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公开(公告)号：US07931696B2
公开(公告)日：2011-04-26
申请号：US12520887
申请日：2008-01-22
IPC分类号： A61Q5/10 , C07D333/00
CPC分类号： A61Q5/065 , A61K8/4986 , A61K2800/94 , C09B44/101 , C09B44/107 , C09B55/003
摘要： Disclosed are dyes of formula wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine, perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; and Q is defined herein.
摘要翻译： 公开了下式的染料，其中D是蒽醌，吖啶，偶氮，偶氮甲碱，肼甲基，苯并二呋喃酮，香豆素，二酮吡咯并吡咯，二氧杂环己烷，二苯基甲烷，甲ane烷，靛类，靛酚，萘二甲酰亚胺，萘醌，硝基芳基，部花青，次甲基，恶嗪， ，苝，芘醌，酞菁，吩嗪，醌亚胺，喹吖啶酮，喹诺酮，芪，苯乙烯基，三苯甲烷，呫吨，噻嗪染料和噻吨染料; 并且Q在本文中定义。
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2.发明授权公开(公告)号：US07476260B2
公开(公告)日：2009-01-13
申请号：US11547571
申请日：2005-03-29
CPC分类号： C09B44/16 , A61K8/49 , A61K8/4926 , A61K8/4946 , A61K2800/94 , A61Q5/10 , C09B44/20 , C09B49/00
摘要： Formula (I) wherein R1 and R2 each independently from each other are a residue of an organic dye: Y1 and Y2 each independently from each other are unsubstituted or substituted, straightchain or branched, interrupted or uninterrupted —C1-C10alkylene-; —C5-C10cycloalkylene-; C5-C10arylene; or —C5-C10arylene-(C1-C10alkylene)-; Z1 and Z2 independently from each other are Formula (II) are each independently from each other hydrogen; or unsubstituted or substituted, straight-chain or branched, mono-cyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); r, q and n independently from each other are 0 or 1, if n is 0, Z3 is hydrogen; and if n is 1, Z3 is —S—: with the proviso that the method does not comprise treating the fiber with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1). Further, the present invention relates to novel disulfid compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.
摘要翻译： 式（I）其中R 1和R 2各自独立地是有机染料的残基：Y 1和Y 2各自独立地是未取代或取代的，直链或支链的，间断的或不间断的-C 1 -C 10亚烷基 - ; -C 5 -C 10环亚烷基 - C5-C10亚芳基 或-C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - ; Z 1和Z 2彼此独立地是式（II）各自独立地为氢; 或未取代或取代的直链或支链的单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; r，q和n彼此独立地为0或1，如果n为0，则Z 3为氢; 并且如果n为1，则Z 3为-S-，条件是该方法不包括用蛋白质二硫代异构酶类型的EC处理纤维（EC 5.3.4.1）。 此外，本发明涉及新的二硫化物，其组合物，特别是其它染料，以及其制备方法。
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公开(公告)号：US07785375B2
公开(公告)日：2010-08-31
申请号：US11922660
申请日：2006-06-21
IPC分类号： A61Q5/10 , C07D279/00
CPC分类号： A61Q5/10 , A61K8/49 , C07D513/04 , C09B23/0091
摘要： Disclosed is a method of dyeing keratin-containing fibers comprising treating the fiber with at least one compound of formula (1), wherein R1, R2, R3, R4 independently from each other are hydrogen; hydroxy; —S—H; —S—C1-C12alkyl; halogen; C1-C12alkyl or C1-C12alkoxy, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy, —(CO)—H or —(CO)—C1-C5alkyl; —NR5R6; —NO2; —(CO)H or (CO)—C1-C5alkyl; C6-C12aryl, C6-C12aryl-C1-C4alkyl or C6-C12aryl-C1-C4alkoxy, wherein the aryl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, —(CO)—H or —(CO)—C1-C5alkyl; R5 and R6 independently from each other are hydrogen; hydroxy; C1-C12alkyl; hydroxy-C1-C12alkyl; —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C5alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; and An is an anion. Furthermore, the present invention relates to novel heterocyclic compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation and application to hair dying.
