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    Method for mask-free localized organic grafting on conductive or semiconductive portions of composite surfaces
    31.
    发明授权
    Method for mask-free localized organic grafting on conductive or semiconductive portions of composite surfaces 有权
    在复合表面的导电或半导体部分上进行无掩模的局部有机接枝的方法

    公开(公告)号：US08394460B2

    公开(公告)日：2013-03-12

    申请号：US10614516

    申请日：2003-07-08

    Applicant: Christophe Bureau ,  Serge Palacin ,  Jean-Philippe Bourgoin ,  Sami Ameur ,  Julienne Charlier

    Inventor： Christophe Bureau ,  Serge Palacin ,  Jean-Philippe Bourgoin ,  Sami Ameur ,  Julienne Charlier

    IPC: B05D1/04 ,  B05D3/02

    CPC classification number: C09D5/4476 ,  B05D1/007 ,  B05D1/18

    Abstract: A process for mask-free localized grafting of organic molecules capable of being electrically activated, onto a composite surface comprising conductive and/or semiconductive portions, by placing said organic molecules in contact with said composite surface, in which said grafting is performed electrochemically in a single step on chosen, defined areas of said conductive and/or semiconductive portions, said areas being brought to a potential higher than or equal to a threshold electrical potential determined relative to a reference electrode, said threshold electrical potential being the potential above which grafting of said organic molecules takes place.

    Abstract translation: 通过将所述有机分子与所述复合表面接触而将能够电激活的有机分子的无掩模局部接枝到包含导电和/或半导体部分的复合表面上的方法，其中所述接枝在电化学 在所述导电和/或半导体部分的选定的限定区域上的单步骤，所述区域被置于高于或等于相对于参考电极确定的阈值电位的电位，所述阈值电势是其上 表示有机分子发生。

    Process for coating electrically conductive substrates
    34.
    发明授权
    Process for coating electrically conductive substrates 失效
    涂覆导电基材的方法

    公开(公告)号：US07862851B2

    公开(公告)日：2011-01-04

    申请号：US11568523

    申请日：2005-05-25

    Applicant: Heinrich Wonnemann ,  Lars Hof ,  Werner Blömer

    Inventor： Heinrich Wonnemann ,  Lars Hof ,  Werner Blömer

    IPC: B05D5/12 ,  C09D5/00

    CPC classification number: B05D7/542 ,  B05D1/007 ,  B05D7/544 ,  C08G59/42 ,  C09D5/033 ,  C09D5/4488

    Abstract: A process for coating electrically conductive substrates by (1) applying an electrocoat film to an electrically conductive substrate and curing it to give an electrocoat and then (2) applying a layer of a pulverulent coating material to the electrocoat and curing it to give a powder coat or alternatively (1) applying an electrocoat film to an electrically conductive substrate and drying it without fully curing it, (2) applying a layer of a pulverulent coating material to the dried electrocoat film(s) and (3) jointly curing the dried electrocoat film and the layer of the pulverulent coating material to give the electrocoat and the powder coat wherein the pulverulent coating material comprises (A) at least one epoxy resin having a melting point, melting range or glass transition temperature>30° C., (B) at least one carboxyl-containing polyester resin having a melting point, melting range or glass transition temperature>30° C., and (C) at least one polycarboxylic acid having a melting point of between 80 and 160° C.

    Abstract translation: （1）将电泳涂层涂布在导电性基材上并进行固化，得到电泳涂层，然后（2）将一层粉状涂料施涂到电泳衣上并使其固化得到粉末的方法， 或者（1）将电涂膜施加到导电基材上并干燥而不完全固化，（2）将一层粉状涂料施加到干燥的电泳涂膜上，和（3）将干燥的 电涂层和粉末涂料层，得到电涂层和粉末涂料，其中粉末涂料包含（A）至少一种具有熔点，熔点或玻璃化转变温度> 30℃的环氧树脂（ B）至少一种具有熔点，熔点或玻璃化转变温度> 30℃的含羧基聚酯树脂，和（C）至少一种具有熔融p的多元羧酸 80至160℃之间的软膏

    METHODS UTILIZING SCANNING PROBE MICROSCOPE TIPS AND PRODUCTS THEREOF OR PRODUCED THEREBY
    35.
    发明申请
    METHODS UTILIZING SCANNING PROBE MICROSCOPE TIPS AND PRODUCTS THEREOF OR PRODUCED THEREBY 有权
    使用扫描探针显微镜的方法及其产品或其生产方法

