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公开(公告)号：US09698314B2
公开(公告)日：2017-07-04
申请号：US14208592
申请日：2014-03-13
Applicant: GENERAL ELECTRIC COMPANY
Inventor： James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar
CPC classification number: H01L33/502 , C09K11/616 , C09K2211/181 , C09K2211/188 , H01L33/52 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+ I wherein A is Li, Na, K, Rb, Cs, NR4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
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公开(公告)号：US20140327026A1
公开(公告)日：2014-11-06
申请号：US14311624
申请日：2014-06-23
Applicant: GENERAL ELECTRIC COMPANY
Inventor： James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar
CPC classification number: H01L33/502 , C09K11/616 , C09K2211/181 , C09K2211/188 , H01L33/52 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+ wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
Abstract translation: 用于合成颜色稳定的Mn4 +掺杂荧光体的方法包括在升高的温度下以气态形式将式I的前体与含氟氧化剂接触以形成颜色稳定的Mn4 +掺杂荧光体Ax [MFy]：Mn4 +，其中A为Li ，Na，K，Rb，Cs或其组合; M是Si，Ge，Sn，Ti，Zr，Al，Ga，In，Sc，Hf，Y，La，Nb，Ta，Bi，Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y为5,6或7。
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公开(公告)号：US20170145304A1
公开(公告)日：2017-05-25
申请号：US15402606
申请日：2017-01-10
Applicant: GENERAL ELECTRIC COMPANY
Inventor： James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar , William Winder Beers
CPC classification number: C09K11/617 , C08K3/34 , C09K11/025 , C09K11/616 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A lighting apparatus includes a semiconductor light source in direct contact with a polymer composite comprising a color stable Mn4+ doped phosphor, wherein the lighting apparatus has a color shift of 1.5 MacAdam ellipses after operating for at least 2,000 hour at a LED current density greater than 2 A/cm2, a LED wall-plug efficiency greater than 40%, and a board temperature greater than 25° C.
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Patent Agency Ranking
公开(公告)号：US20140268655A1
公开(公告)日：2014-09-18
申请号：US14285746
申请日：2014-05-23
Applicant: GENERAL ELECTRIC COMPANY
Inventor： James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar
CPC classification number: C09K11/617 , C08K3/34 , C09K11/025 , C09K11/616 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A color stable Mn4+ doped phosphor of formula I, Ax[MFy]:Mn4+ I wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and wherein % intensity loss of the phosphor after exposure to light flux of at least 80 w/cm2 at a temperature of at least 50° C. for at least 21 hours is ≦4%.
Abstract translation: 式I的颜色稳定的Mn4 +掺杂的荧光体，Ax [MFy]：Mn4 + I，其中A是Li，Na，K，Rb，Cs或它们的组合; M是Si，Ge，Sn，Ti，Zr，Al，Ga，In，Sc，Hf，Y，La，Nb，Ta，Bi，Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y为5,6或7; 并且其中在至少80℃的温度下暴露至少80w / cm 2的光通量至少21小时后的荧光粉的强度损失百分比为±4％。
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公开(公告)号：US20140264418A1
公开(公告)日：2014-09-18
申请号：US14208592
申请日：2014-03-13
Applicant: GENERAL ELECTRIC COMPANY
Inventor： James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar
CPC classification number: H01L33/502 , C09K11/616 , C09K2211/181 , C09K2211/188 , H01L33/52 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+ I whereinA is Li, Na, K, Rb, Cs, NR4 or a combination thereof;M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof;R is H, lower alkyl, or a combination thereof;x is the absolute value of the charge of the [MFy] ion; andy is 5, 6 or 7.