摘要翻译： 公开了一种染色含角蛋白纤维的方法，包括用至少一种式（1）化合物处理纤维，其中R 1，R 2，R 3，R 4彼此独立地为氢; 羟基; -S-H; -S-C 1 -C 12烷基; 卤素; C 1 -C 12烷基或C 1 -C 12烷氧基，其可以被一个或多个C 1 -C 5烷基，C 1 -C 5 - 烷氧基，羟基， - （CO）-H或 - （CO）-C 1 -C 5烷基取代; -NR5R6; -NO2; - （CO）H或（CO）-C 1 -C 5烷基; C 1 -C 12芳基，C 6 -C 12芳基-C 1 -C 4烷基或C 6 -C 12芳基-C 1 -C 4烷氧基，其中芳基部分可被一个或多个C 1 -C 5烷基，C 1 -C 5烷氧基， - （CO）-H或 - （CO） -C 1 -C 5烷基; R5和R6彼此独立地是氢; 羟基; C 1 -C 12烷基; 羟基-C 1 -C 12烷基; - （CO）-H; - （CO）-C 1 -C 5烷基; 苯基或苯基-C 1 -C 5烷基，其中苯基部分可被一个或多个C 1 -C 5烷基，C 1 -C 5烷氧基，卤素，-NH 2，单C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-NO 2，羧基或羟基 ; 而An是阴离子。 此外，本发明涉及新颖的杂环化合物，其组合物，特别是其它染料，以及其制备和应用于染发的方法。
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公开(公告)号：US20100000029A1
公开(公告)日：2010-01-07
申请号：US12310118
申请日：2007-08-08
IPC分类号： A61K8/49 , C09B29/036
CPC分类号： C09B44/16 , A61K8/4946 , A61Q5/065 , A61Q5/10 , C09B49/00 , C09B55/003 , C09B56/18
摘要： Disclosed are thiol dyes of formula (1) wherein L1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, or C5-C10arylene-C1-C10alkylene, which may by interrupted by —O—, —NH—, —S—, —CO—, o-SO2—; Y is the residue of an organic dye Z is a group of formula (1b) or —C≡N; wherein A is O; S; or N-L2; B is L3; —OL3; —NL3L4; or —SL3; and L2, L3 and L4, independently from other are hydrogen; C1-C12alkyl; C5-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译： 公开了式（1）的硫醇染料，其中L 1是氢; C 1 -C 12烷基; 或苯基-C 1 -C 4烷基; X是C 1 -C 12亚烷基，C 2 -C 12亚烯基，C 5 -C 10亚环烷基，C 5 -C 10亚芳基或C 5 -C 10亚芳基-C 1 -C 10亚烷基，其可以被-O - ， - NH - ， - S-， - CO- SO2-; Y是有机染料的残基Z是式（1b）或-C≡N的基团; 其中A为O; S; 或N-L2; B是L3; -OL3; -NL3L4; 或-SL3; 和L2，L3和L4独立地是氢; C 1 -C 12烷基; C5-C12芳基-C1-C12烷基。 该化合物可用于染色有机材料，例如角蛋白纤维，优选人发。
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公开(公告)号：US20100000028A1
公开(公告)日：2010-01-07
申请号：US11922069
申请日：2006-06-07
IPC分类号： A61K8/49 , C07D401/12 , A61Q5/10
CPC分类号： C09B23/14 , A61K8/4926 , A61Q5/10 , C09B23/145 , C09B49/00
摘要： Disclosed are styryl sulfide dyes of formula (1), wherein R1, R′1, R2, R′2, R3 and R′3, independently from each other are hydrogen; C1-C20alkyl or C1-C20alkoxy, which may be substituted by one or more C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2 or hydroxy; C3-C6cycloalkyl; —C(O)H; —C(O)—C1-C5alkyl; halogen; NO2; OH; phenyl, which may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2 or hydroxy; or a radical of formula —NR4R5, wherein R4 and R5 independently from each other are hydrogen; C1-C12alkyl, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy or —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C4alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —N2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; W1, W′1, W2, W′2, W3, W′3, W4 or W′4, independently from each other are —CH— or —N+—; wherein only one of W1/W′1, W2/W′2, W3/W′3, W4/W4′ is —N+; and the bivalent radical -Q-Z-Y—S—S—Y′-Z′-Q′- is bonded to W1 or W2 and W′1 or W′2 respectively; Y1 and Y2 independently from each other are C1-C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene); Q and Q′ independently from each other are the direct bond; or —C(O)—; —C(O)O—; —OCO—; —N(R6)—; formula (AA); —C(O)N(R6)—; —(R6)NC(O)—; —O—; —S—; —S(O)—; or —S(O)2—; and R6 and R7 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl). Further, the present invention relates to novel styryl sulfide compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.
