公开(公告)号：US08871959B2

公开(公告)日：2014-10-28

申请号：US13122999

申请日：2009-10-02

Applicant: Markus Gitter

Inventor： Markus Gitter

IPC: C07D303/00 ,  C07D301/03 ,  C07D301/10

CPC classification number: C07D301/10

Abstract: The present invention relates to a continuous process for producing an alkylene oxide by direct oxidation of an alkene with oxygen by reacting a mixture comprising alkene and oxygen in the presence of a silver-comprising catalyst for a run time Δt(i), wherein during the oxidation, the catalyst is additionally contacted at least once with a further mixture comprising ethanol for a run time Δt(ii), wherein the run time Δt(i)>Δt(ii).

Abstract translation: 本发明涉及通过在含银催化剂的存在下使包含烯烃和氧气的混合物在运行时间（D）（i）下反应直接氧化烯烃来生产烯化氧的连续方法，其中 在氧化期间，催化剂另外与包含乙醇的另外的混合物至少一次接触一次，持续运行时间和（d），其中运行时间和运行时间和（d）。

公开(公告)号：US08859790B2

公开(公告)日：2014-10-14

申请号：US13574715

申请日：2011-01-26

Applicant: Prasad Muppa ,  Ron Postma ,  Bart Van Den Berg ,  Juergen Stock ,  Holger Wiederhold ,  Hans Rausch ,  Jorg Schallenberg ,  Stefan Bernhardt

Inventor： Prasad Muppa ,  Ron Postma ,  Bart Van Den Berg ,  Juergen Stock ,  Holger Wiederhold ,  Hans Rausch ,  Jorg Schallenberg ,  Stefan Bernhardt

IPC: C07D301/12 ,  B01J23/32 ,  B01J27/24 ,  B01D17/02 ,  B01J19/24 ,  C07D301/03 ,  B01J4/00 ,  B01F5/06

CPC classification number: C07D301/14 ,  B01D17/0208 ,  B01F5/061 ,  B01J4/00 ,  B01J19/2435 ,  B01J2219/00094 ,  B01J2231/72 ,  C07D301/03 ,  C07D301/12 ,  Y02P20/582

Abstract: Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.

Abstract translation: 提供了用于形成环氧化合物的装置和方法。 在一个实施方案中，提供了制备环氧化物的方法，包括加入氧化剂，水溶性锰络合物和末端烯烃以形成多相反应混合物，使末端烯烃与氧化剂在多相反应混合物中反应，所述多相反应混合物具有 在水溶性锰络合物的存在下的至少一个有机相，将反应混合物分离成至少一个有机相和水相，并重新使用至少部分水相。 本发明还涉及用于执行上述过程的装置。

公开(公告)号：US08765633B2

公开(公告)日：2014-07-01

申请号：US13070087

申请日：2011-03-23

Applicant: Hiroyuki Hirota ,  Hiromi Yunoki ,  Kenichi Ochiai

Inventor： Hiroyuki Hirota ,  Hiromi Yunoki ,  Kenichi Ochiai

IPC: B01J23/58 ,  B01J23/48 ,  C07D301/10 ,  C07D301/03

CPC classification number: B01J37/0203 ,  B01J21/04 ,  B01J23/66 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/0093 ,  B01J35/026 ,  B01J35/1009 ,  B01J37/0207 ,  B01J37/0213 ,  B01J37/04 ,  B01J37/06 ,  B01J37/18 ,  C07D301/10 ,  Y02P20/52

Abstract: A catalyst for the production of ethylene oxide in high efficiency and high selectivity, as well as stably for a long period of time is provided.A catalyst for the production of ethylene oxide comprising silver and a reaction promoter supported on a porous carrier comprising α-alumina as a main component, characterized in that a relative standard deviation of silver supporting rate of each particle of the catalyst is 0.001 or more and 0.1 or less.

Abstract translation: 提供了一种以高效率和高选择性生产环氧乙烷以及长时间稳定生产的催化剂。 一种用于生产包含银的催化剂和负载在包含α-氧化铝作为主要成分的多孔载体上的反应促进剂的催化剂，其特征在于，催化剂的每种颗粒的银支持速率的相对标准偏差为0.001以上， 0.1以下。

公开(公告)号：US20140171665A1

公开(公告)日：2014-06-19

申请号：US14136272

申请日：2013-12-20

Applicant: Shell Oil Company

Inventor： Jeroen VAN WESTRENEN

IPC: C07C7/10 ,  C07D301/03

CPC classification number: C07C7/10 ,  C07C1/20 ,  C07C7/08 ,  C07C11/04 ,  C07C11/06 ,  C07D301/03 ,  Y02P30/42 ,  C07C11/02

Abstract: The present invention provides a process for removing oxygenate from an olefin stream comprising oxygenate, comprising providing to an oxygenate recovery zone the olefin stream comprising oxygenate and a solvent comprising ethanol, treating the olefin stream comprising oxygenate with the solvent, and retrieving from the oxygenate recovery zone at least one oxygenate-depleted olefinic product stream comprising olefin and a spent solvent comprising at least part of the oxygenate.

