Abstract:
Molded iron catalysts which contain metallic iron particles, obtained from anisometric iron oxide particles by contact with hydrogen at .ltoreq.500.degree. C., and a lubricant, are prepared.
Abstract:
Caprolactam is recovered from oligomers and/or polymers of caprolactam by cleavage of oligomers and/or polymers of caprolactam and subsequent working up by distillation of the caprolactam obtained in the cleavage, by a process including (a) cleaving oligomers and/or polymers of caprolactam to obtain an aqueous reaction mixture which contains caprolactam, (b) removing water from the reaction mixture obtained under (a) to obtain a residue, (c) distilling the residue obtained under (b) in an acidic medium and (d) then distilling the distillate in an alkaline medium to obtain caprolactam, or (c') distilling the residue obtained under (b) in an alkaline medium and (d') then distilling the distillate in an acidic medium to obtain caprolactam.
Abstract:
A platinum-on-graphite catalyst having a platinum content of from 0.01 to 5% w/w, wherein the graphite support has an apparent density of from 1.7 to 2.2 g/ml and the use thereof as a hydrogenation catalyst.
Abstract:
A molded iron catalyst material which has an indentation hardness of from 850 to 1500 kp/cm.sup.2 and contains metallic iron particles, obtained from iron oxide particles by contact with hydrogen at less than 500.degree. C., and a lubricant, its preparation and its use.
Abstract translation:一种模压铁催化剂材料,其压痕硬度为850至1500kp / cm 2,并含有通过在低于500℃与氢接触的氧化铁颗粒获得的金属铁颗粒,以及润滑剂及其制备及其用途 。
Abstract:
The invention relates to: A) a continuous method for producing a lightweight sandwich panel having an upper and a lower cover layer made of pressed wood chips glued to one another, as well as an intermediate hard foam layer which is thick in relation to a cover layer, arranged between the cover layers and fixedly connected thereto, the method comprising the following steps: 1) providing a scattered layer of glue-coated woodchips; 2) pressing this layer and bonding the wood chips under pressure and temperature conditions typical of conventional chipboard production such that a high vapour pressure is built up in the centre between the cover layers; 3) relieving the pressure on the chipboard by moving the pressing surfaces away from one another, whereby the chipboard tears open in the centre due to the built-up vapour pressure and divides into two cover layers of equal thickness; 4) moving the cover layers apart such that an intermediate layer can be inserted; 5) introducing a hard foam system that can be foamed and cured to form a hard foam between the cover layers; 6) bringing the cover layers together to the nominal thickness of the lightweight sandwich panel to be produced and holding the pressure until the intermediate layer has finished reacting; and 7) finishing the lightweight sandwich panel. B) The invention further relates to a lightweight sandwich panel producible according to the method described in A), with a transition zone created by the uneven portions of the cover layers on the inner side, which are filled with the polyurethane hard foam.
Abstract:
A hydrogenation catalyst, obtainable by carrying out essentially the following steps:(a) treatment of a platinum metal salt with finely divided sulfur followed by(b) reduction of the platinum metal salt to metallic platinum metal.
Abstract:
The preparation of cyclohexene oxide, cyclohexanol and cyclohexanone involvesa) oxidizing cyclohexane using a gas containing molecular oxygen to form cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone,b) jointly separating the mixture from a) and c) by distillation, andc) reaction of the cyclohexyl hydroperoxide fraction from b) with cyclohexene in the presence of a transition-metal compound from group 4 to 6, forming cyclohexene oxide, and separating the product mixture in b).
Abstract:
Caprolactam is purified continuously by passing a 75-95% strength by weight aqueous caprolactam solution together with hydrogen at 50.degree.-95.degree. C. and 1.5-100 bar upward through a fixed-bed supported palladium or nickel catalyst in a tubular zone while maintaining a residence time of from 10 to 100 min.
Abstract:
5-Membered, 6-membered or 7-membered cyclic imines are prepared by hydrogenating a C.sub.2 -C.sub.4 -alkanedinitrile in the liquid phase, at from 180.degree. to 300.degree. C. and under superatmospheric pressure, in the presence of a catalyst, by a process in which an iron catalyst obtained by reduction of an iron oxide with hydrogen at .ltoreq.500.degree. C. is used.