公开(公告)号：US09039889B2

公开(公告)日：2015-05-26

申请号：US12881900

申请日：2010-09-14

申请人： Ki-Hyouk Choi ,  Ashok K. Punetha ,  Mohammed R. Al-Dossary ,  Mohammad F. Aljishi

发明人： Ki-Hyouk Choi ,  Ashok K. Punetha ,  Mohammed R. Al-Dossary ,  Mohammad F. Aljishi

IPC分类号： C10B55/00 ,  C10G51/02 ,  C10G65/00 ,  C10G65/02 ,  C10G49/18 ,  C10G49/22

CPC分类号： C10G65/10 ,  C10G47/32 ,  C10G49/18 ,  C10G49/22 ,  C10G65/02 ,  C10G2300/42 ,  C10G2300/805

摘要： A hydrocarbon feedstock upgrading method is provided. The method includes supplying the hydrocarbon feedstock, water and a pre-heated hydrogen donating composition to a hydrothermal reactor where the mixed stream is maintained at a temperature and pressure greater than the critical temperatures and pressure of water in the absence of catalyst for a residence time sufficient to convert the mixed stream into a modified stream. The hydrogen donating composition is pre-heated and maintained at a temperature of greater than about 50° C. for a period of at least about 10 minutes. The modified stream includes upgraded hydrocarbons relative to the hydrocarbon feedstock. The modified stream is then separated into a gas stream and a liquid stream and the liquid stream is separated into a water stream and an upgraded hydrocarbon product stream.

摘要翻译： 提供了一种烃原料提质方法。 该方法包括将烃原料，水和预热的供氢组合物供应到水热反应器中，其中混合流保持在不存在催化剂的停留时间的情况下大于临界温度和压力的温度和压力 足以将混合流转化为改性流。 给氢组合物被预热并保持在大于约50℃的温度下至少约10分钟的时间。 修饰的流包括相对于烃原料的改进的烃。 然后将改性的流分离成气流和液体流，并将液体流分离成水流和升级的烃产物流。

公开(公告)号：US08298377B2

公开(公告)日：2012-10-30

申请号：US13287448

申请日：2011-11-02

申请人： Taishi Kurata

发明人： Taishi Kurata

IPC分类号： C10G9/00

CPC分类号： C10G9/00 ,  B01J4/02 ,  B01J19/0013 ,  B01J19/008 ,  B01J2219/00081 ,  B01J2219/00094 ,  B01J2219/00157 ,  C10G9/42 ,  C10G45/00 ,  C10G47/32 ,  C10G49/007

摘要： Equipment and a process for upgrading oil are provided to produce a refined oil lighter than a material oil by cracking the heavier material oil with the addition of hydrogen under relatively relaxed production conditions. An equipment for upgrading oil according to one aspect of the invention includes an emulsion making portion (10), a refinery tank portion (20), and a heating portion (30), and configured to make an emulsion (E) by emulsifying ionized alkaline water (A) in a material oil (O1) in the emulsion making portion (10), and to drop droplets (D) of the emulsion (E) onto the surface (S) of a heat medium (O2) in the refinery tank portion (20) heated by the heating portion (30).

公开(公告)号：US20120181217A1

公开(公告)日：2012-07-19

申请号：US13009062

申请日：2011-01-19

申请人： Ki-Hyouk Choi ,  Mohammad F. Aljishi

发明人： Ki-Hyouk Choi ,  Mohammad F. Aljishi

IPC分类号： C10G67/06

CPC分类号： C10G55/04 ,  C10G21/08 ,  C10G25/00 ,  C10G45/02 ,  C10G47/00 ,  C10G47/32 ,  C10G2300/1033 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/308 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/805 ,  C10G2400/04

摘要： A petroleum feedstock upgrading method is provided. The method includes supplying a mixed stream that includes hydrocarbon feedstock and water to a hydrothermal reactor where the mixed stream is maintained at a temperature and pressure greater than the critical temperatures and pressure of water in the absence of catalyst for a residence time sufficient to convert the mixed stream into a modified stream having an increased concentration of lighter hydrocarbons and/or concentration of sulfur containing compounds. The modified stream is then supplied to an adsorptive reaction stage charged with a solid adsorbent operable to remove at least a portion of the sulfur present to produce a trimmed. The trimmed stream is then separated into a gas and a liquid streams, and the liquid stream is separated into a water stream and an upgraded hydrocarbon product stream.

