Nitric Oxide Detection
    22.
    发明申请
    Nitric Oxide Detection 失效
    一氧化氮检测

    公开(公告)号:US20080261322A1

    公开(公告)日:2008-10-23

    申请号:US12065545

    申请日:2006-09-04

    申请人: Dirk Burdinski

    发明人: Dirk Burdinski

    IPC分类号: G01N33/00 B01J19/00

    摘要: The present invention relates to a method for amplifying the detected signal in a gas sensor. More specifically, the present invention relates to a method for increasing the concentration of the gas which is being detected in a sample or increasing the concentration of a gas which is directly obtained from the gas in the sample by chemical reaction. The gas which is to be detected is nitric oxide (NO). In particular, the method concerns the selective conversion of NO to NO2 which allows a threefold amplification of the number of analyte molecules in NO trace gas analysis in a single amplification cycle. Subsequent reduction or thermal decomposition of the obtained NO2 can provide NO again, which can again be introduced in a new amplification cycle. Multiple (n) amplification cycles can provide a sensitivity amplification by a factor 3n. The method can be combined with a multitude of detection methods and tolerates a high humidity. The method is therefore of general use in the analysis of NO from a variety of sources.

    摘要翻译: 本发明涉及一种在气体传感器中放大检测信号的方法。 更具体地说,本发明涉及一种增加样品中检测的气体浓度的方法,或通过化学反应增加直接从样品中的气体获得的气体的浓度。 要检测的气体是一氧化氮(NO)。 特别地,该方法涉及NO向NO 2的选择性转化,其允许在单个放大循环中在NO痕量气体分析中分析物分子数量的三倍放大。 所得到的NO 2的还原或热分解可以再次提供NO,这可以再次在新的扩增循环中引入。 多(n)个放大循环可以通过因子3进行灵敏度放大。 该方法可以与多种检测方法相结合,并能承受高湿度。 因此,该方法通常用于分析来自各种来源的NO。

    System for diagnosing reagent solution quality and emissions catalyst degradation
    23.
    发明申请
    System for diagnosing reagent solution quality and emissions catalyst degradation 有权
    用于诊断试剂溶液质量和排放催化剂降解的系统

    公开(公告)号:US20050287034A1

    公开(公告)日:2005-12-29

    申请号:US10876066

    申请日:2004-06-24

    申请人: J. Wills Eric Andrews

    发明人: J. Wills Eric Andrews

    摘要: A system for determining a reagent solution quality indicator includes a reagent solution source for supplying the reagent solution to an emissions catalyst configured to receive a NOx-containing gas therethrough, means for determining a flow rate of NOx reduced from the gas by the catalyst, means for determining a flow rate of the reagent solution into the catalyst, and a control circuit determining the reagent solution quality indicator as a function of the NOx flow rate and the reagent solution flow rate. The system may additionally be configured to diagnose reagent solution quality by configuring the control circuit to monitor the reagent solution quality indicator over time and produce a fault value if the reagent solution quality indicator crosses a reagent quality indicator threshold, and to diagnose the catalyst by producing another fault value if the catalyst capacity point falls outside of a catalyst capacity point threshold.

    摘要翻译: 用于确定试剂溶液质量指示剂的系统包括用于将试剂溶液供给到构造成接收含有NO x的气体的排放催化剂的试剂溶液源,用于确定由催化剂从气体还原的NOx的流量的装置, 用于确定试剂溶液进入催化剂的流量;以及控制电路,其根据NOx流量和试剂溶液流速确定试剂溶液质量指示器。 该系统还可以被配置为通过配置控制电路来随时间监视试剂溶液质量指示器来诊断试剂溶液质量,并且如果试剂溶液质量指示符穿过试剂质量指示剂阈值并产生故障值,并通过产生 如果催化剂容量点超出催化剂容量点阈值以外的另一个故障值。

    In-line localized monitoring of catalyst activity in selective catalytic NOx reduction systems
    24.
    发明申请
    In-line localized monitoring of catalyst activity in selective catalytic NOx reduction systems 失效
    选择性催化NOx还原系统中催化剂活性的在线局部监测

    公开(公告)号:US20050255605A1

    公开(公告)日:2005-11-17

    申请号:US11112667

    申请日:2005-04-21

    摘要: Localized catalyst activity in an SCR unit for controlling emissions from a boiler, power plant, or any facility that generates NOx-containing flue gases is monitored by one or more modules that operate on-line without disrupting the normal operation of the facility. Each module is positioned over a designated lateral area of one of the catalyst beds in the SCR unit, and supplies ammonia, urea, or other suitable reductant to the catalyst in the designated area at a rate that produces an excess of the reductant over NOx on a molar basis through the designated area. Sampling probes upstream and downstream of the designated area draw samples of the gas stream for NOx analysis, and the catalyst activity is determined from the difference in NOx levels between the two probes.

