Agent for the liquid paraffin waxing of yarns
    41.
    发明授权
    Agent for the liquid paraffin waxing of yarns 失效
    纱线液体石蜡打蜡剂

    公开(公告)号:US4322302A

    公开(公告)日:1982-03-30

    申请号:US164036

    申请日:1980-06-30

    摘要: Agent for the liquid paraffin waxing of yarns which consists of(a) from 5 to 20% of paraffin, melting range of 45.degree. to 60.degree. C.;(b) from 2 to 10% of one or several alkyl imidazolines of the formula I ##STR1## in which R is C.sub.12 -C.sub.22 -alkyl, alkenyl or hydroxyalkyl,R.sub.1 is hydrogen or C.sub.1 -C.sub.22 -saturated or unsaturated aliphatic or aromatic acyl,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -hydroxyalkyl,n is a number of from 2 to 6, andX is a halogen anion, a C.sub.1 -C.sub.4 -alkyl sulfate anion, a C.sub.1 -C.sub.4 -dialkyl phosphate anion, or a C.sub.1 -C.sub.4 -alkyl carboxylate anion;(c) from 1 to 5% of one or several aminoxides of the formula II ##STR2## in which R is C.sub.8 -C.sub.12 -alkyl or alkenyl,R.sub.1 is C.sub.1 -C.sub.4 -alkyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, andn is a number of from 0 to 6, and (d) from 5 to 20% of one or several polyglycol ethers of the formula IIIR--O--(C.sub.2 H.sub.4 O).sub.n --H III, in whichR is C.sub.8 -C.sub.18 -alkyl or alkenyl andn is a number of from 3 to 12, as well as water ad 100%.

    摘要翻译: 用于(a)5至20%石蜡,熔点范围为45至60℃的纱线的液体石蜡打蜡剂。 (b)2至10%的一种或几种式I的烷基咪唑啉,其中R是C 12 -C 22 - 烷基,烯基或羟烷基,R 1是氢或C 1 -C 22饱和或不饱和的脂族或芳族 酰基,R 2为氢,C 1 -C 4 - 烷基或C 1 -C 4 - 羟烷基,n为2至6的数,X为卤素阴离子,C1-C4烷基硫酸根阴离子,C1-C4-二烷基 磷酸根阴离子或C1-C4烷基羧酸根阴离子; (c)1至5%的一种或多种式II II的氨基氧化物,其中R是C 8 -C 12 - 烷基或烯基,R 1是C 1 -C 4 - 烷基,R 2是氢或C 1 -C 4烷基 ,和n为0至6的数,和(d)5至20%的一种或多种式III的RO-(C 2 H 4 O)n H III的聚乙二醇醚,其中R为C 8 -C 18 - 烷基或链烯基 n为3〜12,水为100%。

    Sulfide polymers of polyoxyalkylenes
    43.
    发明授权
    Sulfide polymers of polyoxyalkylenes 失效
    聚氧化烯的硫化物聚合物

    公开(公告)号:US4255561A

    公开(公告)日:1981-03-10

    申请号:US78709

    申请日:1979-09-25

    摘要: The sulfide polymers of polyoxyalkylenes having the formula: ##STR1## wherein M is alkyl of from 1 to 4 carbon atoms, benzyl, phenyl, hydrogen or an alkali metal or ammonium ion; A, C and D represent lower alkylene of 2 to 4 carbon atoms; B is alkylene of 2 to 8 carbon atoms; y and z are each integers having a value of 0 to 50; x is an integer having a value of from 1 to 50; n is an integer having a value of 1 to 30; and m has a value of from 2 to 10; and intermixtures of said polyoxyalkylene sulfide polymers.The above polymers have excellent antioxidating properties and are useful as synthetic metal working lubricants, antistatic agents and antioxidants for various other types of applications. They can also be used as crosslinking agents to impart oxidation resistance and static elimination.

