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公开(公告)号：US20120029257A1
公开(公告)日：2012-02-02
申请号：US12845618
申请日：2010-07-28
IPC分类号： C07C5/00
摘要： A reforming process using a medium pore zeolite under conditions to facilitate the conversion of C8 paraffinic compounds to para-xylene is provided. Para-xylene is produced at greater than thermodynamic equilibrium concentrations using the process.
摘要翻译： 提供了在促进C8链烷烃化合物转化为对二甲苯的条件下使用中孔沸石的重整方法。 使用该方法在大于热力学平衡浓度下产生对二甲苯。
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32.发明申请公开(公告)号：US20120024754A1
公开(公告)日：2012-02-02
申请号：US12845617
申请日：2010-07-28
IPC分类号： C10G59/02
CPC分类号： C10G35/04 , C10G35/065 , C10G35/085 , C10G35/09 , C10G35/095 , C10G59/02 , C10G2300/1044 , C10G2300/305 , C10G2400/02
摘要： The present invention relates to a multistage reforming process to produce a high octane product. A naphtha boiling range feedstock is processed in a multi-stage reforming process, in which said process involves at least 1) a penultimate stage for reforming the naphtha feedstock to produce a penultimate effluent 2) a final stage for further reforming at least a portion of the penultimate effluent 3) a regeneration step for the final stage catalyst. The severity of the penultimate stage can be increased during final stage catalyst regeneration in order to maintain the target RON of the reformate product and avoid reactor downtime.
摘要翻译： 本发明涉及一种生产高辛烷值产品的多级重整方法。 石脑油沸程原料在多级重整过程中进行处理，其中所述方法涉及至少1）用于重整石脑油原料以产生倒数第二流出物的倒数第二级2）用于进一步重整至少一部分 倒数第二流出物3）最终阶段催化剂的再生步骤。 为了维持重整产物的目标RON，避免反应堆停机，可以在终催化剂再生期间增加倒数第二阶段的严重性。
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公开(公告)号：US20120024753A1
公开(公告)日：2012-02-02
申请号：US12845615
申请日：2010-07-28
IPC分类号： C10G35/085 , C10G35/06
CPC分类号： C10G59/02 , C10G35/085 , C10G35/09 , C10G35/24 , C10G2300/1044 , C10G2300/305 , C10G2300/4006 , C10G2300/4012 , C10G2400/02
摘要： The present invention relates to a multistage reforming process to produce a high octane product. A naphtha boiling range feedstock is processed in a multi-stage reforming process, in which said process involves at least 1) a penultimate stage for reforming the naphtha feedstock to produce a penultimate effluent 2) a final stage for further reforming at least a portion of the penultimate effluent 3) a regeneration step for the final stage catalyst. The severity of the penultimate stage can be increased during final stage catalyst regeneration in order to maintain the target RON of the reformate product and avoid reactor downtime.
摘要翻译： 本发明涉及一种生产高辛烷值产品的多级重整方法。 石脑油沸程原料在多级重整过程中进行处理，其中所述方法涉及至少1）用于重整石脑油原料以产生倒数第二流出物的倒数第二级2）用于进一步重整至少一部分 倒数第二流出物3）最终阶段催化剂的再生步骤。 为了维持重整产物的目标RON，避免反应堆停机，可以在终催化剂再生期间增加倒数第二阶段的严重性。
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34.发明申请公开(公告)号：US20100160700A1
公开(公告)日：2010-06-24
申请号：US12338436
申请日：2008-12-18
IPC分类号： C07C2/00
摘要： Improved processes and catalysts are described for the conversion of oxygenate-containing olefinic Fischer Tropsch naphtha into aromatics. This involves removal of the oxygenates without complete saturation of the olefins followed by aromatization of the oxygenate-depleted olefinic naphtha preferably over a catalyst that is tolerant to oxygenates.
