摘要:
The present invention relates to novel radiation-curing powder coating binders containing maleic and/or fumaric acid esters and one or more amorphous or partially crystalline resins containing at least one group that reacts with ethylenically unsaturated compounds under the action of actinic radiation to form a polymer. The binders have a glass transition temperature ranging from 30 to 90° C. The binders can be used as a constituent in coating compositions.
摘要:
The invention relates to the use of special mixtures of at least two polycarboxylic acids as crosslinker components for thermally curing powder-lacquer binding agents having groups that are capable of reacting with carboxyl groups. The mixtures include at least two polycarboxylic acids each melting above 95° C. and having up to 20 carbon atoms and consist of at least 5 wt. %, of the polycarboxylic acid with the lowest melting point and at least 10 wt. %, of the polycarboxylic acid with the highest melting point of all polycarboxylic acids present in the mixture to at least 5 wt. %. Additionally, the polycarboxylic acid mixture is a solid below 40° C. and a liquid above 160° C.
摘要:
The present invention relates to powder coating binders containing polyurethanes having (meth)acryloyl groups which are applied onto a substrate, fused with heat and cured by electromagnetic radiation and to a process for preparing the same.
摘要:
The present invention relates to a process for preparing urethanes containing (meth)acryloyl groups that are suitable as binders for powder coatings by reacting a polyisocyanate component with a hydroxyl group-containing component that contains at least one compound additionally containing (meth)acryloyl groups in a melt of compounds containing (meth)acryloyl groups, which are crystalline in the solid state and have a melting point of 30 to 100° C. and a dynamic viscosity at 111° C. of less than 10 Pa·s, at elevated temperature until the NCO content has dropped below 0.5 wt. %. The present invention also relates to the use of these urethanes as binders for powder coating compositions for coating substrates made of wood, metal, plastics or mineral substances, which may have been primed.
摘要:
The invention relates to a process for the electrostatic lacquering of non-conductive surfaces. For this purpose, a layer of a conductive organic polymer from the class of the polypyrroles, polyanilines or polythiophenes is applied to the surface and this layer is then electrostatically lacquered.
摘要:
Powder coating binders having a glass temperature of ≧35° C. containing at least one polymer and one or more radiation-curing reactive thinners, a process for the production of these powder coating binders and their use as a component of powder coatings.
摘要:
A process for preparing polyisocyanate-modified polycarboxylic acids by conversion of anhydride-group-free polycarboxylic acids with isocyanate-functional compounds. The process includes reacting A) an anhydride-group-free polycarboxylic-acid component with B) an isocyanate-functional component having an (average) isocyanate functionality of at least 1.8, at an equivalent ratio of carboxylic acid groups to isocyanate groups of from 1.2:1 to 120:1. The polyisocyanate-modified polycarboxylic acids are solid below 40° C. and liquid above 130° C., and have an average carboxylic acid functionality of at least 1.8, a content of free carboxylic acid groups of from 4.0 wt. % to 80.0 wt. % and a content of amide groups of from 0.4 wt. % to 32.5 wt. %.
摘要:
Polyaddition compounds containing uretdione groups prepared by reacting uretdione polyisocyanates formed from diisocyanates having exclusively secondary- and/or tertiary-attached isocyanate groups with a molar fraction of isocyanurate structures, based on the sum of uretdione groups and isocyanurate groups, of not more than 10%, with compounds reactive towards isocyanates. The polyaddition compounds can be use as a starting component in the preparation of polyurethane plastics, in particular as crosslinkers for heat-crosslinkable powder coating materials. The compounds may be used as starting components in the preparation of moldings and shaped parts, and as starting components in the preparation of coating materials and coatings.
摘要:
Powder coating binders having a glass temperature of ≧35° C. containing at least one polymer and one or more radiation-curing reactive thinners, a process for the production of these powder coating binders and their use as a component of powder coatings.
摘要:
A titanium dioxide composition useful as the opacifier agent for vitreous enamels and fusion enamels comprises TiO.sub.2 predominantly in the form of isometric primary particles from 0.5 to 5.0 .mu.m in size, which are aggregated to predominantly spherolithic particles 1 to 100 .mu.m in diameter, with a BET surface of 1 to 4.5 m.sup.2 /g and an apparent density of 0.2 to 1.3 kg/1, is prepared by subjecting titanium dioxide hydrate having a BET surface of from 50 to 500 m.sup.2 /g to accelerated calcination at temperatures of 800.degree. to 1600.degree. C.