公开(公告)号：US09938457B1

公开(公告)日：2018-04-10

申请号：US15270657

申请日：2016-09-20

Applicant: General Electric Company

Inventor： Digamber Gurudas Porob ,  James Edward Murphy ,  Florencio Garcia ,  Srinivas Prasad Sista ,  Anant Achyut Setlur ,  William Winder Beers ,  Fangming Du

IPC: C09K11/61 ,  H01L33/00 ,  H01L33/06 ,  H01L33/32 ,  H01L33/56 ,  H01L33/50 ,  H01L33/62 ,  H01L25/075

CPC classification number: C09K11/617 ,  C09K11/02 ,  H01L25/0753 ,  H01L33/0095 ,  H01L33/06 ,  H01L33/32 ,  H01L33/502 ,  H01L33/56 ,  H01L33/62 ,  H01L2933/0041 ,  H01L2933/005 ,  H01L2933/0066

Abstract: Methods for fabricating coated semiconductor elements are presented. The methods include the steps of combining a phosphor of formula I and a polymer binder to form a composite material, providing a semiconductor wafer including IniGajAlkN, wherein 0≤i; 0≤j; 0≤k, and a sum of i, j and k is equal to 1, coating the composite material on a surface of the semiconductor wafer to form a coated semiconductor wafer, and dicing the coated semiconductor wafer using a cutting fluid apparatus to form one or more coated semiconductor elements. A cutting fluid of the cutting fluid apparatus includes a C1-C20 alcohol, a C1-C20 ketone, a C1-C20 acetate compound, acetic acid, oleic acid, carboxylic acid, a source of A, silicic acid, or a combination thereof.

公开(公告)号：US20180040782A1

公开(公告)日：2018-02-08

申请号：US15231026

申请日：2016-08-08

Applicant: General Electric Company

Inventor： Digamber Gurudas Porob ,  James Edward Murphy ,  Florencio Garcia ,  Megan Marie Brewster

IPC: H01L33/50 ,  C09K11/61 ,  H01L33/64 ,  C08K3/08 ,  C08K3/00 ,  H01L33/56 ,  C09K11/02 ,  C08K3/34

CPC classification number: H01L33/502 ,  C08K3/013 ,  C08K3/08 ,  C08K3/34 ,  C08K2201/001 ,  C08K2201/005 ,  C09K11/02 ,  C09K11/025 ,  C09K11/616 ,  C09K11/617 ,  H01L33/501 ,  H01L33/56 ,  H01L33/644

Abstract: A lighting apparatus includes an LED light source radiationally coupled to a composite material including a phosphor of formula I and a thermally conductive material dispersed in at least a portion of a binder material. The thermally conductive material includes a material selected from the group consisting of indium oxide, tin oxide, indium tin oxide, calcium oxide, barium oxide, strontium oxide, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, strontium hydroxide, zinc hydroxide, aluminum phosphate, magnesium phosphate, calcium phosphate, barium phosphate, strontium phosphate, diamond, graphene, polyethylene nanofibers, carbon nanotubes, silver metal nanoparticles, copper metal nanoparticles, gold metal nanoparticles, aluminum metal nanoparticles, boron nitride, silicon nitride, an alkali metal halide, calcium fluoride, magnesium fluoride, a compound of formula II, and combinations thereof.

公开(公告)号：US20170254943A1

公开(公告)日：2017-09-07

申请号：US15370762

申请日：2016-12-06

Applicant: GENERAL ELECTRIC COMPANY

Inventor： James Edward Murphy

IPC: F21V8/00

Abstract: A remote phosphor package according to the present invention includes a green emitting quantum dot material and a Mn4+ doped phosphor of formula I, dispersed in a host matrix wherein A is Li, Na, K, Rb, Cs, or combinations thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or combinations thereof; x is an absolute value of a charge of the [MFy] ion; and y is 5, 6 or 7.