    公开(公告)号：US20100330345A1

    公开(公告)日：2010-12-30

    申请号：US11933251

    申请日：2007-10-31

    Applicant: Chad A MIRKIN ,  Richard Piner ,  Seunghun Hong

    Inventor： Chad A MIRKIN ,  Richard Piner ,  Seunghun Hong

    IPC: G01Q60/24 ,  B05D5/00 ,  C23F1/04 ,  B05C1/00 ,  B05C13/00 ,  G01Q80/00 ,  B32B3/10 ,  C40B40/00

    CPC classification number: B82B3/00 ,  B05D1/007 ,  B05D1/185 ,  B05D1/26 ,  G01Q80/00 ,  G03F7/0002 ,  G03F7/165 ,  Y10S977/849 ,  Y10S977/853 ,  Y10S977/854 ,  Y10S977/855 ,  Y10S977/856 ,  Y10S977/857 ,  Y10S977/86 ,  Y10S977/88 ,  Y10S977/884 ,  Y10S977/885 ,  Y10S977/886 ,  Y10S977/895 ,  Y10T428/24802

    Abstract: The invention provides a lithographic method referred to as “dip pen” nanolithography (DPN). DPN utilizes a scanning probe microscope (SPM) tip (e.g., an atomic force microscope (AFM) tip) as a “pen,” a solid-state substrate (e.g., gold) as “paper,” and molecules with a chemical affinity for the solid-state substrate as “ink.” Capillary transport of molecules from the SPM tip to the solid substrate is used in DPN to directly write patterns consisting of a relatively small collection of molecules in submicrometer dimensions, making DPN useful in the fabrication of a variety of microscale and nanoscale devices. The invention also provides substrates patterned by DPN, including submicrometer combinatorial arrays, and kits, devices and software for performing DPN. The invention further provides a method of performing AFM imaging in air. The method comprises coating an AFM tip with a hydrophobic compound, the hydrophobic compound being selected so that AFM imaging performed using the coated AFM tip is improved compared to AFM imaging performed using an uncoated AFM tip. Finally, the invention provides AFM tips coated with the hydrophobic compounds.

    Abstract translation: 本发明提供了称为“浸笔”纳米光刻（DPN）的光刻方法。 DPN使用扫描探针显微镜（SPM）尖端（例如，原子力显微镜（AFM）尖端）作为“笔”，固态基底（例如，金）作为“纸”，并且具有化学亲和力的分子 固体底物作为“墨水”。DPN中使用分子从SPM尖端到固体基质的毛细管转运，以直接写入由亚微米尺寸的相对小的分子集合组成的图案，使得DPN可用于制造 各种微米级和纳米级器件。 本发明还提供由DPN图案化的衬底，包括亚微米组合阵列，以及用于执行DPN的试剂盒，装置和软件。 本发明还提供了一种在空气中进行AFM成像的方法。 该方法包括用疏水性化合物涂覆AFM尖端，选择疏水性化合物，使得与使用未涂覆的AFM尖端进行的AFM成像相比，使用涂覆的AFM尖端进行的AFM成像得到改善。 最后，本发明提供涂覆有疏水化合物的AFM尖端。

    Method of forming multi-layer coatings on automobile bodies without a primer bake
    38.
    发明授权
    Method of forming multi-layer coatings on automobile bodies without a primer bake 有权
    在没有底漆的汽车车身上形成多层涂层的方法

    公开(公告)号：US07740912B2

    公开(公告)日：2010-06-22

    申请号：US11543675

    申请日：2006-10-05

    Applicant: Peter William Uhlianuk ,  Delson Jayme Trindade ,  San C. Yuan

    Inventor： Peter William Uhlianuk ,  Delson Jayme Trindade ,  San C. Yuan

    IPC: B05D3/02 ,  B05D7/00 ,  C08F8/30

    CPC classification number: C09D175/04 ,  B05D1/007 ,  B05D7/572 ,  B05D7/577 ,  C08G18/6233 ,  C08G18/6254 ,  C08G18/631 ,  C09D5/002 ,  C09D133/062 ,  Y10T428/31935 ,  C08L2666/16

    Abstract: This invention relates to a method for forming a multi-layer coating on a vehicle body, comprised of applying primer coating, base coating, and clear coat layers in a wet-on-wet-on-wet manner, and simultaneously curing the applied three layers together in a single baking step. The primer layer comprises a film-forming binder (a) a caprolactone-modified linear acrylic polymer; and (b) an aminoplast resin crosslinking agent, wherein the composition is essentially free of crosslinked nonaqueous dispersion resin particles or crosslinked microgel resin particles or both. The resulting multi-layered coating film has excellent aesthetic appearance, strike-in resistance, chipping resistance, sag resistance, and film build even when formed in a three wet layered application method.