摘要翻译： 提供石油原料提质方法。 该方法包括将包含烃原料和水的混合物流供应到水热反应器中，其中混合物流保持在​​不存在催化剂的情况下，其温度和压力大于水的临界温度和压力，停留时间足以使 将混合物流转化为具有增加的较轻烃浓度和/或含硫化合物浓度的改性物流。 然后将经修饰的料流供应到装有固体吸附剂的吸附反应阶段，该固体吸附剂可操作以除去至少一部分存在的硫以产生修剪。 然后将修整的流分离成气体和液体流，并将液体流分离成水流和升级的烃产物流。

公开(公告)号：US20120061291A1

公开(公告)日：2012-03-15

申请号：US12881900

申请日：2010-09-14

申请人： Ki-Hyouk Choi ,  Ashok K. Punetha ,  Mohammed R. Al-Dossary ,  Mohammad F. Aljishi

发明人： Ki-Hyouk Choi ,  Ashok K. Punetha ,  Mohammed R. Al-Dossary ,  Mohammad F. Aljishi

IPC分类号： C10G69/02 ,  C10G49/22

CPC分类号： C10G65/10 ,  C10G47/32 ,  C10G49/18 ,  C10G49/22 ,  C10G65/02 ,  C10G2300/42 ,  C10G2300/805

摘要： A hydrocarbon feedstock upgrading method is provided. The method includes supplying the hydrocarbon feedstock, water and a pre-heated hydrogen donating composition to a hydrothermal reactor where the mixed stream is maintained at a temperature and pressure greater than the critical temperatures and pressure of water in the absence of catalyst for a residence time sufficient to convert the mixed stream into a modified stream. The hydrogen donating composition is pre-heated and maintained at a temperature of greater than about 50° C. for a period of at least about 10 minutes. The modified stream includes upgraded hydrocarbons relative to the hydrocarbon feedstock. The modified stream is then separated into a gas stream and a liquid stream and the liquid stream is separated into a water stream and an upgraded hydrocarbon product stream.

摘要翻译： 提供了一种烃原料提质方法。 该方法包括将烃原料，水和预热的供氢组合物供应到水热反应器中，其中混合流保持在不存在催化剂的停留时间的水的临界温度和压力以上的温度和压力 足以将混合流转化为改性流。 给氢组合物被预热并保持在大于约50℃的温度下至少约10分钟的时间。 修饰的流包括相对于烃原料的改进的烃。 然后将改性的流分离成气流和液体流，并将液体流分离成水流和升级的烃产物流。

公开(公告)号：US20110275869A1

公开(公告)日：2011-11-10

申请号：US13101368

申请日：2011-05-05

申请人： ROMAN PROCHAZKA ,  STEFAN BITTERLICH ,  OTTO MACHHAMMER ,  STEPHAN DEUERLEIN ,  DIRK KLINGLER ,  EMMANOUIL PANTOUFLAS ,  ALOIS KINDLER ,  BERND ZOELS

发明人： ROMAN PROCHAZKA ,  STEFAN BITTERLICH ,  OTTO MACHHAMMER ,  STEPHAN DEUERLEIN ,  DIRK KLINGLER ,  EMMANOUIL PANTOUFLAS ,  ALOIS KINDLER ,  BERND ZOELS

