Synthesis of ansa-metallocenes and their parent ligands in high yield
    29.
    发明授权
    Synthesis of ansa-metallocenes and their parent ligands in high yield 有权
    以高产量合成了金属茂及其母体配体

    公开(公告)号:US07064225B2

    公开(公告)日:2006-06-20

    申请号:US10876948

    申请日:2004-06-25

    IPC分类号: C07F17/00 C07C2/50

    CPC分类号: C07F17/00 B01J31/00 C07C2/72

    摘要: The present invention provides a method of making compounds comprising linked cyclopentadienyl and fluorenyl groups, including substituted analogs thereof, which are precursors to ansa-metallocenes comprising bridged cyclopentadienyl and fluorenyl ligands. In one aspect, this invention provides a preparative method for (5-cyclopentadienyl)[5-(2,7-di-tert-butylfluorenyl)]hex-1-ene, and ansa-metallocenes comprising this ligand.

    摘要翻译: 本发明提供了制备包含连接的环戊二烯基和芴基(包括其取代的类似物)的化合物的方法,其是包含桥连环戊二烯基和芴基配体的ansa-金属茂的前体。 一方面,本发明提供了(5-环戊二烯基)[5-(2,7-二叔丁基芴基)]己-1-烯的制备方法和包含该配体的仲 - 金属茂。