Structural materials with nearly zero carbon emissions
    16.
    发明授权
    Structural materials with nearly zero carbon emissions 有权
    几乎零碳排放的结构材料

    公开(公告)号:US09388074B2

    公开(公告)日:2016-07-12

    申请号:US12746781

    申请日:2008-12-16

    摘要: Processes and methods of making and preparing, compositions and structural products therefrom are provided, whereby the surface area of alumino-silicate based powders is greatly increased and rendered chemically active so that when the functionalized powders are mixed with water poly-condensation reactions occur between the surfaces binding the powders together to form a structural material with negligible emission of carbon compounds. In another embodiment, the surface functionalized powders can be mixed with an additive; a dry aggregate, such as sand and water to make a slurry that can be poured or cast into any desired shape and rapidly cured to a hardened shape suitable for use as a structural material with the mechanical strength equivalent to Portland-cement based concrete products. In additional embodiments, the alumino-silicate based powders are nano-functionalized and foam functionalized to provide light weight and structurally strong materials that can also be used in combination with or as replacement for Portland-cement.

    摘要翻译: 提供了制备和制备其组合物和结构产品的方法和方法,由此铝硅酸盐基粉末的表面积大大增加并具有化学活性,使得当官能化粉末与水混合时,多缩合反应发生在 表面将粉末结合在一起形成具有可忽略的碳化合物排放的结构材料。 在另一个实施方案中,表面官能化粉末可与添加剂混合; 干燥的骨料,例如砂和水,以制成可以浇注或浇铸成任何所需形状的浆料,并迅速固化成适合用作具有与波特兰 - 水泥基混凝土产品相当的机械强度的结构材料的硬化形状。 在另外的实施方案中,基于硅铝酸盐的粉末是纳米官能化的和泡沫官能化的,以提供轻质量和结构上强的材料,其也可以与波特兰 - 水泥的组合或代替。

    Facile synthesis of metalloporphyrin polymers
    18.
    发明授权
    Facile synthesis of metalloporphyrin polymers 有权
    金属卟啉聚合物的简便合成

    公开(公告)号:US09090742B2

    公开(公告)日:2015-07-28

    申请号:US13930120

    申请日:2013-06-28

    发明人: Sean Vail David Evans

    IPC分类号: C08G79/00 C08G61/12

    摘要: A method is provided for synthesizing a metal (M) meso-tetraphenylporphyrin polymer. The method begins with the provision of a free-base (H2)-meso-tetra-4-(trialkylsilyl)ethynylphenylporphyrin (H2-tetra-C≡C-TriAS-TPP) including a trialkylsilyl (TriAS) moiety attached to an ethynyl termini. In response to a reaction with a metal (M)-containing material, the H2-tetra-C≡C-TriAS-TPP is converted to a metal (M)-tetra-4-(trialkylsilyl)ethynylphenylporphyrin (M-tetra-C≡C-TriAS-TPP). Then, the M-tetra-C≡C-TriAS-TPP is converted to a M-tetra-4-ethynylphenylporphyrin (M-tetra-C≡C-TPP) monomer by removing the trialkylsilyl (TriAS) moiety from the ethynyl termini. Finally, a plurality of M-tetra-C≡C-TPP monomers are coupled together to supply a metal (M)-meso-tetraphenylporphyrin polymer (M-poly-meso-TPP), whereby meso-phenyl groups of adjacent M-tetra-C≡C-TPP monomers in the M-poly-meso-TPP are connected through a butadiyne linking moiety. In one aspect, the metal is zinc.

    摘要翻译: 提供了一种合成金属(M)内消旋 - 四苯基卟啉聚合物的方法。 该方法开始于提供包含连接到乙炔基末端的三烷基甲硅烷基(TriAS)部分的游离碱(H 2) - 四乙基 - 四-4-(三烷基甲硅烷基)乙炔基苯基卟啉(H 2 - 四-C≡C-TriAS-TPP) 。 响应于与含金属(M)的材料的反应,将H 2 - 四-C≡C-TriAS-TPP转化为金属(M) - 四-4-(三烷基甲硅烷基)乙炔基苯基卟啉(M-四-C ≡C-TriAS-TPP)。 然后,通过从乙炔基末端除去三烷基甲硅烷基(TriAS)部分,将M-tetra-C≡C-TriAS-TPP转化为M-四-4-乙炔基苯基卟啉(M-tetra-C≡C-TPP)单体。 最后,将多个M-tetra-C≡C-TPP单体偶联在一起以供应金属(M) - 四 - 四苯基卟啉聚合物(M-poly-meso-TPP),由此相邻的M-四 M-poly-meso-TPP中的-C≡C-TPP单体通过Butadiyne连接部分连接。 在一个方面,金属是锌。

