公开(公告)号：US20110089380A1

公开(公告)日：2011-04-21

申请号：US12679387

申请日：2008-09-22

Applicant: Jan C. Hummelen ,  Floris Berend Kooistra ,  David F. Kronholm

Inventor： Jan C. Hummelen ,  Floris Berend Kooistra ,  David F. Kronholm

IPC: H01B1/12 ,  C07C69/712 ,  C07C69/616 ,  B82Y30/00

CPC classification number: H01L51/0047 ,  B82Y10/00 ,  H01L51/4253 ,  Y02E10/549

Abstract: One aspect of the invention relates to compositions comprising one or more fullerene derivatives that comprise one or more covalent addends. In certain embodiments, the fullerene derivatives are selected from the group consisting of methanofullerene derivatives, Prato adduct fullerene derivatives, Diels-Alder fullerene derivatives, diazoline fullerene derivatives, Bingel fullerene derivatives, ketolactam fullerene derivatives, and azafulleroid fullerene derivatives. In certain embodiments, the fullerenes are C60 or C70 or a mixture thereof. The invention also relates to semiconductors, photodiodes, solar cells, photodectectors, and transistors comprising one or more fullerene derivatives that comprise one or more covalent addends.

Abstract translation: 本发明的一个方面涉及包含一种或多种包含一种或多种共价加成元素的富勒烯衍生物的组合物。 在某些实施方案中，富勒烯衍生物选自甲基富勒烯衍生物，Prato加合物富勒烯衍生物，Diels-Alder富勒烯衍生物，二唑啉富勒烯衍生物，Bingel富勒烯衍生物，酮内酰胺富勒烯衍生物和azafulleroid富勒烯衍生物。 在某些实施方案中，富勒烯是C60或C70或其混合物。 本发明还涉及包含一种或多种包含一种或多种共价加成元素的富勒烯衍生物的半导体，光电二极管，太阳能电池，光电探测器和晶体管。

公开(公告)号：US08580810B2

公开(公告)日：2013-11-12

申请号：US12516992

申请日：2007-11-29

Applicant: David F. Kronholm ,  Alexander B. Sieval ,  Jan C. Hummelen

Inventor： David F. Kronholm ,  Alexander B. Sieval ,  Jan C. Hummelen

IPC: A61K31/44 ,  C07D221/02 ,  C07D221/04

CPC classification number: C07D221/18 ,  A61K8/4926 ,  A61K2800/522 ,  A61Q19/00 ,  A61Q19/004 ,  C07D471/06

Abstract: The present invention relates to compositions and methods of using free radical scavengers with reduced 1O2 generation. In certain embodiments, these compositions and methods of use relate to fullerene-derived ketolactams and fullerene-derived keto lactam derivatives, fullerene derivatives, and/or fullerenes. In yet other embodiments, the invention relates to cosmetic or dermatological compositions comprising said free radical scavengers with reduced 1O2 generation.

Abstract translation: 本发明涉及使用还原的一氧化二氮的自由基清除剂的组合物和方法。 在某些实施方案中，这些组合物和使用方法涉及富勒烯衍生的酮内酰胺和富勒烯衍生的酮内酰胺衍生物，富勒烯衍生物和/或富勒烯。 在其它实施方案中，本发明涉及化妆品或皮肤病学组合物，其包含具有降低的1O 2代的所述自由基清除剂。

公开(公告)号：US20120043507A1

公开(公告)日：2012-02-23

申请号：US13218757

申请日：2011-08-26

Applicant: DAVID F. KRONHOLM ,  Jan C. Hummelen ,  Alexander B. Sieval ,  Patrick Van't Hof

Inventor： DAVID F. KRONHOLM ,  Jan C. Hummelen ,  Alexander B. Sieval ,  Patrick Van't Hof

IPC: H01B1/12 ,  B82Y99/00

CPC classification number: H01L51/0047 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/152 ,  H01L51/0558 ,  H01L51/4253 ,  Y02E10/549

Abstract: Disclosed are compositions of mixed fullerene derivatives with utility in organic semiconductors, and methods of making and using such compositions. In certain embodiments, the present invention relates to compositions of mixed fullerene derivatives further comprising one or more additional fullerene-based components within specified ranges. In certain other embodiments, the invention relates to methods of producing mixed fullerene derivatives of a specific composition from mixed fullerene starting materials, or pure fullerene derivatives of a specific composition from mixed fullerene derivatives. In yet other embodiments, the invention relates to semiconductors and devices comprising a composition of the invention.

