摘要:
A heat resistant battery includes a positive electrode including a positive electrode current collector and a positive electrode active material fixed on the positive electrode current collector, wherein the positive electrode active material includes a sodium-containing transition metal compound capable of electrochemically storing and releasing a sodium ion; a negative electrode including a negative electrode current collector and a negative electrode active material fixed on the negative electrode current collector, wherein the negative electrode active material contains at least one selected from the group consisting of a sodium-containing titanium compound and a non-graphitizable carbon, each of the sodium-containing titanium compound and the non-graphitizable carbon capable of storing and releasing a sodium ion at a lower potential than a potential of the sodium-containing transition metal compound; and a sodium ion-conductive electrolyte provided at least between the positive electrode and the negative electrode, wherein the sodium ion-conductive electrolyte includes a salt of an organic cation having a pyrrolidinium skeleton and a bis(perfluoroalkyl sulfonyl)imide anion.
摘要:
Provided is a method for operating a molten salt battery having a sodium compound (NaCrO2) in a positive electrode and tin (Sn) in a negative electrode with a molten salt as an electrolytic solution. Although the operating temperature range of the molten salt battery is originally from 57° C. to 190° C., the molten salt battery is operated with an internal temperature thereof (temperature of electrodes and molten salt) set at from 98° C. to 190° C. to cause sodium to turn to a liquid phase. The sodium penetrates into a Sn—Na alloy micronized in the negative electrode, so that separation of the Sn—Na alloy is suppressed.
摘要:
A method of making an oil repellent sheet material according to an embodiment of the present disclosures includes a step of applying to a porous sheet a composition for forming an oil repellent layer, the composition containing a solvent and an amorphous fluorine resin dispersed therein, and a step of swaging the porous sheet after the step of applying, wherein the porous sheet has a fibrous skeleton composed mainly of polytetrafluoroethylene, the method of making an oil repellent sheet material further comprising a heat treatment step of heating the porous sheet to which the composition for forming an oil repellent layer is applied, before or after the step of swaging.
摘要:
A heat resistant battery includes a positive electrode including a positive electrode current collector and a positive electrode active material fixed on the positive electrode current collector, wherein the positive electrode active material includes a sodium-containing transition metal compound capable of electrochemically storing and releasing a sodium ion; a negative electrode including a negative electrode current collector and a negative electrode active material fixed on the negative electrode current collector, wherein the negative electrode active material contains at least one selected from the group consisting of a sodium-containing titanium compound and a non-graphitizable carbon, each of the sodium-containing titanium compound and the non-graphitizable carbon capable of storing and releasing a sodium ion at a lower potential than a potential of the sodium-containing transition metal compound; and a sodium ion-conductive electrolyte provided at least between the positive electrode and the negative electrode, wherein the sodium ion-conductive electrolyte includes a salt of an organic cation having a pyrrolidinium skeleton and a bis(perfluoroalkyl sulfonyl)imide anion.
摘要:
An aspect of the present invention relates to a negative electrode for a sodium molten salt battery, the negative electrode including a negative electrode current collector and a negative electrode mixture layer arranged on a surface of the negative electrode current collector, the negative electrode mixture layer including negative electrode active material particles and a film arranged on a surface of each of the negative electrode active material particles, the negative electrode active material particles containing hard carbon, and the film containing a sodium-containing sulfide.
摘要:
A sodium ion secondary battery includes an electrode group including a positive electrode and a negative electrode; an electrolyte, the electrode group being impregnated with the electrolyte; a case including a container with an opening portion and a sealing plate that closes the opening portion: and one or more insulating members, in which the electrolyte contains a molten salt, the molten salt contains cations and anions, the cations include a sodium ion and an organic cation, and all the insulating members are composed of a fluorine atom-free material.
摘要:
A molten-salt battery includes a positive electrode including a positive-electrode active material that reversibly occludes and releases sodium, a negative electrode including a negative-electrode active material that reversibly occludes and releases sodium, a separator disposed between the positive electrode and the negative electrode, and a molten-salt electrolyte. The molten-salt electrolyte contains an ionic liquid in an amount of 90% by mass or more. The ionic liquid contains a first salt and a second salt. The first salt contains a sodium ion which is a first cation, and a first anion. The second salt contains an organic cation which is a second cation, and a second anion. The positive-electrode active material contains a composite oxide having a layered O3-type crystal structure and containing Na, Fe, and Co. An amount of Co relative to a total of Fe and Co contained in the composite oxide is 40 to 60 atomic percent.
摘要:
A molten salt battery comprising a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and an electrolyte, wherein the electrolyte includes a molten salt, the molten salt contains at least sodium ions, and the moisture content We1 in the molten salt is 300 ppm or less in terms of mass ratio.
摘要:
As a molten salt composition lacking a clear melting point and including a molten salt that can be suitably used as an electrolytic solution of a secondary battery, there is provided a molten salt composition including a mixture of two or more kinds of molten salts which can be used as an electrolytic solution of a secondary battery. Particularly, provided is a molten salt composition comprising two kinds of molten salts each having cations with ion diameters different from each other, composition ratio being set to a composition ratio within a range in which the molten salt composition lacks a melting point. Also provided is a secondary battery including the molten salt composition as an electrolytic solution, which can maintains an available state even when the temperature becomes low without rapidly becoming unavailable.