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公开(公告)号：US07482438B2
公开(公告)日：2009-01-27
申请号：US10594047
申请日：2005-03-23
CPC分类号： C09B44/16
摘要： Disclosed are azo dyes of formula (1), wherein R1 is hydrogen; C1-C14alkyl; hydroxy-C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a) —(CH2)n1—O—(CH2)n2—CH3; a radical of formula (1b) C10aryl; or C6-C10aryl-C1-C6alkyl; R3 is hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C6alkyl; or CO—R6; R4 is CO—R6; R5 is C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; R6 is hydrogen; C1-C14alkyl; C2-C14alkenyl; or C6-C10aryl; R7, R8, R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; m is 1; or 2; An− is an anion; If m=1, R2 is hydrogen; C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a); a radical of formula (1b); C6-C10aryl; or C6-C10aryl-C1-C6alkyl; If m=2, R2 is the direct bond; or C1-C14alkylene, which is optionally substituted by one or more C1-C4alkyl, or which is optionally interrupted by C5-C10arylene, —O— or —NR9R10—; R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair.
摘要翻译： 公开了式（1）的偶氮染料，其中R 1是氢; C 1 -C 14烷基; 羟基-C 1 -C 14烷基; C2-C14烯基; （1a） - （CH2）n1-O-（CH2）n2-CH3的基团; 式（1b）的基团C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; R3是氢; C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 6烷基; 或CO-R6; R4是CO-R6; R5是C1-C14烷基; C2-C14烯基; C6-C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; R6是氢; C 1 -C 14烷基; C2-C14烯基; 或C 6 -C 10芳基; R 7，R 8，R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; m为1; 或2; An-是阴离子; 如果m = 1，则R2为氢; C 1 -C 14烷基; C2-C14烯基; 式（1a）的基团; 式（1b）的基团; C6-C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; 如果m = 2，则R2是直接键; 或C 1 -C 14亚烷基，其任选被一个或多个C 1 -C 4烷基取代，或任选地被C 5 -C 10亚芳基，-O-或-NR 9 R 10 - 取代; R9和R10彼此独立地是氢; 或C 1 -C 5烷基; 和n1，n2，n3和n4彼此独立地为0至5的数字。该化合物可用于染色有机材料，优选人发。
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公开(公告)号：US07806940B2
公开(公告)日：2010-10-05
申请号：US11922071
申请日：2006-06-07
CPC分类号： C09B44/16 , A61K8/4946 , A61K8/84 , A61K2800/57 , A61Q5/065 , C07D403/00 , C08G73/00 , C08G73/0273 , C08G73/0616 , C09B44/101 , C09B49/00 , C09B69/106
摘要： Disclosed are oligomeric cationic azo dyes of formula (1), their salts, isomers, hydrates and other solvates, wherein n, R1, R2, X, Y− and Z+ are defined in claims and disclosure. Furthermore, the present invention relates to novel cationic oligomeric azo dyes of formula (1), compositions, thereof, especially comprising other dyes, and to application for hair dyeing.
摘要翻译： 公开了式（1）的低聚阳离子偶氮染料，其盐，异构体，水合物和其它溶剂化物，其中n，R1，R2，X，Y-和Z +在权利要求和公开中定义。 此外，本发明涉及式（1）的新型阳离子低聚偶氮染料，其组合物，特别是其它染料，以及染发用途。
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公开(公告)号：US20090300855A1
公开(公告)日：2009-12-10
申请号：US11922660
申请日：2006-06-21
IPC分类号： A61K8/49 , A61Q5/10 , C07D279/08
CPC分类号： A61Q5/10 , A61K8/49 , C07D513/04 , C09B23/0091
摘要： Disclosed is a method of dyeing keratin-containing fibers comprising treating the fiber with at least one compound of formula (1), wherein R1, R2, R3, R4 independently from each other are hydrogen; hydroxy; —S—H; —S—C1-C12alkyl; halogen; C1-C12alkyl or C1-C12alkoxy, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy, —(CO)—H or —(CO)—C1-C5alkyl; —NR5R6; —NO2; —(CO)H or (CO)—C1-C5alkyl; C6-C12aryl, C6-C12aryl-C1-C4alkyl or C6-C12aryl-C1-C4alkoxy, wherein the aryl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, —(CO)—H or —(CO)—C1-C5alkyl; R5 and R6 independently from each other are hydrogen; hydroxy; C1-C12alkyl; hydroxy-C1-C12alkyl; —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C5alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; and An is an anion. Furthermore, the present invention relates to novel heterocyclic compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation and application to hair dying.