摘要翻译： 描述了改进的方法和催化剂用于将含氧化合物的烯属费 - 托石脑油转化成芳族化合物。 这涉及去除含氧化合物而不完全饱和烯烃，然后优选在含氧化合物的烯烃石脑油的芳构化的范围内对耐受含氧化合物的催化剂进行芳族化。
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公开(公告)号：US20090301934A1
公开(公告)日：2009-12-10
申请号：US12134153
申请日：2008-06-05
IPC分类号： C10G35/06
CPC分类号： C10G59/02 , C10G35/09 , C10G35/095
摘要： The present invention relates to a multistage reforming process to produce a high octane product. A naphtha boiling range feedstock is processed in a multi-stage reforming process, in which said process involves at least 1) a penultimate stage for reforming the naphtha feedstock to produce a penultimate effluent 2) a separation step for separating the penultimate effluent into at least an intermediate stream and a heavy stream based on boiling point and 3) a final stage for further reforming the intermediate stream.
摘要翻译： 本发明涉及一种生产高辛烷值产品的多级重整方法。 石脑油沸程原料在多级重整过程中进行处理，其中所述方法至少包括1）用于重整石脑油原料以产生倒数第二流出物的倒数第二级2）用于将倒数第二流出物分离成至少 中间物流和基于沸点的重流，以及3）用于进一步重整中间物流的最后阶段。
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公开(公告)号：US20090301933A1
公开(公告)日：2009-12-10
申请号：US12134131
申请日：2008-06-05
IPC分类号： C10G59/02
CPC分类号： C10G59/02 , C10G35/095
摘要： The present invention is a multistage reforming process to produce high octane product from naphtha boiling range feed. In the process, a effluent product from a penultimate reforming stage is separated into at least a first stream and a second stream by boiling point. The lower boiling of the two streams is further reformed in a final reforming stage over a medium pore molecular sieve catalyst.
摘要翻译： 本发明是从石脑油沸程进料产生高辛烷值的多级重整方法。 在此过程中，来自倒数第二个重整阶段的流出物被分离成至少第一流和第二流通过沸点。 在中孔分子筛催化剂的最终重整阶段，两股料流的较低沸点进一步重整。
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37.发明授权Recovery of alcohols from Fischer-Tropsch naphtha and distillate fuels containing the same 有权从费 - 托石脑油回收醇和含有它的馏出燃料公开(公告)号：US07402187B2
公开(公告)日：2008-07-22
申请号：US10267406
申请日：2002-10-09
IPC分类号： C10L1/18
CPC分类号： C10L10/08 , C07C29/10 , C10L1/026 , C10L1/1824 , C07C31/12 , C07C31/125
摘要： Olefins and alcohols present in Fischer-Tropsch products are converted to primary and secondary alkyl alcohols having at least four carbons through acid catalyzed etherification and hydrolysis reactions. The alcohols are added to a highly isoparaffinic distillate fuel blend, improving the lubricity of the mixture, and forming a distillate fuel with improved lubricity.
摘要翻译： 在费 - 托产品中存在的烯烃和醇通过酸催化醚化和水解反应转化成具有至少四个碳的伯和仲烷基醇。 将醇加入到高度异链烷烃馏出物燃料混合物中，改善混合物的润滑性，并形成具有改善的润滑性的馏出燃料。
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公开(公告)号：US07238337B2
公开(公告)日：2007-07-03
申请号：US11264197
申请日：2005-10-31
申请人： Cong-Yan Chen
发明人： Cong-Yan Chen
IPC分类号： C01B37/02
CPC分类号： C01B37/02
摘要： An all-silica zeolite having the IFR framework topology can be directly synthesized by preparing a reaction mixture comprising (1) an active source of silicon oxide, (2) a structure directing agent comprising a N-benzyl-1,4-diazabicyclo[2.2.2] octane cation, (3) an active source of hydroxide and (4) water and maintaining the reaction mixture under conditions sufficient to form crystals of the zeolite.