公开(公告)号：US09580648B2

公开(公告)日：2017-02-28

申请号：US14285746

申请日：2014-05-23

Applicant: GENERAL ELECTRIC COMPANY

Inventor： James Edward Murphy ,  Anant Achyut Setlur ,  Florencio Garcia ,  Robert Joseph Lyons ,  Ashfaqul Islam Chowdhury ,  Nagaveni Karkada ,  Prasanth Kumar Nammalwar

IPC: C09K11/61 ,  C09K11/67 ,  H01L33/50

CPC classification number: C09K11/617 ,  C08K3/34 ,  C09K11/025 ,  C09K11/616 ,  H01L33/502 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00012

Abstract: A color stable Mn4+ doped phosphor of formula I, Ax[MFy]:Mn4+  I wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and wherein % intensity loss of the phosphor after exposure to light flux of at least 80 w/cm2 at a temperature of at least 50° C. for at least 21 hours is ≦4%.

Abstract translation: 式I的颜色稳定的Mn4 +掺杂的荧光体，Ax [MFy]：Mn4 + I，其中A是Li，Na，K，Rb，Cs或它们的组合; M是Si，Ge，Sn，Ti，Zr，Al，Ga，In，Sc，Hf，Y，La，Nb，Ta，Bi，Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y为5,6或7; 并且其中在至少80℃的温度下暴露至少80w / cm 2的光通量至少21小时后的荧光粉的强度损失百分比为±4％。

公开(公告)号：US09512356B2

公开(公告)日：2016-12-06

申请号：US14267434

申请日：2014-05-01

Applicant: GENERAL ELECTRIC COMPANY

Inventor： Robert Joseph Lyons ,  James Edward Murphy ,  Anant Achyut Setlur, Jr.

IPC: C09K11/61 ,  C09K11/08 ,  H01L33/50

CPC classification number: C09K11/617 ,  H01L33/502 ,  H01L33/507 ,  H01L2224/48091 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00012

Abstract: A process for preparing a Mn4+ doped phosphor of formula I Ax[MFy]:Mn+4   I includes combining in an acidic solution, an A+ cation, an anion of formula MFy, and a Mnn+ source comprising a fluoromanganese compound, precipitating a Mnn+ containing phosphor precursor from the acidic solution, and contacting the Mnn+ containing phosphor precursor with a fluorine-containing oxidizing agent in gaseous form, at an elevated temperature, to form the Mn4+ doped phosphor; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and n is 2 or 3.

公开(公告)号：US20150361335A1

公开(公告)日：2015-12-17

申请号：US14303020

申请日：2014-06-12

Applicant: General Electric Company

Inventor： James Edward Murphy ,  Anant Achyut Setlur ,  Florencio Garcia ,  Srinivas Prasad Sista

IPC: C09K11/61 ,  F21K99/00 ,  F21V9/16

CPC classification number: C09K11/616 ,  C09K11/617 ,  F21K9/60 ,  F21V9/30 ,  H01L33/502 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2924/181 ,  H01L2924/00012

Abstract: A process for synthesizing a manganese (Mn4+) doped phosphor includes milling particles of the a phosphor precursor of formula I, and contacting the milled particles with a fluorine-containing oxidizing agent at an elevated temperature Ax[MFy]:Mn4+  (I) wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7.

Abstract translation: 用于合成锰（Mn4 +）掺杂荧光体的方法包括研磨式I的荧光体前体的研磨颗粒，并且在升高的温度下将碾磨的颗粒与含氟氧化剂接触。[MFy]：Mn4 +（I）其中A 是Li，Na，K，Rb，Cs或它们的组合; M是Si，Ge，Sn，Ti，Zr，Al，Ga，In，Sc，Hf，Y，La，Nb，Ta，Bi，Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y是5,6或7。

公开(公告)号：US20150166887A1

公开(公告)日：2015-06-18

申请号：US14568396

申请日：2014-12-12

Applicant: GENERAL ELECTRIC COMPANY

Inventor： James Edward Murphy ,  William Winder Beers ,  Robert Joseph Lyons ,  Fangming Du

IPC: C09K11/61 ,  H01L33/50

CPC classification number: C09K11/616 ,  H01L33/502 ,  H01L33/507 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2924/181 ,  H01L2924/00012

Abstract: A process for preparing a color stable Mn4+ doped complex fluoride phosphor of formula I includes Ax(M(1−m),Mnm)Fy  (I) contacting a first aqueous HF solution comprising (1−m) parts of a compound of formula HxMFy, and a second aqueous HF solution comprising m*n parts of a compound of formula Ax[MnFy], with a third aqueous HF solution comprising (1−n) parts of the compound of formula Ax[MnFy] and a compound of formula AaX, to yield a precipitate comprising the color stable Mn4+ doped complex fluoride phosphor; wherein A is Li, Na, K, Rb, Cs, NR4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; X is an anion; a is the absolute value of the charge of the X anion; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; 0