摘要翻译： 公开了一种染色含角蛋白纤维的方法，包括用至少一种式（1）化合物处理纤维，其中R 1，R 2，R 3，R 4彼此独立地为氢; 羟基; -S-H; -S-C 1 -C 12烷基; 卤素; C 1 -C 12烷基或C 1 -C 12烷氧基，其可以被一个或多个C 1 -C 5烷基，C 1 -C 5 - 烷氧基，羟基， - （CO）-H或 - （CO）-C 1 -C 5烷基取代; -NR5R6; -NO2; - （CO）H或（CO）-C 1 -C 5烷基; C 1 -C 12芳基，C 6 -C 12芳基-C 1 -C 4烷基或C 6 -C 12芳基-C 1 -C 4烷氧基，其中芳基部分可被一个或多个C 1 -C 5烷基，C 1 -C 5烷氧基， - （CO）-H或 - （CO） -C 1 -C 5烷基; R5和R6彼此独立地是氢; 羟基; C 1 -C 12烷基; 羟基-C 1 -C 12烷基; - （CO）-H; - （CO）-C 1 -C 5烷基; 苯基或苯基-C 1 -C 5烷基，其中苯基部分可被一个或多个C 1 -C 5烷基，C 1 -C 5烷氧基，卤素，-NH 2，单C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-NO 2，羧基或羟基 ; 而An是阴离子。 此外，本发明涉及新颖的杂环化合物，其组合物，特别是其它染料，以及其制备和应用于染发的方法。
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公开(公告)号：US20090293208A1
公开(公告)日：2009-12-03
申请号：US11922071
申请日：2006-06-07
CPC分类号： C09B44/16 , A61K8/4946 , A61K8/84 , A61K2800/57 , A61Q5/065 , C07D403/00 , C08G73/00 , C08G73/0273 , C08G73/0616 , C09B44/101 , C09B49/00 , C09B69/106
摘要： Disclosed are oligomeric cationic azo dyes of formula (I), wherein their salts, isomers, hydrates and other solvates, wherein R1 is hydrogen; C1-C12alkyl, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy or —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C4alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; R2 is hydrogen; or C1-C5alkyl; X is C1-C10alkylene, which may be substituted by one or more C1-C5alkyl, hydroxy, C1-C5-alkoxy, amino, mono-C1-C5alkylamino, di-C1-C5alkylamino, —SH, and/or interrupted by one or more —O— or —S—S—; C5-C10cycloalkylene; C5-C12arylene; C5-C12arylene-(C1-C10alkylene); biphenylene, which may be substituted by one or more C1-C5alkyl, hydroxy, C1-C5-alkoxy, amino, mono-C1-C5alkylamino, di-C1-C5alkylamino, —SH, and/or interrupted by one or more —O—, C1-C4-alkylene, —NR3—, —S— or —S—S—; R3 is hydrogen; C1-C12alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C12alkyl; or C1-C12alkyl-C6-C12aryl; Y is an anion; Z is 1,3-thiazolyl; 1,2-thiazolyl; 1,3-benzothiazolyl; 2,3-benzothiazolyl; imidazolyl; 1,3,4-thiadiazolyl; 1,3,5-thiadiazolyl; 1,3,4-triazolyl; pyrazolyl; benzimidazolyl; benzopyrazolyl; pyridinyl; quinolinyl; pyrimidinyl; or isoxazolyl; and n is a number from 2-100. Furthermore, the present invention relates to novel cationic oligomeric azo dyes, compositions thereof, especially comprising other dyes, and to application for hair dying.
