公开(公告)号：US20150274581A1

公开(公告)日：2015-10-01

申请号：US14474708

申请日：2014-09-02

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Qiang Fu ,  Lisa Anne Moore ,  Linda Ruth Pinckney ,  Charlene Marie Smith

IPC: C03C10/00

CPC classification number: C03C10/0027 ,  C03C3/093 ,  C03C3/097 ,  C03C10/0054 ,  C03C21/002 ,  C03C2204/00

Abstract: Glass and glass ceramic compositions having a combination of lithium disilicate and -spodumene crystalline phases along with methods of making the glass and glass ceramic compositions are described. The compositions are compatible with conventional rolling and float processes and have high mechanical strength and fracture resistance. Further, the compositions are able to be chemically tempered to even higher strength glass ceramics that are useful as large substrates in multiple applications.

Abstract translation: 描述了具有二硅酸锂和锂辉石结晶相的组合的玻璃和玻璃陶瓷组合物以及制备玻璃和玻璃陶瓷组合物的方法。 该组合物与常规的滚压和浮法相容，具有高的机械强度和耐断裂性。 此外，组合物能够在多种应用中用作大基材的甚至更高强度的玻璃陶瓷进行化学回火。

公开(公告)号：US20130296155A1

公开(公告)日：2013-11-07

申请号：US13933600

申请日：2013-07-02

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Marie Jacqueline Monique Comte ,  George Owen Dale ,  Linda Ruth Pinckney ,  Charlene Marie Smith ,  Ronald Leroy Stewart ,  Steven Alvin Tietje

IPC: C03C14/00 ,  C03B32/02

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C10/0009 ,  C03C10/0027 ,  C03C14/00 ,  C03C21/002 ,  Y10T428/315

Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit β-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2  O + Na 2  O + K 2  O + MgO + ZnO _ ]  [ Al 2  O 3 + B 2  O 3 ] between 0.7 to 1.5; b. a ratio: [ TiO 2 + SnO 2 _ ]  [ SiO 2 + B 2  O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity≧about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.

Abstract translation: 公开了可结晶玻璃，玻璃陶瓷，IXable玻璃陶瓷和IX玻璃陶瓷。 玻璃陶瓷显示出β-锂辉石为主要结晶相。 这些玻璃和玻璃陶瓷（摩尔％）包括：62-75SiO 2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; 和0.05-0.2 SnO2。 另外，这些玻璃和玻璃陶瓷具有以下标准：a。 的比例：0.7〜1.5的[Li 2 O + Na 2 O + K 2 O + MgO + ZnO]] [Al 2 O 3 + B 2 O 3] b。 比例：[TiO 2 + SnO 2]] [SiO 2 + B 2 O 3]大于0.04。 此外，玻璃陶瓷在400-700nm的波长范围内表现出大约85％的不透明度，约0.8mm厚度，并且观察角度为10°，CIE光源F02由包含a * 在-3和+3之间，b *在-6和+6之间，L *在88和97之间。

公开(公告)号：US20130274085A1

公开(公告)日：2013-10-17

申请号：US13837863

申请日：2013-03-15

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Marie Jacqueline Monique Comte ,  George Owen Dale ,  Linda Ruth Pinckney ,  Charlene Marie Smith ,  Ronald Leroy Stewart ,  Steven Alvin Tietje

IPC: C03C14/00 ,  C03C10/00

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C10/0009 ,  C03C10/0027 ,  C03C14/00 ,  C03C21/002 ,  Y10T428/315

Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit β-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2  O + Na 2  O + K 2  O + MgO + ZnO ] [ Al 2  O 3 + B 2  O 3 ]  between 0.7 to 1.5; b. a ratio: [ TiO 2 + SnO 2 ] [ SiO 2 + B 2  O 3 ]  greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ≧about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.

Abstract translation: 公开了可结晶玻璃，玻璃陶瓷，IXable玻璃陶瓷和IX玻璃陶瓷。 玻璃陶瓷显示出β-锂辉石为主要结晶相。 这些玻璃和玻璃陶瓷（摩尔％）包括：62-75SiO 2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; 和0.05-0.2 SnO2。 另外，这些玻璃和玻璃陶瓷具有以下标准：a。 比例：0.7〜1.5的[Li 2 O + Na 2 O + K 2 O + MgO + ZnO] [Al 2 O 3 + B 2 O 3] b。 比例：[TiO 2 + SnO 2] [SiO 2 + B 2 O 3]大于0.04。 此外，玻璃陶瓷在400-700nm的波长范围内表现出大约85％的不透明度，约0.8mm厚度，并且观察角度为10°，CIE光源F02由包含a * 在-3和+3之间，b *在-6和+6之间，L *在88和97之间。

