摘要:
The present invention relates to a composition for cross-linking and stabilization of a polymer containing hydrolysable silane groups comprising a sulphonic acid as a silanol condensation catalyst characterized in that it comprises a stabilizer which is neutral or acidic, does not contain ester groups and is a compound according to formula (I): wherein R is an unsubstituted or substituted aliphatic or aromatic hydrocarbyl radical which may comprise heteroatoms, R′ is a hydrocarbyl radical, R″ is a hydrocarbyl radical and R′ and/or R″ being a bulky radical, X1, X2 or X3 is the same or different H or OH, whereby at least X1, X2 or X3 is OH, and n is 1 to 4; or a compound according to formula (II): R′″—(S)p—R′″ (II) wherein R′″ is an aliphatic hydrocarbyl radical and p is 1 to 6; or a mixture of any of such compounds, to a stabilized polymer comprising the above stabilizers and to a process for cross-linking and stabilization of silane group containing polymers in the presence of the above mentioned stabilizers.
摘要:
The present invention relates to an improved method for preparing an ethylene-silane copolymer comprising hydrolysable silane groups by radical-initiated polymerisation of ethylene and an olefinically unsaturated silane compound, such as vinyl trimethoxysilane (VTMS). Said method is performed in a multi-zone reactor comprising two or more reaction zones, wherein advantageously essentially all of the silane compound is introduced into the first reaction zone to provide a higher conversion of silane monomer into polymer.
摘要:
The present application concerns a process for the removal of hydrocarbons from an aqueous stream, which process may include conducting a phenol-containing water stream into a separation column, separating the phenol-containing water in the column using heat to form an overhead portion and a bottoms portion, and collecting the overhead portion as well as the bottoms portion. Further, the process may include adding an eluent to an aqueous stream, thereby forming an aqueous mixture, subsequently conducting the aqueous mixture into a separation vessel, wherein it is allowed to settle into two phases, which form a hydrocarbon stream and a phenol-containing water stream, subsequently collecting the hydrocarbon stream, and conducting the phenol-containing water stream to the separation column for further separation.
摘要:
A process for the removal of by-products from a phenolic mixture, which process may include the following steps: subjecting a phenolic mixture to extractive distillation to produce an initial phenolic mixture, contacting the initial phenolic mixture containing phenol and one or more by products with a catalyst to produce a first purified phenol product mixture, and distilling the first purified phenol product mixture to produce a second purified phenol product mixture; wherein the extractive distillation is carried out in two columns, a higher pressure column and a lower pressure column.
摘要:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol and a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 945 kg/m3 to 958 kg/m3. The coatings have a high stiffness, good properties at elevated temperatures and acceptable stress-cracking properties.
摘要翻译:本发明涉及具有多峰聚乙烯层的涂覆管。 多峰乙烯共聚物是乙烯与一种或多种具有4-10个碳原子的α-烯烃共聚单体的共聚物,其重均分子量为70000g / mol至250000g / mol,熔体指数MFR2为0.05 g / 10分钟至5g / 10min,熔体指数MFR5为0.5至10g / 10min,密度为945kg / m 3至958kg / m 3。 涂层具有高刚度,在高温下具有良好的性能和可接受的应力开裂性能。
摘要:
Novel polyolefin compositions comprising (A) a first propylene-ethylene random copolymer and (B) a second propylene-ethylene random copolymer, wherein the polyolefin composition has an ethylene content CMAB of 1-10 wt % and an MFR(AB) of 3-20 g/10 min with the proviso that CMAB>CMA and MFR(A)/MFR(AB)>1.45 and where the polyolefin composition further has a randomness R of the ethylene distribution in the polymer chain of 0.945. Articles made from the novel polyolefin compositions have excellent optical properties even after subjecting them to a heat sterilisation step.
摘要:
The present invention relates to a polymer composition, comprising: (i) a polypropylene matrix; (ii) a first elastomeric phase dispersed within the matrix and having a glass transition temperature Tg1, measured with dynamical mechanical thermal analysis according to ISO 6721-2, wherein the first elastomeric phase comprises an ethylene copolymer having comonomer units derived from C3 to C8 olefins; (iii) a second elastomeric phase dispersed within the matrix, wherein the second elastomeric phase is crosslinked and has a glass transition temperature Tg2, measured with dynamical mechanical thermal analysis according to ISO 6721-2, within the range of −70° C. to −90° C., wherein the difference between Tg1 and Tg2 is at least 15° C. and Tg1 is higher than Tg2.
摘要:
Propylene polymer composition comprising a polypropylene (A), an elastomeric copolymer (B) of ethylene and at least one α-olefin comonomer selected form the group consisting of propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene and 1-octene, and an ethylene C2 to C8 alkyl acrylate copolymer (C) wherein the composition has a strain hardening SH3.0/2.5 (at a Hencky strain rate of 3 s−1) of at least 0.5.
摘要:
The present invention relates to a crosslinkable polymer composition, comprising (i) a polyolefin, (ii) a polar copolymer, and (iii) a glycerol ester compound.