C07D307/60 , C07F7/025 , C07C31/40
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公开(公告)号：US2915564A
公开(公告)日：1959-12-01
申请号：US50152255
申请日：1955-04-15
发明人： HANSLEY VIRGIL L , STUART SCHOTT
IPC分类号： C07C29/128 , C07C29/147 , C07C29/68
CPC分类号： C07C29/147 , C07C29/128 , C07C29/68 , C07C31/125 , C07C31/30
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公开(公告)号：US1689356A
公开(公告)日：1928-10-30
申请号：US14571126
申请日：1926-11-01
申请人： CHEM FAB AUF ACTIEN
发明人： HANS MEERWEIN
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公开(公告)号：US12071519B2
公开(公告)日：2024-08-27
申请号：US18228531
申请日：2023-07-31
申请人： 9449710 CANADA INC.
发明人： Adel Essaddam , Fares Essaddam
IPC分类号： C08J11/26 , C07C31/30 , C07C67/03 , C07C69/82 , C08J11/16 , C08J11/22 , C08J11/24 , C07C29/132
CPC分类号： C08J11/16 , C07C31/30 , C07C67/03 , C07C69/82 , C08J11/22 , C08J11/24 , C08J11/26 , C07C29/132 , C08J2367/02
摘要： The present disclosure relates to the formation of dimethyl terephthalate (DMT). The present invention also relates to the depolymerization of polyethylene terephthalate (PET) and the recovery of terephthalic acid and ethylene glycol.
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60.发明授权公开(公告)号：US09676904B2
公开(公告)日：2017-06-13
申请号：US14363281
申请日：2012-09-11
申请人： Dongmei Cui , Xinli Liu , Bo Liu , Shihui Li , Dongtao Liu , Chunji Wu
发明人： Dongmei Cui , Xinli Liu , Bo Liu , Shihui Li , Dongtao Liu , Chunji Wu
IPC分类号： C08G63/82 , C08G63/84 , C07C31/28 , C07C29/70 , C07C33/22 , C07C33/24 , C08G63/83 , C08G63/85 , C07C31/30 , B01J31/02 , C07F3/04 , C07F5/06
CPC分类号： C08G63/823 , B01J31/0212 , B01J2231/14 , B01J2531/22 , C07C29/70 , C07C31/28 , C07C31/30 , C07C33/22 , C07C33/24 , C07F3/04 , C07F5/069 , C08G63/826 , C08G63/83 , C08G63/84 , C08G63/85
摘要： The invention provides a metal alkoxide complex of Formula (I), wherein X, M, R1, R2, R3, m, n, y and z are as defined in the Description. The invention also provides a catalyst composition comprising the metal alkoxide complex and a hydroxy-containing compound, wherein the molar ratio of the metal alkoxide complex to the hydroxy-containing compound is 1:0.1-1000. The invention also provides a production method of poly-ε-caprolactone or polyactide, wherein an ε-caprolactone monomer or a lactide monomer is reacted in the presence of the metal alkoxide complex or catalyst composition to obtain poly-ε-caprolactone or polylactide. The metal alkoxide complex and the catalyst composition thereof can be used to catalyze the synthesis of poly-ε-caprolactone or polylactide with a high efficiency. The molecular weight of polycaprolactone or polylactide can be controlled by the molar ratio of the metal alkoxide complex and the hydroxy-containing compound, and is adjustable in the range of 1000-600,000, and wherein the molecular weight distribution is from 1.03 to 1.50. [Xn-mM(OCR1R2R3)m]y.(organic solvent)z (I)
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