公开(公告)号：US20190016632A1

公开(公告)日：2019-01-17

申请号：US16117639

申请日：2018-08-30

Applicant: CORNING INCORPORATED

Inventor： Guangli Hu ,  Charlene Marie Smith ,  Steven Alvin Tietje

IPC: C03C21/00 ,  C03C23/00 ,  C03C10/00 ,  C03C3/091 ,  C03C3/093 ,  C03C3/097

CPC classification number: C03C21/002 ,  C03C3/091 ,  C03C3/093 ,  C03C3/097 ,  C03C10/00 ,  C03C10/0027 ,  C03C23/007

Abstract: Embodiments of a glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than 0.7·t, comprise a tangent that is less than about −0.1 MPa/micrometers or greater than about 0.1 MPa/micrometers, are disclosed. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t). In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a point between the first surface and the second surface and increases from the point to the second surface. The concentration of the metal oxide may be about 0.05 mol % or greater or about 0.5 mol % or greater throughout the thickness. Methods for forming such glass-based articles are also disclosed.

公开(公告)号：US09908811B2

公开(公告)日：2018-03-06

申请号：US15682735

申请日：2017-08-22

Applicant: Corning Incorporated

Inventor： Timothy Michael Gross ,  Guangli Hu ,  Rostislav Vatchev Roussev ,  Charlene Marie Smith ,  Zhongzhi Tang ,  Steven Alvin Tietje

IPC: C03C21/00 ,  C03C23/00 ,  C03C4/18 ,  C03C3/093 ,  C03C3/097

CPC classification number: C03C21/002 ,  C03C3/093 ,  C03C3/097 ,  C03C4/18 ,  C03C23/007 ,  C03C2204/00

Abstract: A glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than about 0.7·t to t, comprise a tangent with a slope having an absolute value greater than about 0.1 MPa/micrometer. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t) and a maximum central tension of less than about 71.5/√(t) (MPa). In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a point between the first surface and the second surface and increases from the point to the second surface. The concentration of the metal oxide may be about 0.05 mol % or greater or about 0.5 mol % or greater throughout the thickness. Methods for forming such glass-based articles are also disclosed.

公开(公告)号：US20170369361A1

公开(公告)日：2017-12-28

申请号：US15702010

申请日：2017-09-12

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Matthew John Dejneka ,  Sinue Gomez ,  Charlene Marie Smith ,  Steven Alvin Tietje

IPC: C03C14/00 ,  C03C21/00 ,  C03C10/00 ,  C03B32/02 ,  C03C3/097 ,  C03C3/093 ,  C03C3/085 ,  C03C4/02 ,  C03B20/00

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C3/097 ,  C03C4/02 ,  C03C10/0027 ,  C03C10/0045 ,  C03C10/0054 ,  C03C21/002 ,  C03C2204/04

Abstract: Disclosed herein are glass-ceramics having crystalline phases including β-spodumene ss and either (i) pseudobrookite or (ii) vanadium or vanadium containing compounds so as to be colored and opaque glass-ceramics having coordinates, determined from total reflectance—specular included—measurements, in the CIELAB color space of the following ranges: L*=from about 20 to about 45; a*=from about −2 to about +2; and b*=from about −12 to about +1. Such CIELAB color space coordinates can be substantially uniform throughout the glass-ceramics. In each of the proceeding, β-quartz ss can be substantially absent from the crystalline phases. If present, β-quartz ss can be less than about 20 wt % or, alternatively, less than about 15 wt % of the crystalline phases. Also Further crystalline phases might include spinel ss (e.g., hercynite and/or gahnite-hercynite ss), rutile, magnesium zinc phosphate, or spinel ss (e.g., hercynite and/or gahnite-hercynite ss) and rutile.

公开(公告)号：US09828282B2

公开(公告)日：2017-11-28

申请号：US15142654

申请日：2016-04-29

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Charlene Marie Smith ,  Steven Alvin Tietje

IPC: C03C10/10 ,  C03C10/00 ,  C03C4/18 ,  C03B32/02 ,  C03C21/00 ,  C03C3/062 ,  C03C3/064 ,  C03C3/097

CPC classification number: C03C10/0018 ,  C03B32/02 ,  C03C3/062 ,  C03C3/064 ,  C03C3/097 ,  C03C4/18 ,  C03C21/00 ,  C03C21/002 ,  C03C2204/00

Abstract: Embodiments of glass ceramic articles and precursor glasses are disclosed. In one or more embodiments, the glass-ceramic articles are transparent and include a nepheline phase and a phosphate phase. The glass-ceramic articles are colorless and exhibit a transmittance of about 70% or greater across the visible spectrum. The glass-ceramic articles may optionally include a lithium aluminosilicate phase. The crystals of the glass-ceramic articles may have a major cross-section of about 100 nm or less.