    Facile Synthesis of Metalloporphyrin Polymers
    19.
    发明申请
    Facile Synthesis of Metalloporphyrin Polymers 有权
    金属卟啉聚合物的简便合成

    公开(公告)号:US20150005463A1

    公开(公告)日:2015-01-01

    申请号:US13930120

    申请日:2013-06-28

    发明人: Sean Vail David Evans

    IPC分类号: C08G79/00

    摘要: A method is provided for synthesizing a metal (M) meso-tetraphenylporphyrin polymer. The method begins with the provision of a free-base (H2)-meso-tetra-4-(trialkylsilyl)ethynylphenylporphyrin (H2-tetra-C≡C-TriAS-TPP) including a trialkylsilyl (TriAS) moiety attached to an ethynyl termini. In response to a reaction with a metal (M)-containing material, the H2-tetra-C≡C-TriAS-TPP is converted to a metal (M)-tetra-4-(trialkylsilyl)ethynylphenylporphyrin (M-tetra-C≡C-TriAS-TPP). Then, the M-tetra-C≡C-TriAS-TPP is converted to a M-tetra-4-ethynylphenylporphyrin (M-tetra-C≡C-TPP) monomer by removing the trialkylsilyl (TriAS) moiety from the ethynyl termini. Finally, a plurality of M-tetra-C≡C-TPP monomers are coupled together to supply a metal (M)-meso-tetraphenylporphyrin polymer (M-poly-meso-TPP), whereby meso-phenyl groups of adjacent M-tetra-C≡C-TPP monomers in the M-poly-meso-TPP are connected through a butadiyne linking moiety. In one aspect, the metal is zinc.

    摘要翻译: 提供了一种合成金属(M)内消旋 - 四苯基卟啉聚合物的方法。 该方法开始于提供包含连接到乙炔基末端的三烷基甲硅烷基(TriAS)部分的游离碱(H 2) - 四乙基 - 四-4-(三烷基甲硅烷基)乙炔基苯基卟啉(H 2 - 四-C≡C-TriAS-TPP) 。 响应于与含金属(M)的材料的反应,将H 2 - 四-C≡C-TriAS-TPP转化为金属(M) - 四-4-(三烷基甲硅烷基)乙炔基苯基卟啉(M-四-C ≡C-TriAS-TPP)。 然后,通过从乙炔基末端除去三烷基甲硅烷基(TriAS)部分,将M-tetra-C≡C-TriAS-TPP转化为M-四-4-乙炔基苯基卟啉(M-tetra-C≡C-TPP)单体。 最后,将多个M-tetra-C≡C-TPP单体偶联在一起以供应金属(M) - 四 - 四苯基卟啉聚合物(M-poly-meso-TPP),由此相邻的M-四 M-poly-meso-TPP中的-C≡C-TPP单体通过Butadiyne连接部分连接。 在一个方面,金属是锌。

    Nanoparticles
    20.
    发明授权
    Nanoparticles 有权
    纳米颗粒

    公开(公告)号:US08828542B2

    公开(公告)日:2014-09-09

    申请号:US12713443

    申请日:2010-02-26

    申请人: Dong Hoon Choi

    发明人: Dong Hoon Choi

    摘要: Nanoparticles can include a core linked to a polymerizable moiety that can be polymerized, cross-linked or cured. The polymerizable nanoparticles can be included in a composition for a polymerization, cross-linking or curing reaction in an amount and disposition sufficient for inhibiting or preventing volume shrinkage during polymerization, cross-linking or curing reaction. Also, the nanoparticles can be included with monomers, dendrimers, oligomers or polymers in the compositions that can be reacted to form a polymerized, cross-linked or cured product.

    摘要翻译: 纳米颗粒可以包括连接到可聚合,交联或固化的可聚合部分的核心。 可聚合的纳米颗粒可以包含在用于聚合,交联或固化反应的组合物中,其量和处理量足以抑制或防止聚合,交联或固化反应期间的体积收缩。 此外,纳米颗粒可以包含在组合物中的单体,树枝状大分子,低聚物或聚合物,其可以反应以形成聚合的,交联的或固化的产物。