摘要:
Process of sulfurizing a blend of 90 to 50 and preferably 88 to 70 parts by volume of triglyceride such as lard oil and 10 to 50 and preferably 12 to 30 parts by volume of an ethylenically unsaturated hydrocarbon containing 2 to 24 carbon atoms. The sulfurization is carried out using elemental sulfur. Simultaneous sulfurization and chlorination may be effected by reacting with sulfur monochloride. Phosphosulfurization may also be carried out by addition of small amounts of a phosphorus sulfide to the sulfurized blend followed by heating at 180.degree. F. to 250.degree. F. for from 30 minutes to 10 hours to effect phosphosulfurization. The sulfurization or phosphosulfurization involves reacting at from 350.degree. F. to 445.degree. F. for 20 minutes to 10 hours followed by blowing with a gas at from 125.degree. F. to 250.degree. F. for 30 minutes to 20 hours to remove hydrogen sulfide. The simultaneous sulfurization and chlorination reaction is carried out at from 90.degree. F. to 280.degree. F. for from 20 minutes to 10 hours followed by blowing with a gas at from 125.degree. F. for 30 minutes to 20 hours. The sulfurized oils contain from 7.5 to 25 weight percent sulfur as based on the blend of olefin and triglyceride.
摘要:
A synthetic sulfurized oil, useful as an additive to lubricants, and especially as a replacement for sulfurized sperm oil, is produced by reaction of sulfur, lard oil and polyisobutylene oligimers containing at least one pair of maximally crowded geminal methyl groups (e.g. "tetraisobutylene"). Preferably, sufficient sulfur to obtain a final sulfurized product containing in the range of about 5-25 weight percent sulfur is reacted with a mixture comprising about 30-90 parts by weight of lard oil and 70-10 parts of the polyisobutylene. Minor amounts (e.g. up to about 15 weight percent) of other unsaturated hydrocarbons (e.g. "C.sub.18 olefin") can also be present in the mixture.
摘要:
Compositions of improved antioxidant characteristics are provided comprising organic media, normally susceptible to oxidation, e.g., oils of lubricant viscosity and greases prepared therefrom containing a minor amount sufficient to impart antioxidant properties thereto of an admixture of a polydisulfide having at least one unit therein with the following structure: ##STR1## WHERE N IS FROM 2 TO ABOUT 20 AND R and R.sub.1 are hydrogen or C.sub.1 -C.sub.10 alkyl; and a compound selected from the group consisting of arylamines and hindered phenols.
摘要:
Sulfurized compositions are prepared by the reaction of unsaturated compounds and a mixture of sulfur and hydrogen sulfide under superatmospheric pressure and in the presence of a catalyst, followed by removal of low boiling materials. They are useful as lubricant additives.
摘要:
Disclosed are a composition of matter, a process for making said composition, and a lubricating oil composition having improved anti-wear properties containing an effective amount of said composition of matter. The composition of matter comprises olefin-dimercapto-thiadiazole compositions, especially an oil soluble reaction product of an olefin; lithium, sodium or potassium 2,5-dimercapto-1,3,4-thiadiazole or mixtures thereof; and a member selected from the group consisting of S.sub.2 Cl.sub.2, SCl.sub.2, S.sub.2 Br.sub.2, SBr.sub.2, R-S-Cl, R-S-Br, and mixtures thereof, wherein R comprises C.sub.1 -C.sub.100 hydrocarbyl or bromo, chloro or hydroxy substituted hydrocarbyl. Some of these compositions can be represented as follows: ##STR1## wherein X comprises R.sub.1 -SS-R.sub.2, wherein R.sub.1 comprises a C.sub.6 -C.sub.100 hydrocarbyl or bromo, chloro or hydroxy substituted hydrocarbyl, and R.sub.2 comprises R.sub.1 or ##STR2## and wherein Y comprises H or X. Preferably R.sub.1 comprises C.sub.6 -C.sub.100 alkene or alkane, still more perferably, C.sub.6 -C.sub.20 alkene or alkane. These compositions are effective wear inhibitors in lubricating oil. The process for making oil soluble derivatives of 2,5-dimercapto-1,3,4-thiadiazole comprises first reacting an olefin with a member selected from the group consisting of S.sub.2 Cl.sub.2, SCl.sub.2, S.sub.2 Br.sub.2, SBr.sub.2, R-S-Cl, R-S-Br, and mixtures thereof, to form a first reaction product; and then reacting said first reaction product with lithium, sodium or potassium 2,5-dimercapto-1,3,4-thiadiazole or mixtures thereof.
摘要:
Compositions containing a base lubricant, an antiwear amount of a polypropylene glycol and sulfur; and a solubility improving amount of a monohydric alcohol having from 5 to 30 carbon atoms are provided. These compositions are especially useful for metal working and cutting applications.
摘要:
A functional fluid composition consisting essentially of (1) a phosphorus compound, preferably a phosphate ester containing at least two alkyl groups such as tributyl phosphate or di-n-butyl phenyl phosphate, alone or particularly in combination with a phosphate ester containing at least two aromatic groups, such as n-butyl diphenyl phosphate or tricresyl phosphate, (2) a polyalkylene glycol material, e.g. a polypropylene glycol ether having a molecular weight ranging from about 600 to about 1200, and particularly a combination of at least two polyalkylene glycol materials, e.g. two polypropylene glycol ethers having substantially different molecular weights, (3) a dicarboxylic acid ester, e.g. a diester of adipic acid such as diisodecyl adipate, and (4) a small amount of certain halogenated organic selenides or tellurides, preferably a chlorinated aryl selenide such as 4,4'-dichlorodiphenyl diselenide, or a chlorinated selenophene or a chlorinated tellurophene, e.g. tetrachloroselenophene or tetrachlorotellurophene.
摘要:
A cosulfurized product of a mixture of (a) a triglyceride having an iodine value greater than 80, preferably rapeseed oil, and (b) nonwax ester comprising the methyl ester of a fatty acid having from 18 to 22 carbon atoms or a mixture thereof, said fatty acid being predominantly monoethylenically unsaturated, has excellent extreme pressure and low temperature properties and is an effective substitute for sulfurized sperm oil.
摘要:
Compositions suitable as replacements for sulfurized sperm oil as extreme pressure additives in lubricants are obtained by sulfurizing a mixture of at least one fatty acid ester (preferably an oil such as soybean oil), at least one C.sub.8 -.sub.36 aliphatic olefin (preferably an .alpha.-olefin), and, optionally, at least one fatty acid (preferably unsaturated).
摘要:
New lubricating compositions are characterized in that in addition to the basic oil, they contain an organic sulfur compound which is a heterocyclic disulfide, which can contain sulfide moieties, containing not more than one carbon atom between heterocyclic sulfur atoms. The lubricating oils are useful as high pressure oils.