摘要:
A process for continuously producing an elastomeric composition includes providing at least one extruder, metering and feeding at least one elastomer, at least one filler, and ingredients different from elastomers and fillers into the at least one extruder, mixing and dispersing the at least one filler and the ingredients different from elastomers and fillers into the at least one elastomer using the at least one extruder, and extruding a resulting elastomeric composition. The at least one extruder includes the housing and at least one screw rotatably mounted in the housing. The housing includes at least one feed opening and a discharge opening. At least one of the ingredients different from elastomers and fillers includes a subdivided product including one or more minor ingredients dispersed in at least one thermoplastic binding agent. An apparatus for continuously producing the elastomeric composition is also disclosed.
摘要:
Process for preparing an electrical cable comprising at least one conductor and at least one layer of extruded insulating coating, which includes: coating, by extrusion, the conductor with a polymeric composition comprising a polyethylene, a radical initiator and at least one unsaturated carboxylic acid of general formula (I) in free form: in which: R1 represents H or CH3; n represents 0 or 1; said unsaturated carboxylic acid being present in an amount of between 0.0006% and 0.25% by weight, said amount being expressed as the weight content of —COOH groups relative to the total weight of the polymeric composition; heating the conductor thus coated so as to obtain cross-linking of said polymeric composition.
摘要:
The invention describes a cable, in particular for electric energy transportation or distribution, in which an electrically insulating layer is present, consisting of a material substantially free of lead or derivatives thereof, and having high resistance to water. This material includes an elastomer terpolymer having the following composition: a) 50-90 moles percent of ethylene; b) 10-50 moles percent of an &agr;-olefin; c) 0.16-5 moles percent of 5-vinyl-2-norbornene; the sum of the moles percent of a), b), c) being 100, said terpolymer having a branching index of less than or equal to 0.5 and a molecular weight distribution index Mw/Mn of greater than or equal to 6.
摘要:
Ethylene copolymers are prepared with comonomers selected from: (a) &agr;-olefins, (b) cycloolefins and (c) polyenes, with a content of ethylene units of between 80 and 99 mol %, a content of units derived from &agr;-olefin, cycloolefin and/or polyene comonomers of between 1 and 20 mol %, characterized in that: (a) in TREF (Temperature Rising Elution Fractionation) analysis, a quantity equal to at least 90% by weight of the copolymer is eluted within a temperature interval of less than 50° C., and (b) Mw/Mn>3, where Mw is the weight-average molecular weight and Mn is the number-average molecular weight, both determined by means of GPC.
摘要:
Cable, in particular for medium-voltage or high-voltage electrical power transmission or distribution, for telecommunications or for data transmission, comprising a conductor and at least one coating layer based on a non-crosslinked polymer material comprising a thermoplastic reactor elastomer with an ethylene-based elastomeric phase co-polymerized with an &agr;-olefin and a propylene-based thermoplastic phase, in which the said elastomeric phase in the said thermoplastic reactor elastomer is at least 45% by weight relative to the total weight of the thermoplastic reactor elastomer, and the said thermoplastic reactor elastomer has value of enthalpy of fusion of peaks present below 130° C. and attributable to polyethylene sequences, such as HIFAX® KS080.
摘要:
A cable, in particular for power transmission, for telecommunications or for data transmission, or also combined power/telecommunications cables, wherein at least one coating layer consists of a recyclable material which is halogen-free and has superior mechanical, electrical, and flame-retardant properties. This material consists of a polymer mixture comprising: (a) a crystalline propylene homopolymer or copolymer; and (b) a copolymer of ethylene with at least one alpha-olefin having from 4 to 12 carbon atoms, and optionally with a diene; the said copolymer (b) being characterized by a density of between 0.90 and 0.86 g/cm3 and by a Composition Distribution Index, defined as the weight percentage of copolymer molecules having an alpha-olefin content within 50% of the average total molar content of alpha-olefin, of greater than 45%. This material may also include a flame-retardant inorganic filler.