摘要翻译： 具有IFR骨架拓扑结构的全硅沸石可以通过制备包含（1）氧化硅活性源的反应混合物，（2）包含N-苄基-1,4-二氮杂双环[2.2 .2]辛烷阳离子，（3）氢氧化物的活性源和（4）水，并在足以形成沸石晶体的条件下保持反应混合物。
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39.发明授权Methods to improve heteroatom lattice substitution in large and extra-large pore borosilicate zeolites 有权改进大孔径和超大孔隙硼硅酸盐沸石中杂原子晶格取代的方法公开(公告)号：US06790433B2
公开(公告)日：2004-09-14
申请号：US10274249
申请日：2002-10-18
申请人： Cong-Yan Chen , Stacey I. Zones
发明人： Cong-Yan Chen , Stacey I. Zones
IPC分类号： C01B3906
CPC分类号： B01J29/86 , C01B39/026
摘要： The invention, in one embodiment, is a method for preparing crystalline zeolites by (a) contacting a calcined essentially aluminum free borosilicate zeolite with an aqueous acid solution, thereby producing an at least partially deboronated zeolite; (b) contacting said at least partially deboronated zeolite with a solution selected from the group consisting of an aqueous aluminum salt solution, thereby producing an aluminosilicate zeolite; an aqueous gallium salt solution, thereby producing a gallosilicate zeolite; an aqueous iron salt solution, thereby producing a ferrosilicate zeolite; and mixtures thereof; and (c) where the contacting in step (b) occurs at a pH of not greater than about 3.5. In another embodiment, the present invention provides a method for preparing crystalline zeolites by contacting a calcined essentially aluminum free large or extra-large pore borosilicate zeolite with a solution selected from the group consisting of an aqueous aluminum salt solution, thereby producing an aluminosilicate zeolite; an aqueous gallium salt solution, thereby producing a gallosilicate zeolite; an aqueous iron salt solution, thereby producing a ferrosilicate zeolite; and mixtures thereof; and where the contacting occurs at a pH of not greater than about 3.5.
摘要翻译： 在一个实施方案中，本发明是通过（a）使煅烧的基本上不含铝的硼硅酸盐沸石与酸水溶液接触来制备结晶沸石的方法，从而产生至少部分脱硼的沸石; （b）使所述至少部分脱硼的沸石与选自铝盐水溶液的溶液接触，从而制备铝硅酸盐沸石; 一种镓盐水溶液，从而生产硅酸镓沸石; 一种铁盐水溶液，从而生产一种硅酸铝沸石; 及其混合物; 和（c）步骤（b）中的接触在不大于约3.5的pH下发生。 在另一个实施方案中，本发明提供了一种制备结晶沸石的方法，该方法通过将煅烧的基本上不含铝的大或超大孔硼硅酸盐沸石与选自铝盐水溶液的溶液接触，由此生产硅铝酸盐沸石; 一种镓盐水溶液，从而生产硅酸镓沸石; 一种铁盐水溶液，从而生产一种硅酸铝沸石; 及其混合物; 并且其中接触在不大于约3.5的pH下进行。
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公开(公告)号：US06566569B1
公开(公告)日：2003-05-20
申请号：US09603489
申请日：2000-06-23
IPC分类号： C07C500
CPC分类号： B01J23/6527 , B01J35/0006 , C10G45/58 , C10G59/00 , Y02P20/582
摘要： A process for preparing a C4- product stream and a C6+ product stream is disclosed. The process involves contacting a C5 containing paraffinic feedstock with a catalyst that includes a hydrogenation/dehydrogenation catalyst and an olefin metathesis catalyst under conditions which dehydrogenate the paraffins to olefins. The olefins are then metathesized and rehydrogenated to provide a product stream. A C4- fraction and a C6+ fraction can each be isolated from the product stream. The C4- fraction can be used, for example, in an alkylation reaction to provide compounds useful in gasoline compositions. Unconverted C5 paraffins can be recycled. The C6+ fraction can be used, for example, as solvents. Alternatively, they can be isomerized to form gasoline additives, or can be converted to aromatic compounds via reforming, for example, using conventional reforming techniques, preferably using the AROMAX™ process or traditional rheniforming conditions.
摘要翻译： 公开了一种制备C4-产物流和C6 +产物流的方法。 该方法包括使含有C5的石蜡原料与包含氢化/脱氢催化剂和烯烃复分解催化剂的催化剂在使链烷烃脱氢成烯烃的条件下接触。 然后将烯烃进行复合和再氢化以提供产物流。 可以从产物流中分离出C4馏分和C6 +馏分。 C4馏分可用于例如烷基化反应以提供可用于汽油组合物中的化合物。 未转化的C5石蜡可以回收利用。 C6 +馏分可以用作例如溶剂。 或者，它们可以被异构化以形成汽油添加剂，或者可以通过重整转化为芳族化合物，例如使用常规的重整技术，优选使用AROMAX TM方法或传统的强化条件。
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