    摘要翻译: 用于控制来自锅炉,发电厂或任何产生不含含烟气的任何设施的SCR单元中的局部催化剂活性由一个或多个在线运行的模块监测,而不会中断 设施的正常运行。 每个模块位于SCR单元中的一个催化剂床的指定横向区域上方,并以指定区域内的催化剂以超过NO 2的产生过量的还原剂的速率供应氨,尿素或其它合适的还原剂, 通过指定区域以摩尔计。 在指定区域的上游和下游的取样探针抽取气体流的样品用于NO x分析,并且催化剂活性是根据两者之间的NO

    Process for checking the processing of the exhaust gases of a heat engine and vehicle with a heat engine using this process
    26.
    发明申请
    Process for checking the processing of the exhaust gases of a heat engine and vehicle with a heat engine using this process 审中-公开
    使用该方法使用热机检查加热发动机和车辆的废气的处理的处理

    公开(公告)号:US20050191754A1

    公开(公告)日:2005-09-01

    申请号:US11068001

    申请日:2005-02-28

    IPC分类号: F02D41/02 F02D41/14 G01N33/00

    摘要: The present invention pertains to a process for checking the processing of the exhaust gases of a heat engine, the nitrogen oxides (NOx) contained in these gases being stored and then reduced in a trap modeled in such a way that the reduction of these nitrogen oxides (NOx) is actuated when the storage capacity of the trap, determined according to the model, reaches a threshold (Mthresh). According to the present invention, such a process is characterized in that the modeling of the trap is checked by measuring the quantity of nitrogen oxides (NOx) stored in this trap by means of a sensor located downstream of the trap, and by comparing this measurement to the quantity of nitrogen oxides (NOx) stored, determined according to the model, in order to correct the latter if the measured quantity is markedly different from the modeled quantity.

    摘要翻译: 本发明涉及一种用于检查热机排气处理的方法,这些气体中所含的氮氧化物(NOx)被储存,然后在陷阱中被还原,使得这些氮氧化物的还原 当根据模型确定的捕集器的存储容量达到阈值(M th thresh)时,致动(NOx)。 根据本发明,这种方法的特征在于通过位于捕集器下游的传感器测量存储在该捕集器中的氮氧化物(NOx)的量来检查捕集阱的建模,并且通过比较该测量 相对于根据模型确定的存储的氮氧化物(NOx)的量,以便如果测量的量与模拟量显着不同,则校正后者。

    Apparatus and method for diagnostic gas analysis
    27.
    发明申请
    Apparatus and method for diagnostic gas analysis 有权
    诊断气体分析仪器及方法

    公开(公告)号:US20040082872A1

    公开(公告)日:2004-04-29

    申请号:US10664225

    申请日:2003-09-16

    IPC分类号: A61B005/08

    摘要: A handheld, small but accurate and reliable device for diagnostic NO measurements using a NO sensor, where the parameters governing the taking of the sample are different from the parameters optimal for the accuracy of said NO sensor I described. By temporarily storing a portion of the exhaled air, and feeding this to the sensor at a flow rate adapted to the NO sensor, the accuracy and sensitivity of a system/method involving NO sensors, in particular electrochemical NO sensors, can be increased. The method for diagnostic NO measurements comprises steps for controlling the inhalation of NO free air, as well as the exhalation, both by built-in means and by audible and/or visual feedback to the patient.

