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    SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION
    31.
    发明申请
    SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION 有权
    用于烯烃聚合的固体催化剂组分和催化剂

    公开(公告)号：US20130324682A1

    公开(公告)日：2013-12-05

    申请号：US13980359

    申请日：2012-01-19

    Applicant: Zhong TAN ,  Lunjia Xie ,  Xiudong Xu ,  Yu Tian ,  Qilong Zhou ,  Zaixing Feng ,  Li'an Yan ,  Siyuan Zhao ,  Jinhua Yu ,  Zhufang Sun ,  Fengkui Li ,  Shanshan Yin ,  Weiwei Song

    Inventor： Zhong TAN ,  Lunjia Xie ,  Xiudong Xu ,  Yu Tian ,  Qilong Zhou ,  Zaixing Feng ,  Li'an Yan ,  Siyuan Zhao ,  Jinhua Yu ,  Zhufang Sun ,  Fengkui Li ,  Shanshan Yin ,  Weiwei Song

    IPC: C08F110/06

    CPC classification number: C08F110/06 ,  C08F10/06 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6548

    Abstract: Disclosed is a solid catalyst component for olefin polymerization. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. Said internal electron donor compound comprises a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I: as in formula I, R1 and R2 radicals are independently chosen from linear or branched C1-C4 alkyl groups; R is chosen from C3-C6 iso-alkyl, sec-alkyl, or cycloalkyl groups. Also disclosed is another solid catalyst component. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. In addition to a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I, the internal electron donor compound can also comprise 2-isopropyl-2-(3-methylbutyl)-1,3-dimethoxy propane and/or a carboxylic ester compound. Also disclosed is a catalyst containing the solid catalyst component. The catalyst is used for olefin polymerization, particularly propylene polymerization, and is relatively active during polymerization. The obtained polymer has the advantages of wide molecular weight distribution, high molecular bulk density, good hydrogen regulation sensitivity, good stereospecificity, good particle shape, and small fine powder content.

    Abstract translation: 公开了用于烯烃聚合的固体催化剂组分。 催化剂组分包括二烷氧基镁载体，钛化合物和在惰性溶剂中反应的内电子给体的产物。 所述内电子给体化合物包含式I所示的2,3-二 - 非线性 - 烷基-2-氰基琥珀酸二酯化合物：如式I所示，R 1和R 2基团独立地选自直链或支链C1- C4烷基; R选自C 3 -C 6异烷基，仲烷基或环烷基。 还公开了另一种固体催化剂组分。 催化剂组分包括二烷氧基镁载体，钛化合物和在惰性溶剂中反应的内电子给体的产物。 除了式I所示的2,3-二 - 非线性 - 烷基-2-氰基琥珀酸二酯化合物之外，内电子给体化合物还可以包含2-异丙基-2-（3-甲基丁基）-1 ，3-二甲氧基丙烷和/或羧酸酯化合物。 还公开了含有固体催化剂组分的催化剂。 该催化剂用于烯烃聚合，特别是丙烯聚合，并且在聚合期间相对有活性。 得到的聚合物具有分子量分布宽，分子体积密度高，调节灵敏度好，立体定向性好，粒子形状好，细粉含量低的优点。

    Compatibilized Polypropylene and Polylactic Acid Blends and Methods of Making and Using Same
    39.
    发明申请
    Compatibilized Polypropylene and Polylactic Acid Blends and Methods of Making and Using Same 有权
    增容的聚丙烯和聚乳酸混合物及其制备和使用方法

    公开(公告)号：US20120080822A1

    公开(公告)日：2012-04-05

    申请号：US13314382

    申请日：2011-12-08

    Applicant: Fengkui Li ,  Tim J. Coffy ,  Michel Daumerie

    Inventor： Fengkui Li ,  Tim J. Coffy ,  Michel Daumerie

    IPC: B29C45/46 ,  C08F255/02

    CPC classification number: C08L23/12 ,  B29C45/0001 ,  B29C47/0004 ,  B29C49/0005 ,  B29C51/002 ,  C08L23/0884 ,  C08L23/10 ,  C08L33/068 ,  C08L51/06 ,  C08L67/04 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2666/02

    Abstract: A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %.

    Abstract translation: 包含聚烯烃，聚乳酸和反应性改性剂的共混物的组合物。 一种制备定向膜的方法，其包括将包含聚丙烯，聚乳酸，反应性改性剂的混合物的反应性挤出混合以形成相容的聚合物共混物，将相容的聚合物共混物浇铸成膜，以及使膜定向。 一种制备反应性改性剂的方法，包括在适于形成环氧官能化聚烯烃的条件下使聚烯烃，多官能丙烯酸酯共聚单体和引发剂接触，其中环氧官能化聚烯烃的接枝收率为0.2wt。 ％至15wt。 ％。

    Long chain branched polypropylene for cast film applications
    40.
    发明申请
    Long chain branched polypropylene for cast film applications 审中-公开
    用于流延膜应用的长链支化聚丙烯

    公开(公告)号：US20100087602A1

    公开(公告)日：2010-04-08

    申请号：US12247756

    申请日：2008-10-08

    Applicant: Fengkui Li ,  Ryan L. Albores ,  John Bieser

    Inventor： Fengkui Li ,  Ryan L. Albores ,  John Bieser

    IPC: C08F10/06 ,  B29C47/36 ,  B29C47/78

    Abstract: A method comprising contacting a polypropylene, an acrylate-containing compound, and an initiator to form a composition, and reactive extruding the composition to form a polymer blend. A method comprising contacting a polypropylene, a multi-functional acrylate monomer, and an initiator to form a composition, reactive extruding the composition to form a reactive extruded composition, and forming the reactive extruded composition into a film wherein the reactive extruded composition has a melt flow rate that is reduced by equal to or greater than 5% when compared to neat polypropylene.

    Abstract translation: 一种方法，包括使聚丙烯，含丙烯酸酯的化合物和引发剂接触以形成组合物，并且反应性挤出所述组合物以形成聚合物共混物。 一种方法，包括使聚丙烯，多官能丙烯酸酯单体和引发剂接触以形成组合物，反应性挤出组合物以形成反应性挤出组合物，以及将反应性挤出组合物形成为膜，其中反应性挤出组合物具有熔体 与纯聚丙烯相比，流速降低5％以上。

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