Abstract translation: 本发明提供从包含含氧化合物的烯烃流中除去含氧化合物的方法，包括向含氧物回收区提供包含含氧化合物和包含乙醇的溶剂的烯烃流，用溶剂处理包含含氧化合物的烯烃流，并从含氧化合物回收 区域包含烯烃和包含至少部分含氧化合物的废溶剂的至少一种含氧化合物贫化烯烃产物流。

公开(公告)号：US20140155638A1

公开(公告)日：2014-06-05

申请号：US13933751

申请日：2013-07-02

Applicant: DEL MAR PHARMACEUTICALS

Inventor： DENNIS M. BROWN

IPC: C07D301/02 ,  C07D301/03 ,  C07D301/26

CPC classification number: C07D301/02 ,  C07D301/03 ,  C07D301/26

Abstract: The present invention provides an efficient method of synthesizing and purifying dianhydrohexitols such as dianhydrogalactitol. In general, as applied to dianhydrogalactitol, the method comprises: (1) reacting dulcitol with a concentrated solution of hydrobromic acid at a temperature of about 80° C. to produce dibromogalactitol; (2) reacting the dibromogalactitol with potassium carbonate in t-butanol to produce dianhydrogalactitol; and (3) purifying the dianhydrogalactitol using a slurry of ethyl ether to produce purified dianhydrogalactitol. Another method produces dianhydrogalactitol from dulcitol; this method comprises: (1) reacting dulcitol with a reactant to convert the 1,6-hydroxy groups of dulcitol to an effective leaving group to generate an intermediate; and (2) reacting the intermediate with an inorganic weak base to produce dianhydrogalactitol through an intramolecular SN2 reaction. Other methods for the synthesis of dianhydrogalactitol from dulcitol are described.

公开(公告)号：US20140046079A1

公开(公告)日：2014-02-13

申请号：US13614684

申请日：2012-09-13

Applicant: Yu-Chuan Hsu ,  Cheng-Fa Hsieh ,  I-Hui Lin

Inventor： Yu-Chuan Hsu ,  Cheng-Fa Hsieh ,  I-Hui Lin

IPC: C07D301/12 ,  C07D301/03

CPC classification number: B01J35/002 ,  B01J29/89 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/186 ,  C07D301/12 ,  C07D303/04

Abstract: A method for preparing an epoxide is disclosed. The method for preparing an epoxide includes the step of performing a reaction of an alkene and oxidant in the presence of a Ti—Si molecular sieve as a catalyst, and increases the conversion rate of hydrogen peroxide and the yield of the epoxide.

Abstract translation: 公开了一种制备环氧化物的方法。 制备环氧化物的方法包括在作为催化剂的Ti-Si分子筛的存在下进行烯烃和氧化剂的反应的步骤，并且增加过氧化氢的转化率和环氧化物的产率。

公开(公告)号：US08580982B2

公开(公告)日：2013-11-12

申请号：US13376879

申请日：2010-06-09

Applicant: Georg Seeber ,  Torsten Mäurer ,  Gerhard Theis ,  Dieter Köffer ,  Frank Rosowski

Inventor： Georg Seeber ,  Torsten Mäurer ,  Gerhard Theis ,  Dieter Köffer ,  Frank Rosowski

IPC: C07D301/03

CPC classification number: C07D301/10

Abstract: The present invention relates to a process for preparing ethylene oxide by reaction of ethylene with oxygen in the presence of at least one silver-comprising catalyst, wherein the reaction takes place in a reactor which has a catalyst packed bed having at least two zones (i) and (ii) and the silver content of the catalyst in zone (i) is lower than the silver content of the catalyst in zone (ii). The catalyst packed bed preferably has a further zone (a) with which the reaction mixture comes into contact before the zones (i) and (ii). According to the invention, the silver content of the catalyst in the zone (a) is higher than the silver content of the catalyst in zone (i).

Abstract translation: 本发明涉及通过乙烯与氧在至少一种含银催化剂存在下反应来制备环氧乙烷的方法，其中该反应在具有至少两个区域的催化剂填充床（i ）和（ii），并且（i）区域中的催化剂的银含量低于区域（ii）中的催化剂的银含量。 催化剂填充床优选具有另外的区域（a），反应混合物在区域（i）和（ii）之前与其接触。 根据本发明，区域（a）中催化剂的银含量高于区域（i）中催化剂的银含量。