IPC分类号： C07C1/00 ,  C07C39/00 ,  C01B3/34

CPC分类号： C10G1/02 ,  C01B3/32 ,  C01B2203/02 ,  C10B53/02 ,  C10G1/06 ,  C10G3/00 ,  C10G3/50 ,  C10G47/32 ,  C10G2300/1014 ,  C10G2300/1096 ,  C10G2400/30 ,  Y02P30/20

摘要： The present invention relates to a process for producing synthesis gas and at least one organic liquid or liquefiable material of value, wherein a) a biomass starting material is provided, b) the biomass starting material is subjected to a decomposition, c) at least one aromatics-enriched fraction C1) and at least one aromatics-depleted fraction C2) are optionally isolated from the decomposed material obtained in step b), d) the decomposition product from step b) or the aromatics-enriched fraction C1) from step c) is fed into a dealkylation zone and reacted in the presence of hydrogen and/or water vapor, e) a discharge is taken from the dealkylation zone and subjected to a separation to give at least one organic liquid or liquefiable material of value and at least one stream enriched in components which are more volatile than the organic material of value, f) the stream enriched in components which are more volatile than the organic material of value which is obtained in step e) is at least partly used for producing synthesis gas.

摘要翻译： 本发明涉及生产合成气和至少一种有价值的有机液体或液化材料的方法，其中a）提供生物质原料，b）生物质起始材料进行分解，c）至少一种 富含芳族化合物的馏分C1）和至少一种不含芳烃的馏分C2）任选地从步骤b）中获得的分解物质中分离出来，d）来自步骤b）的分解产物或来自步骤c）的富含芳烃的级分C1） 进料到脱烷基区并在氢气和/或水蒸汽的存在下反应，e）从脱烷基区取出并进行分离，得到至少一种有价值的有机液体或可液化材料，并且至少一种 富含比值的有机材料更易挥发的组分的流，f）富含比在步骤e）中获得的值的有机材料更易挥发的组分的物流在 最少部分用于生产合成气。

公开(公告)号：US20110163005A1

公开(公告)日：2011-07-07

申请号：US12683653

申请日：2010-01-07

申请人： Jose J. P. Lourenco ,  John Gordon Murphy

发明人： Jose J. P. Lourenco ,  John Gordon Murphy

IPC分类号： C10G47/00

CPC分类号： C10G15/08 ,  C10G9/007 ,  C10G31/06 ,  C10G47/00 ,  C10G47/32 ,  C10G2300/302

摘要： Methods, systems and other embodiments associated with upgrading heavy oil by hydrocracking are presented. A method of upgrading heavy oil includes mixing raw heavy oil with hydrogen to produce a mixed heavy oil. The mixed heavy oil is heated to produce heated heavy oil. High pressure pulses are created in the heated heavy oil to crack the heated heavy oil to produce cracked oil with a lower viscosity than the raw heavy oil.

摘要翻译： 提出了通过加氢裂化与重油相关的方法，系统和其它实施方案。 重油改质方法包括将原重油与氢混合，制成混合重油。 将混合的重油加热以产生加热的重油。 在加热的重油中产生高压脉冲，以使加热的重油裂解以产生比原始重油低的粘度的裂化油。

公开(公告)号：US20100314583A1

公开(公告)日：2010-12-16

申请号：US12633232

申请日：2009-12-08

申请人： Dwijen K. Banerjee

发明人： Dwijen K. Banerjee

IPC分类号： C01B3/02 ,  C10G47/00 ,  C10G47/02

CPC分类号： C10G11/16 ,  C10G11/20 ,  C10G45/04 ,  C10G45/26 ,  C10G47/02 ,  C10G47/26 ,  C10G47/32 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/42

摘要： A method of mixing a catalyst with a heavy oil to create a heavy oil/catalyst mixture. This is followed by combining the heavy oil/catalyst mixture with supercritical water to form light hydrocarbon products and heavy hydrocarbon products. By doing so the light hydrocarbon products can be separated into a gaseous top product, an upgraded liquid hydrocarbon product and a water phase.