    摘要翻译: 具有下式的聚氧化烯的硫化物聚合物:MS {[(AO)x(BO)y(CO)z] nDS} m M I.其中M是1至4个碳原子的烷基,苄基,苯基,氢或 碱金属或铵离子; A,C和D表示2至4个碳原子的低级亚烷基; B是2至8个碳原子的亚烷基; y和z分别为0〜50的整数。 x是1至50的整数; n为1〜30的整数, m的值为2〜10; 和所述聚氧化烯硫化物聚合物的混合物。 上述聚合物具有优异的抗氧化性能,可用作各种其它类型应用的合成金属加工润滑剂,抗静电剂和抗氧化剂。 它们也可以用作交联剂以赋予抗氧化性和静电消除。

    Anionic fluorochemical surfactants, process of coating and treated
polymeric shapes
    44.
    发明授权
    Anionic fluorochemical surfactants, process of coating and treated polymeric shapes 失效
    阴离子含氟表面活性剂,涂层和处理聚合物形状的工艺

    公开(公告)号:US4208466A

    公开(公告)日:1980-06-17

    申请号:US942993

    申请日:1978-09-18

    申请人: Alex J. Szur

    发明人: Alex J. Szur

    摘要: 6-Hydroxyhexyl perfluoroisopropyl ether is prepared by reaction of hexafluoroacetone and potassium fluoride to obtain an alcoholate which is then reacted with 1-chloro-6-hexanol. One mole of the ether may be reacted with about 1 mole to about 20 moles of ethylene oxide to produce a hydroxyethyl ether. One mole of 2,2,3,4,4,4-hexafluorobutanol may be reacted with from about 1 to about 5 moles of propylene oxide to produce a hydroxypropyl ether. One mole of hexafluorobutanol may also be reacted with about 1 to about 5 moles of propylene oxide and then about 1 mole to about 20 moles of ethylene oxide to produce a hydroxyethyl ether. The hydroxyhexyl ether, hydroxylpropyl ether and both hydroxyethyl ethers may be sulfated to produce anionic surfactants which are useful as antistatic agents and lubricants for polymeric shapes such as nylon films and filaments.

    摘要翻译: 通过六氟丙酮和氟化钾的反应制备6-羟基己基全氟异丙醚,得到醇化物,然后与1-氯-6-己醇反应。 1摩尔的醚可以与约1摩尔至约20摩尔的环氧乙烷反应以产生羟乙基醚。 1摩尔的2,2,3,4,4,4-六氟丁醇可以与约1至约5摩尔的环氧丙烷反应以产生羟丙基醚。 1摩尔六氟丁醇也可以与约1至约5摩尔环氧丙烷反应,然后与约1摩尔至约20摩尔环氧乙烷反应,生成羟乙基醚。 羟基己基醚,羟丙基醚和两羟乙基醚可以被硫酸化以产生可用作抗静电剂的阴离子表面活性剂和用于聚合物形状的润滑剂,例如尼龙膜和长丝。

    Method for providing polymers with durable improved properties

    公开(公告)号:US4045510A

    公开(公告)日:1977-08-30

    申请号:US616183

    申请日:1975-09-24

    申请人: Robert B. Login

    发明人: Robert B. Login

    摘要: Polymers reactive towards free amino groups, such as polyamides, polyureas, polyurethanes or polyesters, are provided with durable modified properties by being brought into contact with an additive polymeric material which (a) is compatible with the polymer being treated, (b) contains a plurality of oxyalkylene groups effective to impart to the modified polymer improved properties such as reduced static propensity, modified dyeability, or greater water absorbency; and (c) has one or more reactive sites, in the form of a pendant free primary amino group or potential primary amino group, blocked by the dehydration of an aldehyde or a ketone with the amine, which in either case affords the capability in proper circumstances of attaching the modifying polymeric material to the polymer being treated by a covalent chemical bond. Suitable modifying polymers are made by reacting a diamino or higher amino compound with a proportion of an aldehyde or ketone sufficient to block at least some of the amino groups present, oxyalkylating the blocked starting material through a surviving amino group to an extent capable of affording the desired properties, and if desired, cross-linking or chain-extending the resulting material to obtain a substance of increased molecular weight. Modifying polymers so made may be used as such (i.e., in the aldehyde- or ketone-blocked form) for treatment of the reactable polymer to be modified, either by blending into a melt or by surface treatment of freshly produced fiber or sheet material. The formation of free amino groups in the modifying polymer can occur in situ when the modified polymer is exposed to water under suitable conditions. The modifying polymer may also be used in a free amino form generated by hydrolyzing before bringing it into contact with the polymer to be modified. Novel treated polymers are thus produced which display modified properties which are retained despite repeated washings and/or long-continued use.