摘要翻译:一种电缆,特别是用于电力传输的电缆,用于电信或数据传输,或者还包括组合的电力/电信电缆,其中至少一个涂层由无卤素的可回收材料组成并且具有优异的机械,电和阻燃材料, 阻燃性能。 该材料由聚合物混合物组成,包括:(a)结晶丙烯均聚物或共聚物; 和(b)乙烯与至少一种具有4至12个碳原子的α-烯烃和任选与二烯的共聚物; 所述共聚物(b)的特征在于密度为0.90至0.86g / cm 3,并且通过组成分布指数,其定义为α-烯烃含量在平均总摩尔含量的50%以内的共聚物分子的重量百分比 α-烯烃,大于45%。 该材料还可以包括阻燃性无机填料。
摘要:
Elastomeric ethylene/propylene or ethylene/propylene/polyene copolymers containing small amounts of one or more &agr;-olefins are prepared by a slurry process wherein the polymerization reaction is carried out in a mixture of liquid propylene and alpha-olefin.
摘要:
A cable, in particular for power transmission, for telecommunications or for data transmission, or also combined power/telecommunications cables, wherein at least one coating layer consists of a recyclable material which is halogen-free and has superior mechanical and electrical properties. This material consists of a polymer mixture comprising: (a) a crystalline propylene homopolymer or copolymer; and (b) a copolymer of ethylene with at least one alpha-olefin having from 4 to 12 carbon atoms, and optionally with a diene; the said copolymer (b) being characterized by a density of between 0.90 and 0.86 g/cm3 and by a Composition Distribution Index, defined as the weight percentage of copolymer molecules having an alpha-olefin content within 50% of the average total molar content of alpha-olefin, of greater than 45%.
摘要翻译:电缆,特别是用于电力传输,用于电信或数据传输的电缆,或者还包括组合的电力/电信电缆,其中至少一个涂层由可再循环材料组成,其是无卤素且具有优异的机械和电气性能。 该材料由聚合物混合物组成,包括:(a)结晶丙烯均聚物或共聚物; 和(b)乙烯与至少一种具有4至12个碳原子的α-烯烃和任选与二烯的共聚物; 所述共聚物(b)的特征在于密度为0.90至0.86g / cm 3,并且通过组成分布指数,其定义为α-烯烃含量在平均总摩尔含量的50%以内的共聚物分子的重量百分比 α-烯烃,大于45%。
摘要:
Amorphous propylene polymers are disclosed having the following characteristics:(a) intrinsic viscosity [.eta.]>1 d1/g;(b) %(r)-%(m)>0, wherein % (r) is the % of syndiotactic diads and %(m) is the % of isotactic diads;(c) less than 2% of the CH.sub.2 groups contained in sequences (CH.sub.2).sub.n, with n.gtoreq.2;(d) Bernoullianity index (B)=1.+-.0.2.These propylene polymers, which are in addition endowed with a narrow molecular weight distribution, can be obtained directly from the polymerization reaction of propylene as sole product and, therefore, do not require to be separated.
摘要:
Catalysts for the polymerization of alpha-olefins, which comprise the product of the reaction between:(a) a metallorganic compound of Al;(b) an electron-donor compound reactive towards MgCl.sub.2 but which is not completely complexed with AlEt.sub.3, at the equivalent point of a potentiometric titration under standard conditions;(c) a solid comprising a halogenated Ti compound and an electron-donor belonging to particular classes of compounds and being extractable with AlEt.sub.3 for at least 70% by mols from the solid, the surface area of which after extraction is higher than 20 m.sup.2 /g.The present invention refers to new supported components of catalysts for the polymerization of olefins CH.sub.2 .dbd.CHR, in which R is an alkyl with 1-4 carbon atoms or an aryl, and of mixtures of such olefins with each other and/or with ethylene, and to the catalysts obtained from such components.