Methane conversion
    113.
    发明授权
    Methane conversion 失效
    甲烷转化

    公开(公告)号:US4721828A

    公开(公告)日:1988-01-26

    申请号:US666694

    申请日:1984-10-31

    申请人: Howard P. Withers

    发明人: Howard P. Withers

    摘要: A method for synthesizing hydrocarbons from a methane source which comprises contacting methane with a reducible oxide of Fe. The iron oxide is preferably combined with an amount of alkali and/or alkaline earth metal which is sufficient to improve the selectively to higher hydrocarbon products. The oxide is reduced by the contact which is carried at about 500.degree. to 1000.degree. C. Reducible oxides of Fe are regenerated by oxidizing the reduced composition with oxygen. The oxide Fe.sub.3 O.sub.4 is particularly effective in the process. Bulk iron oxides promoted by sodium and/or compounds thereof are particularly preferred contact solids.

    摘要翻译: 一种从甲烷源合成烃的方法,包括使甲烷与Fe的还原氧化物接触。 氧化铁优选与一定量的碱金属和/或碱土金属组合,其足以改善选择性地高级烃产物。 通过在约500℃〜1000℃下进行的接触来还原氧化物。通过用氧氧化还原的组成来再生Fe的可还原氧化物。 氧化物Fe 3 O 4在该方法中特别有效。 由钠和/或其化合物促进的体内氧化铁是特别优选的接触固体。

    Process for preparing a basic lithium phosphate catalyst for the
isomerization of alkene oxides
    114.
    发明授权
    Process for preparing a basic lithium phosphate catalyst for the isomerization of alkene oxides 失效
    制备用于烯烃氧化物异构化的碱性磷酸锂催化剂的方法

    公开(公告)号:US4720598A

    公开(公告)日:1988-01-19

    申请号:US878507

    申请日:1986-06-23

    CPC分类号: B01J27/1806 C07C29/56

    摘要: Process for preparing a basic lithium phosphate catalyst suitable for the gas phase isomerization of an alkene oxide to the corresponding alcohol, in which process an aqueous solution of a lithium compound is mixed in the presence of an alkali metal hydroxide with an aqueous solution of a phosphate salt or phosphoric acid, the process being characterized in that the aqueous solution of the phosphate salt or phosphoric acid is added evenly during a period of at least six hours to the homogeneously stirred aqueous solution of the lithium compound, upon which the precipitated lithium phosphate is washed with water and subsequently calcined.

    摘要翻译: 制备适用于将烯烃氧化物气相异构化至相应醇的碱式磷酸锂催化剂的方法,其中将锂化合物的水溶液在碱金属氢氧化物的存在下与磷酸盐水溶液混合 盐或磷酸,其特征在于将磷酸盐或磷酸的水溶液在至少6小时的时间内均匀地加入到锂化合物的均匀搅拌的水溶液中,沉淀的磷酸锂是在其上 用水洗涤,随后煅烧。

    Hydrotreating catalysts prepared from hydrogels
    115.
    发明授权
    Hydrotreating catalysts prepared from hydrogels 失效
    由水凝胶制备的加氢处理催化剂

    公开(公告)号:US4717698A

    公开(公告)日:1988-01-05

    申请号:US924091

    申请日:1986-10-28

    申请人: Richard A. Kemp

    发明人: Richard A. Kemp

    摘要: This invention relates to a process for preparing highly active hydrotreating catalysts prepared by incorporating a metals solution containing cobalt and an element selected from the group consisting of molybdenum, tungsten and mixtures thereof, into a phosphated alumina hydrogel support. The final calcined catalysts have surface areas greater than about 300 m.sup.2 /g, flat plate crush strengths greater than about 16 lbs and more than about 80% of their pore volume in pores having diameters less than about 70 .ANG..

    摘要翻译: 本发明涉及一种制备高活性加氢处理催化剂的方法,该催化剂通过将含有钴的金属溶液和选自钼,钨及其混合物的元素掺入磷酸化氧化铝水凝胶载体而制备。 最终煅烧的催化剂具有大于约300m 2 / g的表面积,平板挤压强度大于约16lbs,并且具有直径小于约70的孔的孔体积的大于约80%。

    Paraffin isomerization catalyst
    117.
    发明授权
    Paraffin isomerization catalyst 失效
    石蜡异构化催化剂

    公开(公告)号:US4710485A

    公开(公告)日:1987-12-01

    申请号:US782836

    申请日:1985-10-02

    申请人: Stephen J. Miller

    发明人: Stephen J. Miller

    IPC分类号: B01J29/85 C10G45/64 B01J27/18

    CPC分类号: B01J29/85 C10G45/64

    摘要: An isomerization catalyst which is useful for lowering the normal paraffin content of a hydrocarbon oil feedstock is described. The catalyst comprises an intermediate pore size silicoaluminophosphate molecular sieve and at least one Group VIII metal wherein the metal is occluded in the moleular sieve.

    摘要翻译: 描述了可用于降低烃油原料的正链烷烃含量的异构化催化剂。 该催化剂包括中等孔径的硅铝磷酸盐分子筛和至少一种第Ⅷ族金属,其中金属被吸留在细孔中。

    Process for producing wide-pore catalyst supports
    120.
    发明授权
    Process for producing wide-pore catalyst supports 失效
    生产宽孔催化剂载体的方法

    公开(公告)号:US4624938A

    公开(公告)日:1986-11-25

    申请号:US727975

    申请日:1985-04-26

    申请人: Richard A. Kemp

    发明人: Richard A. Kemp

    摘要: This invention relates to a process for preparing catalyst supports with a wide pore size distribution by simultaneously titrating an acid aluminum species and a basic aluminum species, and interacting the precipitate with a phosphorus-containing oxide during the aging step. The porous resulting alumina supports have surface areas above about 300 m.sup.2 /g with a significant fraction of the pores having diameters greater than 350 .ANG. and a significant fraction of the pores having diameters less than 70 .ANG..

    摘要翻译: 本发明涉及通过同时滴定酸性铝物质和碱性铝物质制备具有宽孔径分布的催化剂载体的方法,并且在老化步骤期间使沉淀物与含磷氧化物相互作用。 多孔产生的氧化铝载体的表面积高于约300m 2 / g,其中大部分孔的直径大于350,大部分孔的直径小于70。