摘要翻译： 公开了式（I）的低聚阳离子偶氮染料，其中其盐，异构体，水合物和其它溶剂合物，其中R 1是氢; 可被一个或多个C 1 -C 5烷基，C 1 -C 5 - 烷氧基，羟基或 - （CO）-H取代的C 1 -C 12烷基; - （CO）-C 1 -C 5烷基; 苯基或苯基-C 1 -C 4烷基，其中苯基部分可以被一个或多个C 1 -C 5烷基，C 1 -C 5烷氧基，卤素，-NH 2，单-C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-NO 2，羧基或羟基 ; R2是氢; 或C 1 -C 5烷基; X是C 1 -C 10亚烷基，其可以被一个或多个C 1 -C 5烷基，羟基，C 1 -C 5 - 烷氧基，氨基，单-C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-SH所取代，和/或被一个或多个 更多-O-或-SS-; C5-C10环亚烷基; C5-C12亚芳基 C5-C12亚芳基 - （C1-C10亚烷基）; 可以被一个或多个C 1 -C 5烷基，羟基，C 1 -C 5 - 烷氧基，氨基，单-C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-SH所取代的亚联苯基，和/或被一个或多个-O- ，C 1 -C 4 - 亚烷基，-NR 3 - ， - S-或-SS-; R3是氢; C 1 -C 12烷基; C2-C14烯基; C6-C12芳基; C 6 -C 12芳基-C 1 -C 12烷基; 或C 1 -C 12烷基-C 6 -C 12芳基; Y是阴离子; Z是1,3-噻唑基; 1,2-噻唑基; 1,3-苯并噻唑基; 2,3-苯并噻唑基; 咪唑基; 1,3,4-噻二唑基; 1,3,5-噻二唑基; 1,3,4-三唑基; 吡唑基; 苯并咪唑基; 苯并吡唑基 吡啶基 喹啉基 嘧啶基; 或异恶唑基; n是2-100的数字。 此外，本发明涉及新型阳离子低聚偶氮染料，其组合物，特别是其它染料，以及用于染发的应用。
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公开(公告)号：US07223295B2
公开(公告)日：2007-05-29
申请号：US10846901
申请日：2004-05-13
IPC分类号： D06P1/08
摘要： Process of coloring porous material, which comprises a) applying to the material being colored at least one capped diazonium compound, and b) then causing the capped diazonium compound present on the material to react with the material.
摘要翻译： 着色多孔材料的方法，其包括：a）向被着色为至少一种封盖重氮化合物的材料施加，和b）然后使存在于该材料上的被覆盖的重氮化合物与该材料反应。
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公开(公告)号：US07307155B2
公开(公告)日：2007-12-11
申请号：US10565137
申请日：2004-07-14
申请人： Victor Paul Eliu , Beate Fröhling
发明人： Victor Paul Eliu , Beate Fröhling
CPC分类号： C09B44/16
摘要： The present invention relates to novel the cationic dyes of formula (1) wherein R1 is an unsubstituted or substituted C1-C14 alkyl or an aryl radical; X− is an anion; R3 is an unsubstituted or substituted C1-C14 alkyl, aryl radical, C1-C6 alkoxy, cyanid, nitro or halide; n is 1 or 2; and if n is 1, then R2 is hydrogen, unsubstituted or substituted C1-C14 alkyl; or if n is 2, then R2 is an unsubstituted or substituted C1-C14 alkylen. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, paper, cellulose or polyamides, and preferably human hair
摘要翻译： 本发明涉及新型式（1）的阳离子染料，其中R 1是未取代或取代的C 1 -C 14烷基或 芳基; X 是阴离子; R 3是未取代或取代的C 1 -C 14烷基，芳基，C 1 -C 6烷基， 氰基，硝基或卤素; n为1或2; 并且如果n为1，则R 2为氢，未取代或取代的C 1 -C 14烷基; 或者如果n为2，则R 2为未取代或取代的C 1 -C 14亚烷基。 此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，丝，纸，纤维素或聚酰胺中的用途，以及 优选人发
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公开(公告)号：US07229479B2
公开(公告)日：2007-06-12
申请号：US10525469
申请日：2003-08-26
申请人： Beate Fröhling , Victor Paul Eliu
发明人： Beate Fröhling , Victor Paul Eliu
IPC分类号： A61K7/13
CPC分类号： A61K8/4966 , A61Q5/065 , C07C245/24 , C09B67/0079
摘要： A method of coloring porous material, especially human hair, is described, which method comprises applying to the material being colored, in any desired order successively, or simultaneously, a) at least one capped diazonium compound and b) at least one cationic water-soluble aromatic coupling component, under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
摘要翻译： 描述了多孔材料，特别是人发的着色方法，该方法包括以任何所需顺序连续地或同时施用着色的材料，a）至少一种封端的重氮化合物和b）至少一种阳离子水溶性聚合物， 在最初不发生偶合的条件下，然后使存在于材料上的封端重氮化合物与偶联组分反应的条件下进行。
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公开(公告)号：US07166711B2
公开(公告)日：2007-01-23
申请号：US10783256
申请日：2004-02-20
申请人： Victor Paul Eliu , Beate Fröhling
发明人： Victor Paul Eliu , Beate Fröhling
CPC分类号： C09B69/065 , A61K8/4946 , A61Q5/065 , C09B44/103
摘要： The present invention relates to novel cationic dye of formula (1) wherein R1 and R7 are each independently of the other hydrogen, hydroxyl; unsubstituted or substituted C1–C6alkyl, aryl radical or C114 C6alkoxy; or —NR3R4, wherein R3 and R4 are each independently of the other hydrogen, unsubstituted or substituted aryl radical or C1–C6alkyl, and R2 is hydrogen, hydroxyl, unsubstituted or substituted C1–C6alkyl, aryl radical or C1–C6alkoxy, —NR3R4, or an organic radical of formula (2) wherein R5 is hydrogen, unsubstituted or substituted aryl radical or C1–C6alkyl, and X− is an anion. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, and preferably human hair.