Abstract translation: 公开了在有机半导体中有用的混合富勒烯衍生物的组合物，以及制备和使用这些组合物的方法。 在某些实施方案中，本发明涉及混合富勒烯衍生物的组合物，其进一步包含一种或多种额定的富勒烯类成分在特定范围内。 在某些其它实施方案中，本发明涉及由混合富勒烯原料或具有组合的纯富勒烯衍生物从混合富勒烯衍生物制备特定组成的混合富勒烯衍生物的方法。 在其它实施方案中，本发明涉及包含本发明组合物的半导体和器件。

公开(公告)号：US20100249168A1

公开(公告)日：2010-09-30

申请号：US12516992

申请日：2007-11-29

Applicant: David F. Kronholm ,  Alexander B. Sieval ,  Jan C. Hummelen

Inventor： David F. Kronholm ,  Alexander B. Sieval ,  Jan C. Hummelen

IPC: A61K31/473 ,  C07D221/18 ,  A61P29/00 ,  A61P17/06 ,  A61P17/02 ,  A61Q19/00 ,  A61P17/10

CPC classification number: C07D221/18 ,  A61K8/4926 ,  A61K2800/522 ,  A61Q19/00 ,  A61Q19/004 ,  C07D471/06

Abstract: The present invention relates to compositions and methods of using free radical scavengers with reduced 1O2 generation. In certain embodiments, these compositions and methods of use relate to fullerene-derived ketolactams and fullerene-derived keto lactam derivatives, fullerene derivatives, and/or fullerenes. In yet other embodiments, the invention relates to cosmetic or dermatological compositions comprising said free radical scavengers with reduced 1O2 generation.

Abstract translation: 本发明涉及使用还原的一氧化二氮的自由基清除剂的组合物和方法。 在某些实施方案中，这些组合物和使用方法涉及富勒烯衍生的酮内酰胺和富勒烯衍生的酮内酰胺衍生物，富勒烯衍生物和/或富勒烯。 在其它实施方案中，本发明涉及化妆品或皮肤病学组合物，其包含具有降低的1O 2代的所述自由基清除剂。

公开(公告)号：US07435403B2

公开(公告)日：2008-10-14

申请号：US10614404

申请日：2003-07-03

Applicant: David F. Kronholm ,  Jack B. Howard

Inventor： David F. Kronholm ,  Jack B. Howard

IPC: B01J19/08

CPC classification number: B82Y40/00 ,  B01D46/0063 ,  B01D46/24 ,  B01D51/00 ,  B82Y30/00 ,  C01B32/15 ,  C01B32/152 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/843 ,  Y10S977/845

Abstract: A method of processing fullerenes includes generating a gas stream having suspended soot particles and condensable gases, wherein the condensable gases comprise fullerenes, and separating at least a portion of the condensable gases from the suspended soot particles using a gas/solid separations process. At least a portion of the fullerenes in the condensable gases can be condensed and collected after separation of the condensable gases.

Abstract translation: 处理富勒烯的方法包括产生具有悬浮的烟灰颗粒和可冷凝气体的气流，其中可冷凝气体包括富勒烯，并使用气/固分离方法从悬浮的烟灰颗粒中分离出至少一部分可冷凝气体。 在可冷凝气体分离后，可冷凝气体中至少一部分富勒烯可被冷凝和收集。

公开(公告)号：US07396520B2

公开(公告)日：2008-07-08

申请号：US10489846

申请日：2002-08-31

Applicant: Jack B. Howard ,  David F. Kronholm ,  Anthony J. Modestino ,  Henning Richter

Inventor： Jack B. Howard ,  David F. Kronholm ,  Anthony J. Modestino ,  Henning Richter

IPC: B01J19/08

CPC classification number: F23C6/02 ,  B01J2219/00157 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152 ,  F23C99/00 ,  Y10S977/734 ,  Y10S977/842

Abstract: A mod of combustion and a multi-component reactor to accomplish this mode of combustion are disclosed which produces fullerenes and fullerenic material by combustion. This mode consists of de-coupling an oxidation region of a flame from a post-flame region, thus giving greater control over operating parameters, such as equivalence ratio, temperature, and pressure; allows conditions of the operating parameters of the combustion reaction to be attained which would not be easily attained by conventional methods; and offers the ability to more easily stabilize the combustion reactions to allow for higher throughputs of fuel and oxidant. Several embodiments of a primary zone of a multicomponent reactor are also disclosed. Said primary zone serves as the oxidation region, operates on the principle of providing recycle to the reacting combustion mixture, and which may be operated as approximately a well-mixed reactor. A secondary zone is also disclosed which provides further residence time for reaction and the ability to control operating parameters, operates on the principle of minimizing recycle of the reacting combustion mixture. The secondary zone may be operated as approximately a plug-flow reactor. The primary and secondary zones may be operated in conjunction or either one alone.

Abstract translation: 公开了一种用于实现这种燃烧模式的燃烧模块和多组分反应器，其通过燃烧产生富勒烯和富勒烯材料。 该模式包括将来自火焰后区域的火焰的氧化区域去耦合，从而对操作参数（例如当量比，温度和压力）进行更大的控制; 允许通过常规方法不容易地获得燃烧反应的操作参数的条件; 并提供更容易稳定燃烧反应的能力，以允许更高的燃料和氧化剂产量。 还公开了多组分反应器的主要区域的几个实施方案。 所述主区域用作氧化区域，其操作原理是向反应燃烧混合物提供循环，并且可以作为大致良好混合的反应器操作。 还公开了次级区域，其提供进一步的反应停留时间和控制操作参数的能力，其操作原理是使反应燃烧混合物的循环最小化。 次级区可以作为大约一个活塞流反应器操作。 主区域和次区域可以一起操作或者单独操作。