公开(公告)号：US09133054B2

公开(公告)日：2015-09-15

申请号：US14068558

申请日：2013-10-31

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Marie Jacqueline Monique Comte ,  George Owen Dale ,  Linda Ruth Pinckney ,  Charlene Marie Smith ,  Ronald Leroy Stewart ,  Steven Alvin Tietje

IPC: C03C10/12 ,  C03C14/00 ,  C03C10/00 ,  C03B32/02 ,  C03B20/00 ,  C03C3/085 ,  C03C3/093 ,  C03C21/00

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C10/0009 ,  C03C10/0027 ,  C03C14/00 ,  C03C21/002 ,  Y10T428/315

Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit β-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2 ⁢ O + Na 2 ⁢ O + K 2 ⁢ O + MgO + ZnO ] [ Al 2 ⁢ O 3 + B 2 ⁢ O 3 ]  between 0.7 to 1.5; b. a ⁢ ⁢ ratio ⁢ : ⁢ [ TiO 2 + SnO 2 ] [ SiO 2 + B 2 ⁢ O 3 ]  greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ≧about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.

Abstract translation: 公开了可结晶玻璃，玻璃陶瓷，IXable玻璃陶瓷和IX玻璃陶瓷。 玻璃陶瓷表现出以聚四氟乙烯为主要结晶相。 这些玻璃和玻璃陶瓷（摩尔％）包括：62-75SiO 2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; 和0.05-0.2 SnO2。 另外，这些玻璃和玻璃陶瓷具有以下标准：a。 比例：0.7〜1.5的[Li 2 O + Na 2 O + K 2 O + MgO + ZnO] [Al 2 O 3 + B 2 O 3] b。 aP比率：[TiO 2 + SnO 2] [SiO 2 + B 2 O 3]大于0.04。 此外，玻璃陶瓷在400-700nm的波长范围内表现出大约85％的不透明度，厚度约为0.8mm，并且观察角度为10°，CIE光源F02由包括a *的镜面反射率确定 -3和+3，b *在-6和+6之间，L *在88和97之间。

公开(公告)号：US08664130B2

公开(公告)日：2014-03-04

申请号：US13837863

申请日：2013-03-15

Applicant: Corning Incorporated

Inventor： George Halsey Beall ,  Marie Jacqueline Monique Comte ,  George Owen Dale ,  Linda Ruth Pinckney ,  Charlene Marie Smith ,  Ronald Leroy Stewart ,  Steven Alvin Tietje

IPC: C03C10/10 ,  C03C10/12 ,  C03C3/083

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C10/0009 ,  C03C10/0027 ,  C03C14/00 ,  C03C21/002 ,  Y10T428/315

Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit β-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 Si O2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2 ⁢ O + Na 2 ⁢ O + K 2 ⁢ O + MgO + ZnO ] [ Al 2 ⁢ O 3 + B 2 ⁢ O 3 ] between 0.7 to 1.5; b. a ratio: [ TiO 2 + SnO 2 ] [ SiO 2 + B 2 ⁢ O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ≧about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.

Abstract translation: 公开了可结晶玻璃，玻璃陶瓷，IXable玻璃陶瓷和IX玻璃陶瓷。 玻璃陶瓷显示出β-锂辉石为主要结晶相。 这些玻璃和摩尔％的玻璃陶瓷包括：62-75SiO 2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; 和0.05-0.2 SnO2。 另外，这些玻璃和玻璃陶瓷具有以下标准：a。 比例：0.7〜1.5的[Li 2 O + Na 2 O + K 2 O + MgO + ZnO] [Al 2 O 3 + B 2 O 3] b。 比例：[TiO 2 + SnO 2] [SiO 2 + B 2 O 3]大于0.04。 此外，玻璃陶瓷在400-700nm的波长范围内表现出大约85％的不透明度，约0.8mm厚度，并且观察角度为10°，CIE光源F02由包含a * 在-3和+3之间，b *在-6和+6之间，L *在88和97之间。

公开(公告)号：US09701573B2

公开(公告)日：2017-07-11

申请号：US14474708

申请日：2014-09-02

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Qiang Fu ,  Lisa Anne Moore ,  Linda Ruth Pinckney ,  Charlene Marie Smith

IPC: C03C10/04 ,  C03C10/12 ,  C03C10/00 ,  C03C3/097 ,  C03C3/093

CPC classification number: C03C10/0027 ,  C03C3/093 ,  C03C3/097 ,  C03C10/0054 ,  C03C21/002 ,  C03C2204/00

Abstract: Glass and glass ceramic compositions having a combination of lithium disilicate and β-spodumene crystalline phases along with methods of making the glass and glass ceramic compositions are described. The compositions are compatible with conventional rolling and float processes and have high mechanical strength and fracture resistance. Further, the compositions are able to be chemically tempered to even higher strength glass ceramics that are useful as large substrates in multiple applications.