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公开(公告)号：US20090300857A1
公开(公告)日：2009-12-10
申请号：US11990813
申请日：2006-08-21
IPC分类号： A61K8/46 , C09B29/036 , C07D213/53 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/4926 , C09B23/145 , C09B26/04 , C09B44/107
摘要： Disclosed are thiol dyes of formula (1), wherein R1, R2, R3, R4 and R5 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); A is a residue of an organic dye; and Y1 is the direct bond; C1-C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene). The compounds are used to dye hair with or without reducing agents. Furthermore, the present invention relates to compositions comprising thiol dyes of formula (1) and to process for the preparation of theses compounds.
摘要翻译： 公开了式（1）的硫醇染料，其中R 1，R 2，R 3，R 4和R 5彼此独立地为氢; 直链或支链的单环或多环，中断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; A是有机染料的残留物; Y1是直接键; C1-C10亚烷基; C5-C10环亚烷基; C5-C12亚芳基 或C 5 -C 12亚芳基 - （C 1 -C 10亚烷基）。 这些化合物用于染发有或没有还原剂的头发。 此外，本发明涉及包含式（1）的硫醇染料和用于制备这些化合物的方法的组合物。
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公开(公告)号：US07811335B2
公开(公告)日：2010-10-12
申请号：US11922069
申请日：2006-06-07
IPC分类号： A61Q5/10 , C07C321/00
CPC分类号： C09B23/14 , A61K8/4926 , A61Q5/10 , C09B23/145 , C09B49/00
摘要： Disclosed are composition and method for dyeing keratin-containing fibers comprising or utilizing styryl sulfide dyes of formula (1), their salts, isomers, hydrates and other solvates, wherein R1, R′1, R2, R′2, R3, R′3, W1, W′1, W2, W′2, W3, W′3, W4, W′4, Q, Q′, Y1 and Y2 are defined in claims and disclosure.
摘要翻译： 公开了包含或利用式（1）的苯乙烯基硫化物染料，其盐，异构体，水合物和其它溶剂化物的含角蛋白的纤维的组合物和方法，其中R 1，R'1，R 2，R'2，R 3，R' 在权利要求和公开中限定了3，W1，W'1，W2，W'2，W3，W'3，W4，W'4，Q，Q'，Y1和Y2。
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公开(公告)号：US07803197B2
公开(公告)日：2010-09-28
申请号：US12310118
申请日：2007-08-08
IPC分类号： A61Q5/10 , C07D471/00
CPC分类号： C09B44/16 , A61K8/4946 , A61Q5/065 , A61Q5/10 , C09B49/00 , C09B55/003 , C09B56/18
摘要： Disclosed are thiol dyes of formula (1) wherein L1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, or C5-C10arylene-C1-C10alkylene, which may by interrupted by —O—, —NH—, —S—, —CO—, o-SO2—; Y is the residue of an organic dye Z is a group of formula (1b) or —C≡N; wherein A is O; S; or N-L2; B is L3; —OL3; —NL3L4; or —SL3; and L2, L3 and L4, independently from other are hydrogen; C1-C12alkyl; C5-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译： 公开了式（1）的硫醇染料，其中L 1是氢; C 1 -C 12烷基; 或苯基-C 1 -C 4烷基; X是C 1 -C 12亚烷基，C 2 -C 12亚烯基，C 5 -C 10亚环烷基，C 5 -C 10亚芳基或C 5 -C 10亚芳基-C 1 -C 10亚烷基，其可以被-O - ， - NH - ， - S-， - CO- SO2-; Y是有机染料的残基Z是式（1b）或-C≡N的基团; 其中A为O; S; 或N-L2; B是L3; -OL3; -NL3L4; 或-SL3; 和L2，L3和L4独立地是氢; C 1 -C 12烷基; C5-C12芳基-C1-C12烷基。 该化合物可用于染色有机材料，例如角蛋白纤维，优选人发。
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公开(公告)号：US07771490B2
公开(公告)日：2010-08-10
申请号：US11990813
申请日：2006-08-21
IPC分类号： A61Q5/10 , C07C317/00
CPC分类号： A61Q5/10 , A61K8/4926 , C09B23/145 , C09B26/04 , C09B44/107
摘要： Disclosed are thiol dyes of formula (I), wherein R1, R2, R3, R4 and R5 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); A is a residue of an organic dye; and Y1 is the direct bond; C1C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene). The compounds are used to dye hair with or without reducing agents. Furthermore, the present invention relates to compositions comprising thiol dyes of formula (I) and to process for the preparation of theses compounds.