    Abstract translation: 本发明涉及一种在车身上形成多层涂层的方法，其特征在于，以湿式湿式湿式方式涂布底涂层，底涂层和透明涂层，同时固化涂布的三层 在一个烘烤步骤中将层合在一起。 底漆层包括成膜粘合剂（a）己内酯改性的线型丙烯酸聚合物; 和（b）氨基塑料树脂交联剂，其中所述组合物基本上不含交联的非水分散树脂颗粒或交联的微粒凝胶树脂颗粒或两者。 所得到的多层涂膜即使在三湿分层涂布方法中形成，也具有优异的美学外观，耐冲击性，耐崩裂性，耐下落性和成膜性。

    METHODS UTILIZING SCANNING PROBE MICROSCOPE TIPS AND PRODUCTS THEREFOR OR PRODUCED THEREBY
    39.
    发明申请
    METHODS UTILIZING SCANNING PROBE MICROSCOPE TIPS AND PRODUCTS THEREFOR OR PRODUCED THEREBY 有权
    使用扫描探针显微镜的方法和产品或其生产的产品

    公开(公告)号：US20100098857A1

    公开(公告)日：2010-04-22

    申请号：US12534086

    申请日：2009-07-31

    Applicant: Chad A. Mirkin ,  Richard Piner ,  Seunghun Hong

    Inventor： Chad A. Mirkin ,  Richard Piner ,  Seunghun Hong

    IPC: B05D5/00

    CPC classification number: B82B3/00 ,  B05D1/007 ,  B05D1/185 ,  B05D1/26 ,  G01Q80/00 ,  G03F7/0002 ,  G03F7/165 ,  Y10S977/84 ,  Y10S977/857 ,  Y10S977/863 ,  Y10S977/877 ,  Y10T428/24917 ,  Y10T436/24

    Abstract: The invention provides a lithographic method referred to as “dip pen” nanolithography (DPN). DPN utilizes a scanning probe microscope (SPM) tip (e.g., an atomic force microscope (AFM) tip) as a “pen,” a solid-state substrate (e.g., gold) as “paper,” and molecules with a chemical affinity for the solid-state substrate as “ink.” Capillary transport of molecules from the SPM tip to the solid substrate is used in DPN to directly write patterns consisting of a relatively small collection of molecules in submicrometer dimensions, making DPN useful in the fabrication of a variety of microscale and nanoscale devices. The invention also provides substrates patterned by DPN and kits for performing DPN.The invention further provides a method of performing AFM imaging in air. The method comprises coating an AFM tip with a hydrophobic compound, the hydrophobic compound being selected so that AFM imaging performed using the coated AFM tip is improved compared to AFM imaging performed using an uncoated AFM tip. Finally, the invention provides AFM tips coated with the hydrophobic compounds.

    Abstract translation: 本发明提供了称为“浸笔”纳米光刻（DPN）的光刻方法。 DPN使用扫描探针显微镜（SPM）尖端（例如，原子力显微镜（AFM）尖端）作为“笔”，固态基底（例如，金）作为“纸”，并且具有化学亲和力的分子 固体底物作为“墨水”。DPN中使用分子从SPM尖端到固体基质的毛细管转运，以直接写入由亚微米尺寸的相对小的分子集合组成的图案，使得DPN可用于制造 各种微米级和纳米级器件。 本发明还提供由DPN图案化的基材和用于进行DPN的试剂盒。 本发明还提供了一种在空气中进行AFM成像的方法。 该方法包括用疏水性化合物涂覆AFM尖端，选择疏水性化合物，使得与使用未涂覆的AFM尖端进行的AFM成像相比，使用涂覆的AFM尖端进行的AFM成像得到改善。 最后，本发明提供涂覆有疏水化合物的AFM尖端。

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