摘要翻译： 一种将催化剂与重油混合以产生重油/催化剂混合物的方法。 然后将重油/催化剂混合物与超临界水混合，形成轻烃产物和重质烃产物。 通过这样做，轻烃产物可以分离成气态顶部产物，升级液体烃产物和水相。

公开(公告)号：US20090173664A1

公开(公告)日：2009-07-09

申请号：US12277270

申请日：2008-11-24

申请人： Ki-Hyouk Choi ,  Ali Al-Shareef

发明人： Ki-Hyouk Choi ,  Ali Al-Shareef

IPC分类号： C10G1/00 ,  B01J19/00

CPC分类号： B01J3/008 ,  C10G9/00 ,  C10G31/08 ,  C10G45/26 ,  C10G47/32 ,  C10G75/00 ,  C10G2300/1033 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/4081 ,  C10G2300/805 ,  E21B43/16

摘要： A process for upgrading heavy oil by mixing the heavy oil with water fluid using an ultrasonic wave generator prior to increasing the temperature and pressure of the mixture to values near to or exceeding the critical point of water, to produce low pour point, high value oil having low sulfur, low nitrogen, and low metallic impurities for use as hydrocarbon feedstock.

摘要翻译： 在将混合物的温度和压力提高到接近或超过水的临界点的值之前，通过使用超声波发生器将重油与水溶液混合来提高重油的方法，以产生低倾点，高价值油 具有低硫，低氮和低金属杂质用作烃原料。

公开(公告)号：US20090159498A1

公开(公告)日：2009-06-25

申请号：US11960891

申请日：2007-12-20

申请人： Daniel Chinn ,  Steven F. Sciamanna ,  Zunqing Alice He

发明人： Daniel Chinn ,  Steven F. Sciamanna ,  Zunqing Alice He

IPC分类号： C10G1/00

CPC分类号： C10G31/08 ,  C10G9/00 ,  C10G45/26 ,  C10G47/32

摘要： A process is provided for in-field upgrading of heavy hydrocarbons such as whole heavy oil, bitumen, and the like using supercritical water.

摘要翻译： 提供了使用超临界水对重质烃如全重油，沥青等进行现场升级的方法。

公开(公告)号：US20090145805A1

公开(公告)日：2009-06-11

申请号：US12277255

申请日：2008-11-24

申请人： Ki-Hyouk Choi

发明人： Ki-Hyouk Choi

IPC分类号： C10G31/06 ,  B01J14/00

CPC分类号： B01J3/008 ,  C10G9/00 ,  C10G31/08 ,  C10G45/26 ,  C10G47/32 ,  C10G75/00 ,  C10G2300/1033 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/4081 ,  C10G2300/805 ,  E21B43/16

摘要： A continuous process to upgrade heavy crude oil for producing more valuable crude feedstock having high API gravity, low asphaltene content, and high middle distillate yield, low sulfur content, low nitrogen content, and low metal co teat without external supply of hydrogen and/or catalyst. Heavy crude oil having substantial amount of asphaltene and heavy components is mixed with highly waxy crude oil having large amount of paraffinic components and water to decompose asphaltene compounds and remove sulfur, nitrogen, and metal containing substances under supercritical conditions. Product has higher API gravity, lower asphaltene content, high middle distillate yield, lower sulfur content, lower nitrogen content, and lower metal content to be suitable for conventional petroleum refining process.

摘要翻译： 一种连续的过程，用于提炼重质原油，用于生产具有高API重力，低沥青质含量和高中间馏分产率的较有价值的原油原料，低硫含量，低氮含量和低金属奶油，而无需外部供应氢气和/或 催化剂。 将具有大量沥青质和重质成分的重质原油与具有大量链烷烃成分和水的高度蜡质原油混合，以分解沥青质化合物并在超临界条件下除去含硫，氮和金属的物质。 产品具有较高的API重力，较低的沥青质含量，较高的中间馏分产率，较低的硫含量，较低的氮含量和较低的金属含量适用于常规的石油炼制过程。