Olefin-dimercapto-thiadiazole compositions and process
    35.
    发明授权
    Olefin-dimercapto-thiadiazole compositions and process 失效
    烯属 - 二巯基 - 噻二唑组合物和方法

    公开(公告)号:US4097387A

    公开(公告)日:1978-06-27

    申请号:US720266

    申请日:1976-09-03

    申请人: Gunter Caspari

    发明人: Gunter Caspari

    摘要: Disclosed are a composition of matter, a process for making said composition, and a lubricating oil composition having improved anti-wear properties containing an effective amount of said composition of matter. The composition of matter comprises olefin-dimercapto-thiadiazole compositions, especially an oil soluble reaction product of an olefin; lithium, sodium or potassium 2,5-dimercapto-1,3,4-thiadiazole or mixtures thereof; and a member selected from the group consisting of S.sub.2 Cl.sub.2, SCl.sub.2, S.sub.2 Br.sub.2, SBr.sub.2, R-S-Cl, R-S-Br, and mixtures thereof, wherein R comprises C.sub.1 -C.sub.100 hydrocarbyl or bromo, chloro or hydroxy substituted hydrocarbyl. Some of these compositions can be represented as follows: ##STR1## wherein X comprises R.sub.1 -SS-R.sub.2, wherein R.sub.1 comprises a C.sub.6 -C.sub.100 hydrocarbyl or bromo, chloro or hydroxy substituted hydrocarbyl, and R.sub.2 comprises R.sub.1 or ##STR2## and wherein Y comprises H or X. Preferably R.sub.1 comprises C.sub.6 -C.sub.100 alkene or alkane, still more perferably, C.sub.6 -C.sub.20 alkene or alkane. These compositions are effective wear inhibitors in lubricating oil. The process for making oil soluble derivatives of 2,5-dimercapto-1,3,4-thiadiazole comprises first reacting an olefin with a member selected from the group consisting of S.sub.2 Cl.sub.2, SCl.sub.2, S.sub.2 Br.sub.2, SBr.sub.2, R-S-Cl, R-S-Br, and mixtures thereof, to form a first reaction product; and then reacting said first reaction product with lithium, sodium or potassium 2,5-dimercapto-1,3,4-thiadiazole or mixtures thereof.

    摘要翻译: 公开了一种物质组合物,一种制备该组合物的方法,以及具有改善的抗磨损性能的润滑油组合物,其含有有效量的所述组合物。

    Fire resistant functional fluids
    37.
    发明授权
    Fire resistant functional fluids 失效
    耐火功能液

    公开(公告)号:US4001129A

    公开(公告)日:1977-01-04

    申请号:US520052

    申请日:1974-11-01

    IPC分类号: C10M169/00 C10M3/40 C10M3/32

    摘要: A functional fluid composition consisting essentially of (1) a phosphorus compound, preferably a phosphate ester containing at least two alkyl groups such as tributyl phosphate or di-n-butyl phenyl phosphate, alone or particularly in combination with a phosphate ester containing at least two aromatic groups, such as n-butyl diphenyl phosphate or tricresyl phosphate, (2) a polyalkylene glycol material, e.g. a polypropylene glycol ether having a molecular weight ranging from about 600 to about 1200, and particularly a combination of at least two polyalkylene glycol materials, e.g. two polypropylene glycol ethers having substantially different molecular weights, (3) a dicarboxylic acid ester, e.g. a diester of adipic acid such as diisodecyl adipate, and (4) a small amount of certain halogenated organic selenides or tellurides, preferably a chlorinated aryl selenide such as 4,4'-dichlorodiphenyl diselenide, or a chlorinated selenophene or a chlorinated tellurophene, e.g. tetrachloroselenophene or tetrachlorotellurophene.

    摘要翻译: 一种功能性流体组合物,其主要由(1)磷化合物,优选含有至少两个烷基的磷酸酯,例如磷酸三丁酯或磷酸二正丁基苯酯,单独或特别是与含有至少两个 芳族基团,例如磷酸正丁基二苯酯或磷酸三甲苯酯,(2)聚亚烷基二醇材料, 分子量为约600至约1200的聚丙二醇醚,特别是至少两种聚亚烷基二醇材料的组合,例如聚亚烷基二醇。 两个具有基本不同分子量的聚丙二醇醚,(3)二羧酸酯, 己二酸的二酯,例如己二酸二异癸酯,和(4)少量的某些卤化有机硒化物或碲化物,优选氯化芳基硒化物如4,4'-二氯二苯基二硒化物,或氯化硒吩或氯化的特氟丙烯,例如。 四氯硒吩或四氯全氟丙烯。