Abstract translation: 制备式I的颜色稳定的Mn4 +掺杂复合氟化物荧光体的方法包括与包含（1-m）份式H x M F y的化合物的第一HF水溶液接触的M 1（M（1-m），Mnm） 和包含m * n个分子式Ax [MnFy]化合物的第二HF水溶液与包含（1-n）份式Ax [MnF y]化合物和式AaX化合物的第一HF水溶液 以产生包含颜色稳定的Mn4 +掺杂的复合氟化物荧光体的沉淀物; 其中A为Li，Na，K，Rb，Cs，NR4或其组合; M是Si，Ge，Sn，Ti，Zr，Al，Ga，In，Sc，Hf，Y，La，Nb，Ta，Bi，Gd或它们的组合; R是H，低级烷基或它们的组合; X是阴离子; a是X阴离子电荷的绝对值; x是[MFy]离子的电荷的绝对值; y为5,6或7; 0

公开(公告)号：US20230279254A1

公开(公告)日：2023-09-07

申请号：US18150675

申请日：2023-01-05

Applicant: General Electric Company

Inventor： Mark D. Doherty ,  Yangang Liang ,  Jie Jerry Liu ,  Samuel Joseph Camardello ,  James Edward Murphy

IPC: C09D11/38 ,  G03F7/004 ,  C09K11/02 ,  C09K11/61 ,  C09K11/71 ,  G02F1/13357 ,  F21V8/00 ,  F21V9/30 ,  H01L33/50 ,  C09D11/322

CPC classification number: C09D11/38 ,  C09D11/322 ,  C09K11/025 ,  C09K11/617 ,  C09K11/71 ,  C09K11/717 ,  F21V9/30 ,  G02B6/0053 ,  G02B6/0073 ,  G02F1/133603 ,  G02F1/133617 ,  G03F7/0042 ,  H01L33/502 ,  C08K2003/328 ,  C08K2201/005

Abstract: A color conversion film is provided. The film includes at least one narrow band emission phosphor dispersed within a binder matrix, wherein the narrow band emission phosphor has a D50 particle size from about 0.1 µm to about 15 µm and is selected from the group consisting of a green-emitting U6+-containing phosphor, a green-emitting Mn2+-containing phosphor, a red-emitting phosphor based on complex fluoride materials activated by Mn4+, and a mixture thereof. A device is also provided.

公开(公告)号：US20230007906A1

公开(公告)日：2023-01-12

申请号：US17783626

申请日：2020-12-09

Applicant: General Electric Company

Inventor： Samuel Joseph Camardello ,  James Edward Murphy

IPC: G02F1/1335 ,  H01L33/50 ,  F21V8/00 ,  G02F1/13357 ,  C09K11/04 ,  C09K11/61 ,  C09K11/77

Abstract: A display including a red subpixel, a green subpixel, a blue subpixel and a fourth subpixel including a teal subpixel or a saturated green pixel and an LED light source. Liquid crystal display devices including U6+-containing phosphors are also provided. Applications for the display include televisions, mobile phones and computer monitors.

公开(公告)号：US11312876B2

公开(公告)日：2022-04-26

申请号：US17152736

申请日：2021-01-19

Applicant: General Electric Company

Inventor： Mark D. Doherty ,  Yangang Liang ,  Jie Jerry Liu ,  Samuel Joseph Camardello ,  James Edward Murphy

IPC: C09K11/71 ,  C09D11/38 ,  G03F7/004 ,  C09K11/02 ,  C09K11/61 ,  G02F1/13357 ,  F21V8/00 ,  F21V9/30 ,  H01L33/50 ,  C09D11/322 ,  C08K3/32 ,  C08K3/34 ,  F21Y115/10

Abstract: An ink composition is provided. The composition includes a binder material and at least one narrow band emission phosphor being uniformly dispersed throughout the composition, wherein the narrow band emission phosphor has a D50 particle size from about 0.1 μm to about 15 μm and is selected from the group consisting of a green-emitting U6+-containing phosphor, a green-emitting Mn2+-containing phosphor, a red-emitting phosphor based on complex fluoride materials activated by Mn4+, and a mixture thereof. A device is also provided.