    摘要翻译: 用于使用NO传感器进行诊断NO测量的手持式小型但精确和可靠的装置,其中控制取样的参数不同于所描述的所述NO传感器I的精度的最佳参数。 通过临时存储呼出的空气的一部分,并以适合于NO传感器的流量将其馈送到传感器,可以增加涉及NO传感器,特别是电化学NO传感器的系统/方法的精度和灵敏度。 用于诊断NO测量的方法包括用于通过内置装置以及通过对患者的声音和/或视觉反馈来控制NO游离空气的吸入以及呼气的步骤。

    Diaminorhodamine derivative
    29.
    发明授权
    Diaminorhodamine derivative 有权
    二氨基罗丹明衍生物

    公开(公告)号:US06469051B2

    公开(公告)日:2002-10-22

    申请号:US09750055

    申请日:2000-12-29

    IPC分类号: A61K31352

    摘要: A compound represented by the following general formula: wherein R1 and R2 represent amino groups present at adjacent positions each other on the phenyl ring; R3, R4, R5 and R6 independently represent a C1-6 alkyl group; R7, R8, R9 and R10 independently represent a hydrogen atom, a C1-6 alkyl group, an allyl group, or a halogen atom; R11 represents a hydrogen atom or a C1-18 alkyl group; and X− represents an anion, and an agent for nitric oxide measurement comprising said compound. The compound efficiently reacts with nitric oxide to give a fluorescent compound that emits strong fluorescence by irradiation with excitation light of a long wavelength. This fluorescent compound is characterized in that said compound is detectable in a fluorescence wavelength range hardly influenced by autofluorescence of cells, and its fluorescence intensity is not attenuated under an acidic condition.

    摘要翻译: 由以下通式表示的化合物:其中R 1和R 2表示在苯环上相邻位置上存在的氨基; R3,R4,R5和R6独立地表示C1-6烷基; R 7,R 8,R 9和R 10独立地表示氢原子,C 1-6烷基,烯丙基或卤素原子; R11表示氢原子或C1-18烷基; 和X-表示阴离子,和含有所述化合物的一氧化氮测定剂。化合物与一氧化氮有效反应,得到通过长波长激发光照射而发出强荧光的荧光化合物。 该荧光化合物的特征在于,所述化合物在几乎不受细胞自发荧光影响的荧光波长范围内是可检测的,其荧光强度在酸性条件下不衰减。

    Evaluating method for NOx eliminating catalyst, an evaluating apparatus therefor, and an efficiency controlling method therefor
    30.
    发明申请
    Evaluating method for NOx eliminating catalyst, an evaluating apparatus therefor, and an efficiency controlling method therefor 失效
    NOx排出催化剂的评价方法及其评价装置及其效率控制方法

    公开(公告)号:US20020132352A1

    公开(公告)日:2002-09-19

    申请号:US10152795

    申请日:2002-05-23

    申请人: Hitachi, Ltd.

    IPC分类号: G01N031/10 G01N033/22

    摘要: In order to prevent a catalyst for an internal combustion engine from decreasing efficiency by deterioration after long time use of the catalyst, the decreased efficiency of the catalyst is determined, and the internal engine is controlled based on results of the determination so as to maintain high efficiency of the catalyst. The catalyst is installed in an exhaust pipe of the engine. Sensors for detecting conditions of exhaust gas both at upstream side and downstream side of the catalyst are provided, respectively. As for the sensor, for example, an oxygen sensor of which output varies stepwise at nullnull1, or a sensor of which output varies in proportion to air-fuel ratio can be used. Detected values of the sensors are taken into a control unit, eliminating efficiency and deteriorating degree of the catalyst are estimated by comparison of the detected values, and the engine is controlled so that the eliminating efficiency becomes maximum. In accordance with the present invention, a preferable exhaust gas cleaning characteristics of the catalyst can be maintained because the decreased efficiency of the catalyst is determined exactly and the engine is controlled so as to prevent the catalyst from decreasing efficiency.

    摘要翻译: 为了防止内燃机的催化剂长时间使用催化剂后的劣化而降低效率,确定催化剂的效率降低,并且根据测定结果来控制内部发动机以保持高 催化剂的效率。 催化剂安装在发动机的排气管中。 分别提供用于检测催化剂的上游侧和下游侧的废气条件的传感器。 对于传感器,例如,可以使用其输出在lambd = 1处逐步变化的氧传感器,或者输出与空燃比成比例变化的传感器。 传感器的检测值被带入控制单元,通过比较检测值来估计催化剂的效率和劣化程度,并且控制发动机以使消除效率变得最大。 根据本发明,由于精确地确定催化剂的效率降低并且控制发动机以防止催化剂效率降低,因此可以保持催化剂的优选废气清洁特性。