摘要翻译： 本发明涉及式（1）的新型阳离子染料，其中R 1和R 7各自独立地为氢，羟基; 未取代或取代的C 1 -C 6烷基，芳基或C 1〜14 C 6烷氧基; 或-NR 3 R 4，其中R 3和R 4各自独立地为另一个氢，未取代的 或取代的芳基或C 1 -C 6烷基，R 2是氢，羟基，未取代或取代的C 1 -C 6烷基， C 1 -C 6烷基，芳基或C 1 -C 6烷氧基，-NR 3 R 或其中R 5为氢的式（2）的有机基团，未取代或取代的芳基或C 1 -C 3 > 6个烷基，X - 是一个阴离子。 此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，丝，纤维素或聚酰胺，优选人 头发。
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公开(公告)号：US07828858B2
公开(公告)日：2010-11-09
申请号：US11992929
申请日：2006-09-13
IPC分类号： A61Q5/10 , C07D277/26
CPC分类号： A61Q5/10 , A61K8/46 , A61K8/49 , A61K8/492 , A61K8/4926 , A61K8/4946 , A61K8/496 , A61K8/498 , C09B67/0033 , C09B67/0034
摘要： Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译： 公开了硫化染料和包含硫化染料混合物的染色组合物的混合物。 染料混合物可用于染色有机材料，例如角蛋白纤维，优选人发。
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公开(公告)号：US07563289B2
公开(公告)日：2009-07-21
申请号：US11992926
申请日：2006-09-27
申请人： Victor Paul Eliu , Beate Fröhling , Achim Bührer
发明人： Victor Paul Eliu , Beate Fröhling , Achim Bührer
IPC分类号： A61Q5/10 , C07D211/20 , C07D293/00
CPC分类号： C09B23/145 , A61K8/46 , A61Q5/065 , A61Q5/10
摘要： Disclosed are thiol dyes of formula (1), wherein R1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene; C2-C12alkenylene; C5-C10cycloalkylene; C5-C10arylene; or C5-C10arylene-C1-C10alkylene; Y is the residue of an organic dye which corresponds to the formula (1a), wherein R2 is hydrogen; or C1-C5alkyl; R3 is a radical of formula (1a1): (1a2); or (1a3); or R2 and R3 together with the linking carbon atom C form a 6 to 10 membered carbocyclic ring which may optionally be a condensated aromatic system and may contain one or more than one hetero atom; and R4, R5 and R6 independently form each other are hydrogen, or C1-C5alkyl; Z is H; or a thio ester group of formula (1b), wherein A is O; S; or N—R9; B is —OR7; —NR7R8, or —SR7; and A is O; S; or N—R9; B is —OR7; —NR7R8, or —SR7; and R7, R8 and R9, independently from each other are hydrogen; C1-C12alkyl C6-C12aryl; or C6-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译： 公开了式（1）的硫醇染料，其中R 1是氢; C 1 -C 12烷基; 或苯基-C 1 -C 4烷基; X是C 1 -C 12亚烷基; C 2 -C 12亚烯基; C5-C10环亚烷基; C5-C10亚芳基 或C 5 -C 10亚芳基-C 1 -C 10亚烷基; Y是对应于式（1a）的有机染料的残基，其中R 2是氢; 或C 1 -C 5烷基; R3是式（1a1）的基团：（1a2）; 或（1a3）; 或R2和R3与连接碳原子C一起形成6至10元碳环，其可以任选地是缩合的芳族体系，并且可以含有一个或多于一个的杂原子; 和R 4，R 5和R 6彼此独立地形成氢或C 1 -C 5烷基; Z是H; 或式（1b）的硫酯基，其中A为O; S; 或N-R9; B为-OR7; -NR7R8或-SR7; A是O; S; 或N-R9; B为-OR7; -NR7R8或-SR7; 和R 7，R 8和R 9彼此独立地是氢; C 1 -C 12烷基C 6 -C 12芳基; 或C 6 -C 12芳基-C 1 -C 12烷基。 该化合物可用于染色有机材料，例如角蛋白纤维，优选人发。
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