Abstract translation: 用于合成颜色稳定的Mn4 +掺杂荧光体的方法包括在高温下以气态形式将式I的前体与含氟氧化剂接触以形成颜色稳定的Mn4 +掺杂荧光体Ax [MFy]：Mn4 + I，其中A为 Li，Na，K，Rb，Cs，NR4或其组合; M是Si，Ge，Sn，Ti，Zr，Al，Ga，In，Sc，Hf，Y，La，Nb，Ta，Bi，Gd或它们的组合; R是H，低级烷基或它们的组合; x是[MFy]离子的电荷的绝对值; y为5,6或7。
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公开(公告)号：US09580648B2
公开(公告)日：2017-02-28
申请号：US14285746
申请日：2014-05-23
Applicant: GENERAL ELECTRIC COMPANY
Inventor： James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar
CPC classification number: C09K11/617 , C08K3/34 , C09K11/025 , C09K11/616 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A color stable Mn4+ doped phosphor of formula I, Ax[MFy]:Mn4+ I wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and wherein % intensity loss of the phosphor after exposure to light flux of at least 80 w/cm2 at a temperature of at least 50° C. for at least 21 hours is ≦4%.
Abstract translation: 式I的颜色稳定的Mn4 +掺杂的荧光体，Ax [MFy]：Mn4 + I，其中A是Li，Na，K，Rb，Cs或它们的组合; M是Si，Ge，Sn，Ti，Zr，Al，Ga，In，Sc，Hf，Y，La，Nb，Ta，Bi，Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y为5,6或7; 并且其中在至少80℃的温度下暴露至少80w / cm 2的光通量至少21小时后的荧光粉的强度损失百分比为±4％。
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公开(公告)号：US10008341B2
公开(公告)日：2018-06-26
申请号：US14571739
申请日：2014-12-16
Applicant: General Electric Company
Inventor： Mohandas Nayak , Nagaveni Karkada , Shalini Thimmegowda , Mallikarjuna Heggadadevanapura Thammaiah , Janakiraman Narayanan , Linda Yvonne Jacobs
IPC: H01H1/02 , H01H1/021 , H01H1/025 , H01H11/04 , B22F3/04 , B22F3/105 , B22F3/14 , B22F3/16 , B22F7/06 , C22C32/00 , H01H1/0233 , H01H1/0237 , B22F3/12 , B22F5/00
CPC classification number: H01H1/021 , B22F3/04 , B22F3/105 , B22F3/12 , B22F3/14 , B22F3/16 , B22F5/00 , B22F7/06 , B22F2999/00 , C22C32/0021 , C22C32/0047 , C22C32/0084 , H01H1/0233 , H01H1/0237 , H01H1/025 , H01H11/048 , B22F3/10 , B22F2201/013 , B22F2201/02 , B22F2207/01
Abstract: A circuit breaker having a monolithic structure and method of making is disclosed. The monolithic structure includes an arm portion having copper and a contact portion having a composite material. The composite material has a metallic matrix and a second phase disposed in the metallic matrix. The method of making the monolithic structure includes introducing a first powder into a first region of a mold, introducing a second powder into a second region of the mold, and consolidating the first powder and the second powder together. The first region of the mold corresponds to a contact portion, and the second region corresponds to an arm portion of the monolithic structure of the circuit breaker.
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公开(公告)号：US08906724B2
公开(公告)日：2014-12-09
申请号：US14311624
申请日：2014-06-23
Applicant: General Electric Company
Inventor： James Edward Murphy , Anant Achyut Setlur , Florencio Garcia , Robert Joseph Lyons , Ashfaqul Islam Chowdhury , Nagaveni Karkada , Prasanth Kumar Nammalwar
CPC classification number: H01L33/502 , C09K11/616 , C09K2211/181 , C09K2211/188 , H01L33/52 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+ I wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
Abstract translation: 用于合成颜色稳定的Mn4 +掺杂荧光体的方法包括在高温下以气态形式将式I的前体与含氟氧化剂接触以形成颜色稳定的Mn4 +掺杂荧光体Ax [MFy]：Mn4 + I，其中A为 Li，Na，K，Rb，Cs或其组合; M是Si，Ge，Sn，Ti，Zr，Al，Ga，In，Sc，Hf，Y，La，Nb，Ta，Bi，Gd或它们的组合; x是[MFy]离子的电荷的绝对值; y为5,6或7。
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