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43 条记录 (耗时 0.021 秒)

    Decolorization of norbornadiene dimers
    11.
    发明授权
    Decolorization of norbornadiene dimers 失效
    降冰片二烯二聚体脱色

    公开(公告)号：US4229612A

    公开(公告)日：1980-10-21

    申请号：US7112

    申请日：1979-01-29

    申请人： Lewis W. Hall, Jr. ,  David L. Kerr ,  Elmer J. Hollstein ,  Harry K. Myers, Jr. ,  Abraham Schneider

    发明人： Lewis W. Hall, Jr. ,  David L. Kerr ,  Elmer J. Hollstein ,  Harry K. Myers, Jr. ,  Abraham Schneider

    IPC分类号： C07C1/00 ,  C07C5/29 ,  C07C7/12 ,  C07C13/64 ,  C07C67/00 ,  C07C13/28

    CPC分类号： C07C13/64 ,  C07C5/29 ,  C07C7/12

    摘要： The removal of color bodies from an olefinic or saturated endo-endo hexacyclic homodimer of norbornadiene or mixtures thereof is accomplished by the use of a serpentine clay. Also acid bentonite clay or a montmorillonite clay can be used to remove the color bodies from the saturated dimer. The saturated dimer has a high density and a high heat of combustion making it useful as a missile fuel. Removal of the color bodies avoids possible catalyst poisoning in the hydrogenation of the olefinic to the saturated dimer. Also removal of the color bodies from the saturated dimer eliminates the possible problem of a material precipitating out on engine turbine blades and causing maintenance or operational problems.

    摘要翻译： 通过使用蛇纹石粘土来实现从降冰片二烯的烯属或饱和内六角六环同系二聚体或其混合物中去除着色体。 酸性膨润土或蒙脱石粘土也可用于从饱和二聚体中除去颜色体。 饱和二聚体具有高密度和高的燃烧热，使其可用作导弹燃料。 去除颜色体可以避免在烯烃氢化成饱和二聚体时催化剂中毒。 从饱和二聚体中去除颜色体也消除了在发动机涡轮叶片上析出物质并导致维护或操作问题的可能问题。

    Catalytic codimerization of norbornadiene with an acrylic acid ester
    17.
    发明授权
    Catalytic codimerization of norbornadiene with an acrylic acid ester 失效
    降冰片二烯与丙烯酸酯的催化同分异构

    公开(公告)号：US4139715A

    公开(公告)日：1979-02-13

    申请号：US812207

    申请日：1977-07-01

    申请人： Harry K. Myers, Jr. ,  Abraham Schneider

    发明人： Harry K. Myers, Jr. ,  Abraham Schneider

    IPC分类号： C07C69/74

    CPC分类号： C07C67/347 ,  C07C2103/86

    摘要： Norbornadiene and an acrylic acid ester, e.g. methyl acrylate, are catalytically codimerized in the presence of a three-component homogeneous catalytic system consisting of nickel acetylacetonate, an alkyl aluminum chloride and 1,2-bisdiphenylphosphino ethane. The resulting codimer can be used as a precursor for missile fuel. The ester portion of the acrylic acid ester is the radical RCH.sub.2 O-- wherein the R is an H or an alkyl containing up to 10 carbon atoms.

    摘要翻译： 降冰片二烯和丙烯酸酯，例如 丙烯酸甲酯在由乙酰丙酮镍，烷基氯化铝和1,2-双二苯基膦基乙烷组成的三组分均相催化体系的存在下进行催化共聚。 所得到的同源二聚体可用作导弹燃料的前体。 丙烯酸酯的酯部分是自由基RCH2O-，其中R是H或含有至多10个碳原子的烷基。

    Catalytic dimerization of norbornadiene to Binor-S
    18.
    发明授权
    Catalytic dimerization of norbornadiene to Binor-S 失效
    降冰片二烯催化二聚化成Binor-S

    公开(公告)号：US4031150A

    公开(公告)日：1977-06-21

    申请号：US631978

    申请日：1975-11-14

    申请人： George Suld ,  Abraham Schneider ,  Harry K. Myers, Jr.

    发明人： George Suld ,  Abraham Schneider ,  Harry K. Myers, Jr.

    IPC分类号： C07C2/42 ,  C07C13/28 ,  B01J31/12 ,  C06B43/00

    CPC分类号： C07C2/42 ,  C07C2103/90 ,  C07C2531/14 ,  C07C2531/24

    摘要： Binor-S is prepared by the dimerization of norbornadiene (bicyclo[2.2.1]hepta-2,5-diene) at an excellent conversion and an excellent selectivity using an effective amount of a two component catalytic system of tris(triphenylphosphine)rhodium chloride and diethylaluminum chloride or ethylaluminum dichloride or aluminum ethylsesquichloride. The range of mole ratio of norbornadiene to tris(triphenylphosphine)rhodium chloride is between from about 100 to about 1000 and the range of mole ratio of one of the aluminum chlorides to the rhodium chloride is between from about 0.5 to about 100. The reaction rate is rapid. Binor-S can be used as precursor for hydrocarbons having utility for either jet or rocket propulsion.

    摘要翻译： 通过使用有效量的三（三苯基膦）氯化铑的双组分催化体系，以优异的转化率和优异的选择性，通过降冰片二烯（双环[2.2.1]庚-2,5-二烯）的二聚制备二萘嵌-S 和二乙基氯化铝或乙基二氯化铝或乙基三氯化铝。 降冰片二烯与三（三苯基膦）氯化铑的摩尔比范围为约100至约1000，氯化铝之一与氯化铑的摩尔比范围为约0.5至约100.反应速率 很快 Binor-S可用作用于喷射或火箭推进的碳氢化合物的前体。

    Dimerization of norbornadiene to a mixture of exo-endo and endo-endo hexacyclic dimers
    19.
    发明授权
    Dimerization of norbornadiene to a mixture of exo-endo and endo-endo hexacyclic dimers 失效
    降冰片二烯二异氰酸酯二异氰酸酯二异氰酸酯二异氰酸酯二异氰酸酯

    公开(公告)号：US4275254A

    公开(公告)日：1981-06-23

    申请号：US639742

    申请日：1975-12-11

    申请人： Abraham Schneider ,  Harry K. Myers, Jr. ,  George Suld

    发明人： Abraham Schneider ,  Harry K. Myers, Jr. ,  George Suld

    IPC分类号： C07C2/52 ,  C10L1/04

    CPC分类号： C10L1/04 ,  C07C2/52 ,  C07C2103/90 ,  C07C2531/14 ,  C07C2531/22

    摘要： Norbornadiene [bicyclo (2.2.1) heptadiene-2,5] is dimerized to a mixture of mainly the exo-endo stereoisomer of the hexacylic dimer of norbornadiene at both an excellent selectivity and conversion using an effective amount of a two component catalytic system of rhodium acetylacetonate and diethylaluminum chloride or ethylaluminum dichloride or aluminum ethylsesquichloride. The mixture also contains the endo-endo stereoisomer and some trimer. After hydrogenation a suitable mixture of the exo-endo and endo-endo dimers can be used as a component of high energy fuel.

    摘要翻译： 将降冰片二烯[双环（2.2.1）庚二烯-2,5]二聚化为主要是降冰片二烯的六酰基二聚体的外部立体异构体的混合物，两者都具有优异的选择性和转化率，使用有效量的双组分催化体系 乙酰丙酮铑和二乙基氯化铝或乙基二氯化铝或乙基三氯化铝。 混合物还含有内切立体异构体和一些三聚体。 在氢化之后，可以将外端和内端二聚体的合适混合物用作高能燃料的组分。