公开(公告)号：US09790125B2

公开(公告)日：2017-10-17

申请号：US14801278

申请日：2015-07-16

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Matthew John Dejneka ,  Sinue Gomez ,  Charlene Marie Smith ,  Steven Alvin Tietje

IPC: C03C10/12 ,  C03C3/085 ,  C03C14/00 ,  C03B32/02 ,  C03C3/093 ,  C03C3/097 ,  C03C4/02 ,  C03C10/00 ,  C03C21/00 ,  C03B20/00

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C3/097 ,  C03C4/02 ,  C03C10/0027 ,  C03C10/0045 ,  C03C10/0054 ,  C03C21/002 ,  C03C2204/04

Abstract: Disclosed herein are glass-ceramics having crystalline phases including β-spodumene ss and either (i) pseudobrookite or (ii) vanadium or vanadium containing compounds so as to be colored and opaque glass-ceramics having coordinates, determined from total reflectance—specular included—measurements, in the CIELAB color space of the following ranges: L*=from about 20 to about 45; a*=from about −2 to about +2; and b*=from about −12 to about +1. Such CIELAB color space coordinates can be substantially uniform throughout the glass-ceramics. In each of the proceeding, β-quartz ss can be substantially absent from the crystalline phases. If present, β-quartz ss can be less than about 20 wt % or, alternatively, less than about 15 wt % of the crystalline phases. Also Further crystalline phases might include spinel ss (e.g., hercynite and/or gahnite-hercynite ss), rutile, magnesium zinc phosphate, or spinel ss (e.g., hercynite and/or gahnite-hercynite ss) and rutile.

公开(公告)号：US20160368818A1

公开(公告)日：2016-12-22

申请号：US15253080

申请日：2016-08-31

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Nicholas Francis Borrelli ,  Charlene Marie Smith ,  Steven Alvin Tietje

IPC: C03C21/00 ,  C03B17/06 ,  C03C10/00

CPC classification number: C03C21/002 ,  C03B17/064 ,  C03C10/0018 ,  C03C10/0027 ,  C03C10/0045 ,  C03C10/0054 ,  C03C2204/00 ,  C03C2204/04 ,  Y10T428/315

Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (β-spodumene and/or β-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.

Abstract translation: 本公开涉及组合物位于SiO 2 -R 2 O 3 -Li 2 O / Na 2 O-TiO 2体系内并且含有由硅铝酸锂（β-锂辉石和/或β-石英固体）组成的硅酸盐结晶相的可熔融成形高结晶玻璃陶瓷制品 溶液）偏硅酸锂和/或二硅酸锂。 此外，这些含硅酸盐晶体的玻璃陶瓷可以表现出从玻璃制品的表面延伸到本体的Na 2 O与Li 2 O的摩尔比变化，特别是从表面到体积的降低的Li 2 O浓度和增加的Na 2 O浓度。 根据第二实施方案，本文公开了一种形成含硅酸盐结晶相的玻璃陶瓷的方法。

公开(公告)号：US09440877B2

公开(公告)日：2016-09-13

申请号：US14522178

申请日：2014-10-23

Applicant: Corning Incorporated

Inventor： George Halsey Beall ,  Nicholas Francis Borrelli ,  Charlene Marie Smith ,  Steven Alvin Tietje

IPC: C03C10/04 ,  C03C10/12 ,  C03B27/03 ,  C03C10/00 ,  C03C21/00

CPC classification number: C03C21/002 ,  C03B17/064 ,  C03C10/0018 ,  C03C10/0027 ,  C03C10/0045 ,  C03C10/0054 ,  C03C2204/00 ,  C03C2204/04 ,  Y10T428/315

Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (β-spodumene and/or β-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.

Abstract translation: 本公开涉及组合物位于SiO 2 -R 2 O 3 -Li 2 O / Na 2 O-TiO 2体系内并且含有由硅铝酸锂（β-锂辉石和/或β-石英固体）组成的硅酸盐结晶相的可熔融成形高结晶玻璃陶瓷制品 溶液）偏硅酸锂和/或二硅酸锂。 此外，这些含硅酸盐晶体的玻璃陶瓷可以表现出从玻璃制品的表面延伸到本体的Na 2 O与Li 2 O的摩尔比变化，特别是从表面到体积的降低的Li 2 O浓度和增加的Na 2 O浓度。 根据第二实施方案，本文公开了一种形成含硅酸盐结晶相的玻璃陶瓷的方法。

公开(公告)号：US09115023B2

公开(公告)日：2015-08-25

申请号：US13973195

申请日：2013-08-22

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Matthew John Dejneka ,  Sinue Gomez ,  Charlene Marie Smith ,  Steven Alvin Tietje

IPC: C03C10/02 ,  C03C10/12 ,  C03C14/00 ,  C03C3/085 ,  C03C3/093 ,  C03C3/097 ,  C03C4/02 ,  C03C10/00 ,  C03C21/00 ,  C03B20/00

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C3/097 ,  C03C4/02 ,  C03C10/0027 ,  C03C10/0045 ,  C03C10/0054 ,  C03C21/002 ,  C03C2204/04

Abstract: Disclosed herein are glass-ceramics having crystalline phases including β-spodumene ss and either (i) pseudobrookite or (ii) vanadium or vanadium containing compounds so as to be colored and opaque glass-ceramics having coordinates, determined from total reflectance—specular included—measurements, in the CIELAB color space of the following ranges: L*=from about 20 to about 45; a*=from about −2 to about +2; and b*=from about −12 to about +1. Such CIELAB color space coordinates can be substantially uniform throughout the glass-ceramics. In each of the proceeding, β-quartz ss can be substantially absent from the crystalline phases. If present, β-quartz ss can be less than about 20 wt % or, alternatively, less than about 15 wt % of the crystalline phases. Also Further crystalline phases might include spinel ss (e.g., hercynite and/or gahnite-hercynite ss), rutile, magnesium zinc phosphate, or spinel ss (e.g., hercynite and/or gahnite-hercynite ss) and rutile.