公开(公告)号：US20140057092A1

公开(公告)日：2014-02-27

申请号：US14068558

申请日：2013-10-31

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Marie Jacqueline Monique Comte ,  George Owen Dale ,  Linda Ruth Pinckney ,  Charlene Marie Smith ,  Ronald Leroy Stewart ,  Steven Alvin Tietje

IPC: C03C14/00 ,  C03B20/00

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C10/0009 ,  C03C10/0027 ,  C03C14/00 ,  C03C21/002 ,  Y10T428/315

Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit β-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2  O + Na 2  O + K 2  O + MgO + ZnO ] [ Al 2  O 3 + B 2  O 3 ] between 0.7 to 1.5; b. a   ratio  :  [ TiO 2 + SnO 2 ] [ SiO 2 + B 2  O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ≧about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.

Abstract translation: 公开了可结晶玻璃，玻璃陶瓷，IXable玻璃陶瓷和IX玻璃陶瓷。 玻璃陶瓷显示出β-锂辉石为主要结晶相。 这些玻璃和玻璃陶瓷（摩尔％）包括：62-75SiO 2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; 和0.05-0.2 SnO2。 另外，这些玻璃和玻璃陶瓷具有以下标准：a。 比例：0.7〜1.5的[Li 2 O + Na 2 O + K 2 O + MgO + ZnO] [Al 2 O 3 + B 2 O 3] b。 比例：[TiO 2 + SnO 2] [SiO 2 + B 2 O 3]大于0.04。 此外，玻璃陶瓷在400-700nm的波长范围内表现出大约85％的不透明度，约0.8mm厚度，并且观察角度为10°，CIE光源F02由包含a * 在-3和+3之间，b *在-6和+6之间，L *在88和97之间。

公开(公告)号：US10196301B2

公开(公告)日：2019-02-05

申请号：US15615186

申请日：2017-06-06

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Qiang Fu ,  Lisa Anne Moore ,  Linda Ruth Pinckney ,  Charlene Marie Smith

IPC: C03C10/04 ,  C03C10/12 ,  C03C10/00 ,  C03C3/097 ,  C03C3/093 ,  C03C21/00

Abstract: Glass and glass ceramic compositions having a combination of lithium disilicate and β-spodumene crystalline phases along with methods of making the glass and glass ceramic compositions are described. The compositions are compatible with conventional rolling and float processes and have high mechanical strength and fracture resistance. Further, the compositions are able to be chemically tempered to even higher strength glass ceramics that are useful as large substrates in multiple applications.

公开(公告)号：US20170334767A1

公开(公告)日：2017-11-23

申请号：US15615186

申请日：2017-06-06

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Qiang Fu ,  Lisa Anne Moore ,  Linda Ruth Pinckney ,  Charlene Marie Smith

IPC: C03C10/00 ,  C03C3/097 ,  C03C3/093

CPC classification number: C03C10/0027 ,  C03C3/093 ,  C03C3/097 ,  C03C10/0054 ,  C03C21/002 ,  C03C2204/00

Abstract: Glass and glass ceramic compositions having a combination of lithium disilicate and -spodumene crystalline phases along with methods of making the glass and glass ceramic compositions are described. The compositions are compatible with conventional rolling and float processes and have high mechanical strength and fracture resistance. Further, the compositions are able to be chemically tempered to even higher strength glass ceramics that are useful as large substrates in multiple applications.

公开(公告)号：US20160152512A9

公开(公告)日：2016-06-02

申请号：US14474708

申请日：2014-09-02

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Qiang Fu ,  Lisa Anne Moore ,  Linda Ruth Pinckney ,  Charlene Marie Smith

IPC: C03C10/00

CPC classification number: C03C10/0027 ,  C03C3/093 ,  C03C3/097 ,  C03C10/0054 ,  C03C21/002 ,  C03C2204/00

Abstract: Glass and glass ceramic compositions having a combination of lithium disilicate and -spodumene crystalline phases along with methods of making the glass and glass ceramic compositions are described. The compositions are compatible with conventional rolling and float processes and have high mechanical strength and fracture resistance. Further, the compositions are able to be chemically tempered to even higher strength glass ceramics that are useful as large substrates in multiple applications.