公开(公告)号：US08569527B2

公开(公告)日：2013-10-29

申请号：US12865010

申请日：2008-05-15

Applicant: Marek Matusz

Inventor： Marek Matusz

IPC: C07D301/10 ,  C07D301/03 ,  C07C69/96 ,  C07C215/00 ,  C07C31/18 ,  C07C27/10

CPC classification number: B01J8/067 ,  B01D53/0423 ,  B01D2253/112 ,  B01D2257/308 ,  B01J8/0476 ,  B01J20/0233 ,  B01J20/04 ,  B01J20/041 ,  B01J20/08 ,  B01J20/28057 ,  B01J20/3021 ,  B01J20/3078 ,  B01J20/3092 ,  B01J20/3204 ,  B01J20/3236 ,  B01J21/04 ,  B01J23/66 ,  B01J23/685 ,  B01J23/686 ,  B01J23/687 ,  B01J23/688 ,  B01J2208/00221 ,  B01J2208/0023 ,  B01J2208/00982 ,  B01J2208/025

Abstract: The present invention provides a reactor system comprising: —one or more purification zones comprising an absorbent which comprises silver, an alkali or alkaline earth metal, and a support material having a surface area of more than 20 m2/g, and —a reaction zone comprising a catalyst, which reaction zone is positioned downstream from the one or more purification zones; an absorbent; a process for reacting a feed comprising one or more feed components; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.

Abstract translation: 本发明提供了一种反应器系统，其包含： - 一个或多个净化区，包括含有银，碱金属或碱土金属的吸收剂和表面积大于20m 2 / g的载体材料，以及 - 反应区 包括催化剂，该反应区位于该一个或多个净化区的下游; 吸收剂; 使包含一种或多种进料组分的进料反应的方法; 和1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的制备方法。

公开(公告)号：US08546592B2

公开(公告)日：2013-10-01

申请号：US13246325

申请日：2011-09-27

Applicant: Wayne Errol Evans ,  Paul Michael McAllister ,  Randall Clayton Yeates ,  Jeffrey Michael Kobe

Inventor： Wayne Errol Evans ,  Paul Michael McAllister ,  Randall Clayton Yeates ,  Jeffrey Michael Kobe

IPC: C07D301/03 ,  C07C29/00

CPC classification number: C07D301/10 ,  C07D301/04

Abstract: A process for the production of an olefin oxide, which process comprises reacting a feed comprising an olefin and oxygen in a reactor tube in the presence of a silver-containing catalyst, wherein the presence of water in the catalyst bed is controlled such that the ratio of the partial pressure of water (PPH2O) divided by the vapor pressure of water (VPH2O) is less than 0.006, preferably less than 0.004.

Abstract translation: 一种生产烯烃氧化物的方法，该方法包括在含银催化剂存在下，使反应器管中含有烯烃和氧的进料反应，其中催化剂床中的水的存在被控制， 的水分压（PPH2O）除以水的蒸气压（VPH2O）小于0.006，优选小于0.004。

公开(公告)号：US20130245294A1

公开(公告)日：2013-09-19

申请号：US13606308

申请日：2012-09-07

Applicant: Leslie Andrew CHEWTER ,  Rajaram RAMESH ,  Sivakumar SADASIVAN VIJAYAKUMARI ,  Jeroen VAN WESTRENEN

Inventor： Leslie Andrew CHEWTER ,  Rajaram RAMESH ,  Sivakumar SADASIVAN VIJAYAKUMARI ,  Jeroen VAN WESTRENEN

IPC: C07C1/22 ,  C07D301/03 ,  C07C29/48

CPC classification number: C07C1/22 ,  C07C1/20 ,  C07C29/48 ,  C07C41/06 ,  C07C2529/40 ,  C07C2529/70 ,  C07D301/03 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04 ,  C07C43/046

Abstract: The present invention provides a method for start-up of an Oxygenate-to-Olefins process, which process comprises the steps: a) providing an oxygenate-comprising feedstock to an Oxygenate-to-Olefins reaction zone and contacting the feedstock with a zeolite-comprising catalyst at a temperature in the range of from 450 to 700° C. ° C., to obtain an reaction product containing olefins; b) separating the reaction product obtained in step a) in at least a product fraction containing ethylene and/or propylene and a product fraction containing C4+ olefins; c) recycling at least part of the C4+ olefins in the product fraction containing C4+ olefins to the Oxygenate-to-Olefins reaction zone in step (a), characterised in that upon start-up the oxygenate-comprising feedstock initially comprises a first amount of externally supplied tert-alkyl ether and subsequently the amount of externally supplied tert-alkyl ether in the oxygenate-comprising feedstock is reduced.

Abstract translation: 本发明提供了一种启动氧化烯 - 烯烃工艺的方法，该方法包括以下步骤：a）将含氧化合物的原料提供到氧化烯 - 烯烃反应区，并使原料与沸石 - 在450-700℃的温度范围内包含催化剂，得到含有烯烃的反应产物; b）将至少含有乙烯和/或丙烯的产物级分和含有C4 +烯烃的产物级分的步骤a）中获得的反应产物分离; c）在步骤（a）中将至少部分含有C4 +烯烃的产物级分中的C4 +烯烃再循环到步骤（a）中的氧化烯 - 烯烃反应区，其特征在于，在启动时，含氧化合物原料最初包含第一量 外部供应的叔烷基醚，随后在含氧化合物的原料中外部供应的叔烷基醚的量减少。