Abstract translation: 本文公开了具有结晶相的玻璃 - 陶瓷，其包含＆bod-锂辉石ss和（i）假性质铁矿或（ii）含钒或钒的化合物，以使其为具有坐标的着色和不透明玻璃陶瓷，所述玻璃陶瓷由总反射率镜面确定 - 测量，CIELAB颜色空间中的以下范围：L * =约20至约45; a * =约-2至约+2; 而b * =约-12至约+1。 这样的CIELAB颜色空间坐标在整个玻璃陶瓷中可以是基本均匀的。 在每个步骤中，晶体相可以基本上不存在。 如果存在，＆bgr; - 石英β可以小于结晶相的约20重量％，或者小于约15重量％。 另外的结晶相可以包括尖晶石ss（例如，hercynite和/或gahnite-hercynite ss），金红石，磷酸镁锌或尖晶石ss（例如hercynite和/或gahnite-hercynite ss）和金红石。

公开(公告)号：US20130296155A1

公开(公告)日：2013-11-07

申请号：US13933600

申请日：2013-07-02

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Marie Jacqueline Monique Comte ,  George Owen Dale ,  Linda Ruth Pinckney ,  Charlene Marie Smith ,  Ronald Leroy Stewart ,  Steven Alvin Tietje

IPC: C03C14/00 ,  C03B32/02

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C10/0009 ,  C03C10/0027 ,  C03C14/00 ,  C03C21/002 ,  Y10T428/315

Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit β-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2  O + Na 2  O + K 2  O + MgO + ZnO _ ]  [ Al 2  O 3 + B 2  O 3 ] between 0.7 to 1.5; b. a ratio: [ TiO 2 + SnO 2 _ ]  [ SiO 2 + B 2  O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity≧about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.

Abstract translation: 公开了可结晶玻璃，玻璃陶瓷，IXable玻璃陶瓷和IX玻璃陶瓷。 玻璃陶瓷显示出β-锂辉石为主要结晶相。 这些玻璃和玻璃陶瓷（摩尔％）包括：62-75SiO 2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; 和0.05-0.2 SnO2。 另外，这些玻璃和玻璃陶瓷具有以下标准：a。 的比例：0.7〜1.5的[Li 2 O + Na 2 O + K 2 O + MgO + ZnO]] [Al 2 O 3 + B 2 O 3] b。 比例：[TiO 2 + SnO 2]] [SiO 2 + B 2 O 3]大于0.04。 此外，玻璃陶瓷在400-700nm的波长范围内表现出大约85％的不透明度，约0.8mm厚度，并且观察角度为10°，CIE光源F02由包含a * 在-3和+3之间，b *在-6和+6之间，L *在88和97之间。

公开(公告)号：US20130274085A1

公开(公告)日：2013-10-17

申请号：US13837863

申请日：2013-03-15

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Marie Jacqueline Monique Comte ,  George Owen Dale ,  Linda Ruth Pinckney ,  Charlene Marie Smith ,  Ronald Leroy Stewart ,  Steven Alvin Tietje

IPC: C03C14/00 ,  C03C10/00

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C10/0009 ,  C03C10/0027 ,  C03C14/00 ,  C03C21/002 ,  Y10T428/315

Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit β-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2  O + Na 2  O + K 2  O + MgO + ZnO ] [ Al 2  O 3 + B 2  O 3 ]  between 0.7 to 1.5; b. a ratio: [ TiO 2 + SnO 2 ] [ SiO 2 + B 2  O 3 ]  greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ≧about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.

Abstract translation: 公开了可结晶玻璃，玻璃陶瓷，IXable玻璃陶瓷和IX玻璃陶瓷。 玻璃陶瓷显示出β-锂辉石为主要结晶相。 这些玻璃和玻璃陶瓷（摩尔％）包括：62-75SiO 2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; 和0.05-0.2 SnO2。 另外，这些玻璃和玻璃陶瓷具有以下标准：a。 比例：0.7〜1.5的[Li 2 O + Na 2 O + K 2 O + MgO + ZnO] [Al 2 O 3 + B 2 O 3] b。 比例：[TiO 2 + SnO 2] [SiO 2 + B 2 O 3]大于0.04。 此外，玻璃陶瓷在400-700nm的波长范围内表现出大约85％的不透明度，约0.8mm厚度，并且观察角度为10°，CIE光源F02由包含a * 在-3和+3之间，b *在-6和+6之间，L *在88和97之间。