摘要翻译： 公开了式（I）的硫醇染料，其中R 1，R 2，R 3，R 4和R 5彼此独立地为氢; 直链或支链的单环或多环，中断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; A是有机染料的残留物; Y1是直接键; C1C10亚烷基; C5-C10环亚烷基; C5-C12亚芳基 或C 5 -C 12亚芳基 - （C 1 -C 10亚烷基）。 这些化合物用于染发有或没有还原剂的头发。 此外，本发明涉及包含式（I）的硫醇染料和用于制备这些化合物的方法的组合物。
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公开(公告)号：US07704284B2
公开(公告)日：2010-04-27
申请号：US11992704
申请日：2006-09-25
IPC分类号： A61Q5/10 , C07D311/82
CPC分类号： C09B49/126 , A61K8/49 , A61K8/498 , A61Q5/10 , C09B11/24 , C09B11/245
摘要： Disclosed are compounds of formula (1a), wherein R1 is N+R8R9; R8 and/or R9 independently from each other are hydrogen; C1-C12alkyl; or phenyl-C1-C4-alkyl; or R8 and/or R9 are a bivalent C3-C6alkylene radical which is linked to the carbon atoms C1 or C2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R2 is NR10R11; or OR10; R10 and R11, independently from each other are hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; or R10 and/or R11 are a bivalent C3-C6alkylene radical which is linked to the carbon atoms C3 or C4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16-membered carbocyclic ring; or R10 and R11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R3, R4, R5, R6 and R7 independently form each other are hydrogen; C1-C12alkyl; halogen; NR12R13; or a radical of formula (1a); R12 and R13 independently from each other are hydrogen; C1-C12alkyl; phenyl-C1-C4alkyl; or a radical of formula (1a2); V is —O—; Or —NR15; R14, R15 R-16 and R17 independently from each other are hydrogen; or C1-C5alkyl; and Hal is a halogen atom; and wherein at least one of R3, R4, R5, R6 and R7 is hydrogen. The compounds are useful for dyeing of keratin-containing fibers with or without reducing agents.
摘要翻译： 公开了式（1a）的化合物，其中R 1是N + R 8 R 9; R 8和/或R 9彼此独立地为氢; C 1 -C 12烷基; 或苯基-C 1 -C 4 - 烷基; 或R 8和/或R 9为分别与碳原子C 1或C 2连接并与连接氮原子一起形成6至16元碳环的二价C 3 -C 6亚烷基; R2为NR10R11; 或OR10; R 10和R 11彼此独立地是氢; C 1 -C 12烷基; 或苯基-C 1 -C 4烷基; 或R 10和/或R 11分别与碳原子C3或C4连接并与连接的氮原子或氧原子一起形成6至16元碳环的二价C 3 -C 6亚烷基; 或R 10和R 11与连接氮原子一起形成4至8元碳环; R 3，R 4，R 5，R 6和R 7彼此独立地形成氢; C 1 -C 12烷基; 卤素; NR12R13; 或式（1a）的基团; R 12和R 13彼此独立地是氢; C 1 -C 12烷基; 苯基-C 1 -C 4烷基; 或式（1a2）的基团; V是-O-; 或-NR 15; R 14，R 15 R 16和R 17彼此独立地是氢; 或C 1 -C 5烷基; 而Hal是卤素原子; 并且其中R 3，R 4，R 5，R 6和R 7中的至少一个是氢。 该化合物可用于用或不含还原剂染色含角蛋白的纤维。
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